4.7 Article

Microwave Absorption of α-Fe2O3@diatomite Composites

期刊

出版社

MDPI
DOI: 10.3390/ijms23169362

关键词

diatomite; alpha-Fe2O3; microwave absorption

资金

  1. National Natural Science Foundation of China - Fundamental Research Funds for the Central Universities [51908092, 2020CDJXZ001, 2021CDJJMRH-005, SKLMT-ZZKT-2021M04]
  2. National Natural Science Foundation of China-Guangdong [U1801254]
  3. Chongqing Special Postdoctoral Science Foundation [XmT2018043]
  4. Chongqing Research Program of Basic Research and Frontier Technology [cstc2017jcyjBX0080]
  5. Natural Science Foundation Project of Chongqing [cstc2019jcyjbsh0079, cstc2019jcyjbshX0085]
  6. Technological projects of Chongqing Municipal Education Commission [KJZDK201800801]
  7. Innovative Research Team of Chongqing [CXTDG201602014]
  8. Innovative technology of New materials and metallurgy [2019CDXYCL0031]

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A neoteric composite material of round sieve diatomite decorated with sea-urchin-like alpha-iron trioxide was prepared and studied for its electromagnetic parameters and absorbing properties.
A neoteric round sieve diatomite (De) decorated with sea-urchin-like alpha-type iron trioxide (alpha-Fe2O3) synthetics was prepared by the hydrothermal method and further calcination. The results of the electromagnetic (EM) parameters of alpha-Fe2O3-decorated De (alpha-Fe2O3@D) showed that the minimum reflection loss (RLmin) of alpha-Fe2O3@D could reach -54.2 dB at 11.52 GHz and the matched absorber thickness was 3 mm. The frequency bandwidth corresponding to the microwave RL value below -20 dB was up to 8.24 GHz (9.76-18 GHz). This indicates that alpha-Fe2O3@D composite can be a lightweight and stable material; because of the low density of De (1.9-2.3 g/cm(3)), the density of alpha-Fe2O3@D composite material is lower than that of alpha-Fe2O3 (5.18 g/cm(3)). We found that the combination of the magnetic loss of sea-urchin-like alpha-Fe2O3 and the dielectric loss of De has the most dominant role in electromagnetic wave absorption and loss. We focused on comparing the absorbing properties before and after the formation of sea-urchin-like alpha-Fe2O3 and explain in detail the effects of the structure and crystal shape of this novel composite on the absorbing properties.

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