Article
Chemistry, Physical
J. B. Gao, D. D. Ben, H. J. Yang, L. X. Meng, H. B. Ji, D. L. Lian, J. Chen, J. L. Yi, L. Wang, P. Li, Z. F. Zhang
Summary: This study investigates the rapid hardening and softening of SLM-Ti6Al4V alloy through electropulsing treatment, which affects the microhardness by evolving microstructures. Electropulsing treatment reduces the thermodynamic barrier for α->β solid-state phase transformation, further refining the microstructure of the SLM-Ti6Al4V alloy.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Yacheng Fang, Pan Ma, Shuimiao Wei, Zhiyu Zhang, Dongye Yang, Hong Yang, Shiguang Wan, Konda Gokuldoss Prashanth, Yandong Jia
Summary: The trade-off between strength and ductility in alloys has been a persistent issue in engineering applications. Conventional techniques often sacrifice ductility to increase strength, while high entropy alloys with dual-phase structures exhibit excellent strength-ductility synergy.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Materials Science, Multidisciplinary
Chen Yang, Jianbin Wang, Wenbo Du, Ruibin Duan, Zhanyong Zhao, Peikang Bai, Bing Han
Summary: Ti6Al4V alloy and Ti6Al4V-1SiCw composites were manufactured using selective laser melting (SLM) and the influence of solution aging heat treatment on microstructure evolution was investigated. The experimental results revealed that the heat-treated Ti6Al4V alloy exhibited coarse columnar crystals, forming a strong fiber texture. The composite had uniformly distributed equiaxed grains, resulting in a scattered texture distribution, which significantly reduced material anisotropy. Heat treatment increased the proportion of low-angle grain boundaries in the composite, forming numerous sub-grain boundaries and preventing the formation of coarse columnar grains. Furthermore, heat treatment effectively reduced dislocations and internal stress generated during the SLM process.
Article
Nanoscience & Nanotechnology
J. Karimi, C. Suryanarayana, I Okulov, K. G. Prashanth
Summary: This study investigated the effect of remelting on the microstructure and mechanical properties of Ti6Al4V materials fabricated using selective laser melting. The results showed that the number of remeltings significantly influenced the homogenization of the microstructure and mechanical properties of the materials, with an increase in hardness and ultimate tensile strength but a decrease in ductility observed with a higher number of melting steps.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Materials Science, Multidisciplinary
Zhonghua Li, Yanlei Chen, Shenghua Zhang, Bin Liu, Zezhou Kuai, Wenjuan Huo, Huirong Yang, Min Wei, Peikang Bai
Summary: This paper investigates the effects of aging heat treatment on the microstructure and mechanical properties of CuCrZr alloy fabricated by selective laser melting. The results show that aging treatment can improve the tensile strength and hardness of the alloy by causing precipitation strengthening of Cr in the microstructure. The findings are important for understanding the performance and optimizing the fabrication process of CuCrZr alloy.
RESULTS IN PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Haifei Lu, Zhao Wang, Jie Cai, Xiang Xu, Kaiyu Luo, Liujun Wu, Jinzhong Lu
Summary: The study revealed that laser shock peening treatment can effectively enhance the hot corrosion resistance of SLMed Ti6Al4V titanium alloy by generating high-density dislocations and nano-twins to enhance the grain boundary effect.
Article
Materials Science, Multidisciplinary
Weidong Huang, Xiayu Chen, Xu Huang, Hui Wang, Yitao Zhu
Summary: Selective laser melting (SLM) technology involves melting metal powder beds, leading to anisotropy, but the influence of process parameters has not been fully studied. Research shows that using different parameter scanning strategies and rotation angle increments can affect the growth trend of grains, thus influencing anisotropy.
Article
Materials Science, Multidisciplinary
Zezhou Kuai, Zhonghua Li, Bin Liu, Yanlei Chen, Shengyu Lu, Peikang Bai
Summary: The effect of heat treatment on the microstructure and mechanical properties of CuCrZr alloy fabricated by selective laser melting (SLM) was investigated. The optimal comprehensive performance of the alloy was achieved through direct ageing (DA) at 470 degrees C for 60 min. The alloy showed increased tensile strength and hardness after solution and ageing treatments.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Nanoscience & Nanotechnology
Y. K. Xiao, Q. Yang, Z. Y. Bian, H. Chen, Y. Wu, Q. Lian, Z. Chen, H. W. Wang
Summary: Selective laser melting (SLM) of aluminium alloys is a research focus for fabricating complex components in aerospace and automotive industries. This study demonstrated the effects of post heat treatment on microstructures and mechanical properties, showing that SLMed TiB2/Al-7Si-Cu-Mg samples can achieve appropriate mechanical properties through post-heat treatments.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Materials Science, Multidisciplinary
Xina Huang, Shoubin Ding, Wen Yue
Summary: Cryogenic treatment was proposed to improve the tribological properties of Ti6Al4V used as an artificial hip joint. The microstructure and hardness of the specimens were found to be affected by cryogenic treatment, leading to an improvement in tribological properties. Different wear mechanisms were observed for specimens treated with cryogenic treatment for different durations.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Nanoscience & Nanotechnology
J. J. Shi, Z. Q. Zhou, K. Xu, G. Y. Zhou, Z. J. Zhou, C. P. Li, G. F. Chen, X. G. Lu, G. H. Cao
Summary: This study investigates the effect of heat treatment on the microstructure and small punch creep property of Inconel 718 alloy fabricated by selective laser melting (SLM). The results show that a higher temperature solution treatment can eliminate stress concentration and lead to grain transformation and recrystallization. The distribution of grain boundaries and twin boundaries affects the creep life and fracture mode.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Article
Materials Science, Multidisciplinary
Paul Lekoadi, Monnamme Tlotleng, Kofi Annan, Nthabiseng Maledi, Bathusile Masina
Summary: This study demonstrates that proper heat treatment parameters can improve the microstructural properties of Ti6Al4V components produced using high speed selective laser melting, leading to enhanced mechanical performance.
Article
Materials Science, Multidisciplinary
Liu Li, Yunxiang Chen, Yanjin Lu, Sijie Qin, Gonghao Huang, Tingting Huang, Jinxin Lin
Summary: This study focused on improving the corrosion resistance of Ti6Al4V3Cu alloys produced by selective laser melting by fabricating antibacterial powders and applying different heat treatments. The research showed that adjusting the microstructure of the alloy through heat treatment can enhance its corrosion resistance.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Nanoscience & Nanotechnology
Abdulaziz Kurdi, A. K. Basak
Summary: The mechanical properties and deformation behaviour of SLMed Ti6Al4V alloy are influenced by the microstructure and loading direction, resulting in anisotropy. The alloy exhibits higher yield and ultimate compressive strength compared to mill-annealed alloy.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Nanoscience & Nanotechnology
Luo Zhang, Yetao Li, Qingdong Zhang, Sheng Zhang
Summary: Selective laser melting (SLM) is a new method for manufacturing superalloy hot-end components. This study investigated the microstructure, phase transformation, and mechanical properties of SLMed IN738 before and after heat treatments. The study found that the optimal treatment involved solution treatment at 1200℃ for 2 hours, followed by aging at 750℃ for 24 hours, which significantly improved the mechanical properties of the samples.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2022)
Article
Materials Science, Multidisciplinary
Rathinavelu Sokkalingam, Zhao Chao, Katakam Sivaprasad, Veerappan Muthupandi, Jayamani Jayaraj, Parthiban Ramasamy, Juergen Eckert, Konda Gokuldoss Prashanth
Summary: CoCrFeMnNi high-entropy alloy/AISI 316L stainless steel bimetal was fabricated using SLM, showing enhanced hardness and tensile strength due to the composition and structure advantages. However, the presence of defects and higher susceptibility to pitting corrosion in CoCrFeMnNi-HEA make it more prone to corrosion attack in corrosive environments.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Sabine C. Bodner, Kostyantin Hlushko, Kevin Kutlesa, Juraj Todt, Oliver Renk, Michael Meindlhumer, Florian Resch, Marc-Andre Nielsen, Jozef Keckes, Jurgen Eckert
Summary: The correlations between process conditions, microstructure, and mechanical properties of additively manufactured components are explored in this study. The results show that the applied hatch strategy has a significant impact on the microstructure and mechanical properties of the samples, especially the anisotropy observed in the plane perpendicular to the build direction.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Sepide Hadibeik, Florian Spieckermann, Martin Nosko, Farzad Khodabakhshi, Mahmoud Heydarzadeh Sohi, Juergen Eckert
Summary: A novel approach for fabricating bulk metallic glass using additive manufacturing has been studied, however, there are challenges, such as unmelted powder and compositional deviation, that need further investigation to optimize the process parameters.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Jelena Petrusa, Benjamin Meier, Gerda Gruenbacher, Wolfgang Waldhauser, Juergen Eckert
Summary: The effects of laser energy density on the relative density and microstructure of cp-TiGd2 fabricated by LB-PBF were studied, and the influence of printing orientation and different surface treatments on surface topography and biocompatibility were investigated. The aim is to develop additive manufacturing process parameters that can achieve full density and satisfactory biocompatibility for cp-TiGd2 as a low-cost alternative to biomedical materials. An optimized process with high density, improved surface roughness, and noncytotoxicity was achieved using a wide range of process parameters.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Chemistry, Physical
Zequn Zhang, Simon Fellner, Sergey Ketov, Megan J. Cordill, Huaping Sheng, Christian Mitterer, Kaikai Song, Christoph Gammer, Juergen Eckert
Summary: The phase evolution of alloys and atomic diffusion are closely related. However, the influence of reactive diffusion on phase formation in high-entropy alloys (HEAs) is still not clear. This study investigates the phase evolution of a multicomponent CoCrFeNi/Al diffusion couple and reveals the combined effects of enthalpy and entropy on phase formation in HEAs at elevated temperatures. Surface modification of HEAs can be achieved through film deposition and annealing processes.
Review
Electrochemistry
Baran Sarac, A. Sezai Sarac, Juergen Eckert
Summary: This review provides an introduction to the use of advanced amorphous metal catalysts for hydrogen storage and production via electrochemistry. Pd-based metallic glasses have gained significant attention due to their unique atomic structure and properties for energy applications. The review covers the fabrication techniques, hydrogen sorption, hydrogen evolution, kinetics, and future prospects of Pd-based metallic glasses. Overall, it offers a comprehensive overview for large-scale hydrogen energy storage and production systems.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Materials Science, Multidisciplinary
Ming-Zhi Zhang, Kun Zhang, Kai-Kai Song, Xiao-Yu Zou, Wei-Dong Song, Ke-Feng Li, Li-Na Hu, Ze-Qun Zhang, Juergen Eckert
Summary: In this study, CoCrFeMnNi high-entropy alloys with a surface gradient nanostructure were produced using industrial shot blasting, which significantly improved their mechanical properties. The severely plastically deformed surface layer had a multi-scale hierarchical structure and increased in depth with shot-blasting time. The microhardness and tensile strength of the alloy were significantly higher after shot-blasting. The improved strain hardening and prevention of early necking in the gradient-nanostructured surface layer contributed to its high toughness.
Article
Chemistry, Physical
Monika Antoni, Florian Spieckermann, Niklas Plutta, Christoph Gammer, Marlene Kapp, Parthiban Ramasamy, Christian Polak, Reinhard Pippan, Michael J. J. Zehetbauer, Juergen Eckert
Summary: The effects of severe plastic deformation (SPD) by means of high-pressure torsion (HPT) on Fe73.9Cu1Nb3Si15.5B6.6 and Fe81.2Co4Si0.5B9.5P4Cu0.8 iron-based metallic glasses were compared. HPT processing extended the consolidation and deformation ranges for Fe73.9Cu1Nb3Si15.5B6.6, and achieved consolidation and deformation with minimum cracks for Fe81.2Co4Si0.5B9.5P4Cu0.8 for the first time. Various analyses revealed that Fe81.2Co4Si0.5B9.5P4Cu0.8 exhibited HPT-induced crystallization phenomena, while Fe73.9Cu1Nb3Si15.5B6.6 did not crystallize even at high HPT-deformation degrees.
Editorial Material
Chemistry, Multidisciplinary
Juergen Eckert, Daniel Kiener
Article
Chemistry, Physical
Keziban Huner, Baran Sarac, Eray Yuece, Amir Rezvan, Matej Micusik, Maria Omastova, Juergen Eckert, A. Sezai Sarac
Summary: The incorporation of iron and carboxylic acid-functionalized polyaniline into polymeric polycaprolactone structures enhances the electron-donating ability and conductivity of the compound, making it suitable for electrochemical immunosensors.
MOLECULAR SYSTEMS DESIGN & ENGINEERING
(2023)
Article
Engineering, Mechanical
Bin Chen, Yunli Li, Daniel Sopu, Juergen Eckert, Wenping Wu
Summary: The shock-induced dynamic mechanical behavior and spallation failure of Ni-based single crystal superalloys are studied using non-equilibrium molecular dynamic simulations. Two modes of classical spallation and micro-spallation are observed during the spallation failure. The deformation mechanism is dominated by slip and drag of dislocations at low shock velocities, while complex phase transitions from FCC to BCC or disordered structures occur at higher velocities, leading to a decrease in spallation strength. The presence of voids significantly lowers the spallation strength, and the reduction in strength is proportional to the radius of the voids.
INTERNATIONAL JOURNAL OF PLASTICITY
(2023)
Article
Materials Science, Multidisciplinary
Xiaoming Liu, Zongde Kou, Ruitao Qu, Weidong Song, Yijia Gu, Changshan Zhou, Qingwei Gao, Jiyao Zhang, Chongde Cao, Kaikai Song, Vladislav Zadorozhnyy, Zequn Zhang, Juergen Eckert
Summary: This study utilizes high-temperature extrusion and annealing to optimize the microstructures and mechanical properties of the Co34Cr32Ni27Al3.5Ti3.5 multicomponent alloy. Hot extrusion reduces grain sizes and promotes the precipitation of nanoparticles inside the FCC matrix and grain boundaries. Subsequent annealing regulates the microstructures and enhances the mechanical properties.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Ming-Wei Wu, Kai Ni, Yang Lei, Xin-Xing Xiong, Yi-Ting Chuang, Quiao-En Lin, Pei Wang, Parthiban Ramasamy, Juergen Eckert
Summary: Selective laser melting (SLM) was utilized to produce CuZrAl metallic glass (MG) scaffolds with combined lattice structures of body-centered cubic and face-centered cubic (F2BCC), and the effects of lattice structures on mechanical behavior were investigated. The results revealed that curved struts remarkably enhanced compressive ductility by 122% and energy absorption by 106%. The presence of curved struts effectively prevented catastrophic shear fracture and delayed fracture occurrence due to the release of strain concentrations. This study demonstrates the potential of improving the ductility and toughness of SLM MG components through appropriate lattice structure design.
Article
Engineering, Manufacturing
Ruiqi Wang, Lixia Xi, Lili Feng, Baran Sarac, Konda Gokuldoss Prashanth, Juergen Eckert, Dongdong Gu
Summary: Dual-phase reinforcing approach is an efficient strategy for fabricating advanced aluminum matrix composites. However, designing a dual-phase reinforcing system with synergistic strengthening effect for LPBF process is challenging.
3D PRINTING AND ADDITIVE MANUFACTURING
(2023)
Article
Materials Science, Multidisciplinary
Xintian Wang, Zhiyong Ji, Robert O. Ritchie, Ilya Okulov, Juergen Eckert, Chunlei Qiu
Summary: In this study, TiAl and Cr3C2 particles were added to a CrMnFeCoNi alloy to improve its processibility and mechanical properties. The addition of TiAl particles resulted in the formation of cracks, but the further addition of Cr3C2 particles helped suppress hot cracking. The presence of long-range ordered domains and precipitates contributed to the improved strength of the dual-particle containing alloy.
MATERIALS TODAY ADVANCES
(2023)
Article
Chemistry, Physical
J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia
Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xianxiang Lv, Jing Jin, Weiguang Yang
Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao
Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong
Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang
Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong
Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu
Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad
Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi
Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang
Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang
Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang
Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu
Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee
Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu
Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)