Integrating Reactive Chlorine Species Generation with H2 Evolution in a Multifunctional Photoelectrochemical System for Low Operational Carbon Emissions Saline Sewage Treatment

Conventional wastewater treatment plants (WWTPs) suffer from high carbon emissions and are inefficient in removing emerging organic pollutants (EOPs). Consequently, we have developed a low operational carbon emissions multifunc-tional photoelectrochemical (PEC) system for saline sewage treatment to simultaneously remove organic pollutants, ammonia, and bacteria, coupled with H2 evolution. A reduced BiVO4 (r-BiVO4) photoanode with enhanced PEC properties, ascribed to constructing sufficient oxygen vacancies and V4+ species, was synthesized for the aforementioned technique. The PEC/r-BiVO4 process could treat saline sewage to meet local WWTPs' discharge standard in 40 min at 2.0 V vs Ag/AgCl and completely degrade carbamazepine (one of EOPs), coupled with 633 mu mol of H2 production; 93.29% reduction in operational carbon emissions and 77.82% decrease in direct emissions were achieved by the PEC/r-BiVO4 process compared with large-scale WWTPs, attributed to the restrained generation of CH4 and N2O. The PEC system activated chloride ions in sewage to generate numerous reactive chlorine species and facilitate center dot OH production, promoting contaminants removal. The PEC system exhibited operational feasibility at varying pH and total suspended solids concentrations and has outstanding reusability and stability, confirming its promising practical potential. This study proposed a novel PEC reaction for reducing operational carbon emissions from saline sewage treatment.

Automated summary

A novel multifunctional photoelectrochemical system with low operational carbon emissions was developed for saline sewage treatment, effectively removing organic pollutants, ammonia, and bacteria while generating hydrogen. Compared to traditional WWTPs, the system significantly reduced operational carbon and direct emissions, demonstrating high operational feasibility and stability.