4.7 Article

Hybrid NF and UF membranes tailored using quaternized polydopamine for enhanced removal of salts and organic pollutants from water

期刊

DESALINATION
卷 539, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.desal.2022.115954

关键词

Nanofiltration; Ultrafiltration; Quaternized polydopamine; Nanohybrid; Antifouling

资金

  1. Khalifa University through the Center for Membrane and Advanced Water Technology (CMAT) [RC2-2018-009]

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In this study, a quaternized polydopamine nanohybrid was synthesized and used as an additive in Poly(ether sulfone) membranes. The hybrid membranes exhibited high water permeability, excellent antifouling activity, and impressive rejection of salt solutions and dyes. They also showed strong antibacterial activity.
In this work, a quaternized polydopamine (QSiPD) nanohybrid was synthesized via condensation reaction between the silicon hydroxyl moieties of the hydrolyzed QSiP and hydroxyl moieties of polydopamine (PDA) and applied for the first time as a single additive to Poly(ether sulfone) (PES) ultrafiltration (UF) and loose nanofiltration (NF) membranes made via non-solvent induced phase separation (NIPS). QSiPD was added at a maximum loading of 8 and 20 wt% in UF and NF membranes, respectively. The nanohybrid material and membranes were thoroughly characterized. The hydrophilicity, surface charge, and pore structures of the hybrid membranes were progressively tuned with the increase of the QSiPD loading. The UF membrane water permeability of the membrane with 2 wt% QSiPD was as high as similar to 559 L m(-2) h(-1) bar(-1). The hybrid UF membranes also exhibited superior antifouling activity with a BSA rejection rate of similar to 99 % uncompromised by the high membrane flux. The hybrid NF membranes showed significant rejection (45-67 %) of several monovalent (NaCl) and divalent (CaCl2, MgSO4, Na2SO4) salt solutions and an outstanding rejection of Congo red dye (>99.9 %). Furthermore, both hybrid UF and NF membranes showed a strong antibacterial activity against E. coli.

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