Stimuli-responsive chirality inversion of metallohelices and related dynamic metal complexes

Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of M8L6 Cubic Cages

(2022) Weichao Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transient chirality inversion during racemization of a helical cobalt(III) complex

(2022) Yoko Sakata et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Chiral Detection with Coordination Polymers

(2021) Shannon Thoonen et al.   Chemistry-An Asian Journal

Enhancement of Alkali Metal Ion Recognition by Metalation of a Tris(saloph) Cryptand Having Benzene Rings at the Bridgeheads

(2021) Shigehisa Akine et al.   INORGANIC CHEMISTRY

Control of Guest Binding Kinetics in Macrocycles and Molecular Cages

(2020) Shigehisa Akine et al.   CHEMISTRY LETTERS

Supramolecular Hydrogels with Tunable Chirality for Promising Biomedical Applications

(2020) Xiaoqiu Dou et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tuning Achiral to Chiral Supramolecular Helical Superstructures

(2020) Dinesh N. Nadimetla et al.   CHEMICAL RECORD

Post‐Metalation Modification of a Macrocyclic Dicobalt(III) Metallohost by Site‐Selective Ligand Exchange for Guest Recognition Control

(2020) Yoko Sakata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Guest Recognition Control Accompanied by Stepwise Gate‐Closing and Opening of a Macrocyclic Metallohost

(2020) Yoko Sakata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Supramolecular Chirality in Metal–Organic Complexes

(2020) Jinqiao Dong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ligand Exchange Strategy for Tuning of Helicity Inversion Speeds of Dynamic Helical Tri(saloph) Metallocryptands

(2019) Yoko Sakata et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Diastereodynamic Probe Transducing Molecular Length into Chiroptical Readout

(2019) Carlo Bravin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complexation of Chiral Zinc(II) Porphyrin Tweezer with Achiral Aliphatic Diamines Revisited: Molecular Dynamics, Electronic CD, and 1H NMR Analysis

(2019) Bapan Saha et al.   INORGANIC CHEMISTRY

Switching of Recognition First and Reaction First Mechanisms in Host–Guest Binding Associated with Chemical Reactions

(2019) Yoko Sakata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(Nano)mechanical Motion Triggered by Metal Coordination: from Functional Devices to Networked Multicomponent Catalytic Machinery

(2019) Abir Goswami et al.   CHEMICAL REVIEWS

A helicate based three-state molecular switch

(2018) Xiaofei Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Different Origins of Strain-Induced Chirality Inversion of Co2+-Triggered Supramolecular Peptide Polymers

(2018) Hyesong Park et al.   CHEMISTRY OF MATERIALS

Synthetic strategies for chiral metal-organic frameworks

(2018) Zongsu Han et al.   CHINESE CHEMICAL LETTERS

Induced chirality of cage metal complexes switched by their supramolecular and covalent binding

(2018) Vladyslava B. Kovalska et al.   DALTON TRANSACTIONS

pseudo[1]Catenane-Type Pillar[5]thiacrown Whose Planar Chiral Inversion is Triggered by Metal Cation and Controlled by Anion

(2018) Eunji Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Response speed control of helicity inversion based on a “regulatory enzyme”-like strategy

(2018) Shiho Sairenji et al.   Scientific Reports

Controlling Supramolecular Chirality in Multicomponent Self-Assembled Systems

(2018) Pengyao Xing et al.   ACCOUNTS OF CHEMICAL RESEARCH

From Hierarchical Helicates to Functional Supramolecular Devices

(2018) Markus Albrecht et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Closed Metallomolecular Cage that can Open its Aperture by Disulfide Exchange

(2018) Shigehisa Akine et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electronic chirality inversion of lanthanide complex induced by achiral molecules

(2018) Satoshi Wada et al.   Scientific Reports

Origin of Both Right- and Left-Handed Helicities in a Supramolecular Gel with and without Ni2+ at the Supramolecular Level

(2017) Misun Go et al.   INORGANIC CHEMISTRY

Complexation of Chiral Zinc-Porphyrin Tweezer with Achiral Diamines: Induction and Two-Step Inversion of Interporphyrin Helicity Monitored by ECD

(2017) Bapan Saha et al.   INORGANIC CHEMISTRY

Chiral transition metal complexes: Synthetic approach and biological applications

(2017) Surbhi Sharma et al.   INORGANICA CHIMICA ACTA

A Metallo-molecular Cage That Can Close the Apertures with Coordination Bonds

(2017) Shigehisa Akine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transfer and Dynamic Inversion of Coassembled Supramolecular Chirality through 2D-Sheet to Rolled-Up Tubular Structure

(2017) Heekyoung Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange

(2017) Yoko Sakata et al.   Nature Communications

Chiral metal–organic cages/containers (MOCs): From structural and stereochemical design to applications

(2017) Mei Pan et al.   COORDINATION CHEMISTRY REVIEWS

Light-Directed Dynamic Chirality Inversion in Functional Self-Organized Helical Superstructures

(2016) Hari Krishna Bisoyi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Helical Systems: Helical Assemblies of Small Molecules, Foldamers, and Polymers with Chiral Amplification and Their Functions

(2016) Eiji Yashima et al.   CHEMICAL REVIEWS

Helicene-based chiroptical switches

(2016) Helena Isla et al.   COMPTES RENDUS CHIMIE

Lanthanide contraction for helicity fine-tuning and helix-winding control of single-helical metal complexes

(2016) Shiho Sairenji et al.   DALTON TRANSACTIONS

Redox-Triggered Helicity Inversion in Chiral Cobalt Complexes in Combination with H+ and NO3– Stimuli

(2016) Janusz Gregoliński et al.   INORGANIC CHEMISTRY

Stimuli-Directed Helical Chirality Inversion and Bio-Applications

(2016) Ziyu Lv et al.   Polymers

Overcoming Statistical Complexity: Selective Coordination of Three Different Metal Ions to a Ligand with Three Different Coordination Sites

(2015) Shigehisa Akine et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Artificial Molecular Machines

(2015) Sundus Erbas-Cakmak et al.   CHEMICAL REVIEWS

Supramolecular Assembly of Achiral Alkynylplatinum(II) Complexes and Carboxylic β-1,3-Glucan into Different Helical Handedness Stabilized by Pt⋅⋅⋅Pt and/or π-π Interactions

(2015) Clive Yik-Sham Chung et al.   CHEMISTRY-A EUROPEAN JOURNAL

Progress in the synthetic and functional aspects of chiral metal–organic frameworks

(2015) Kamal Kumar Bisht et al.   CRYSTENGCOMM

Solvation-Induced Helicity Inversion of Pseudotetrahedral Chiral Copper(II) Complexes

(2015) Anne-Christine Chamayou et al.   INORGANIC CHEMISTRY

Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion

(2015) Nadia Marino et al.   Chemical Science

Ion-mediated conformational switches

(2015) Peter C. Knipe et al.   Chemical Science

Stereochemistry in Subcomponent Self-Assembly

(2014) Ana M. Castilla et al.   ACCOUNTS OF CHEMICAL RESEARCH

Reversibly tunable helix inversion in supramolecular gels trigged by Co2+

(2014) So Hyeon Park et al.   CHEMICAL COMMUNICATIONS

Dynamic Helicity Control of a Single-helical Oligooxime Complex and Acid–Base-triggered Repeated Helicity Inversion Mediated by Amino Acids

(2014) Shiho Sairenji et al.   CHEMISTRY LETTERS

Stereocontrol in Dinuclear Triple Lithium-Bridged Titanium(IV) Complexes: Solving Some Stereochemical Mysteries

(2014) Markus Albrecht et al.   CHEMISTRY-A EUROPEAN JOURNAL

Strong Solvent-Dependent Preference of Δ and Λ Stereoisomers of a Tris(diamine)nickel(II) Complex Revealed by Vibrational Circular Dichroism Spectroscopy

(2014) Christian Merten et al.   INORGANIC CHEMISTRY

Solid Polymer Films Exhibiting Handedness-Switchable, Full-Color-Tunable Selective Reflection of Circularly Polarized Light

(2014) Yuuya Nagata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic helicity control of single-helical oligooxime metal complexes by coordination of chiral carboxylate ions

(2014) Shiho Sairenji et al.   TETRAHEDRON LETTERS

Supramolecular Chirality in Dynamic Coordination Chemistry

(2014) Hiroyuki Miyake   Symmetry-Basel

Stereochemical Communication within Tetrahedral Capsules

(2013) Ana M. Castilla et al.   CHEMISTRY LETTERS

Anion and Solvent Induced Chirality Inversion in Macrocyclic Lanthanide Complexes

(2013) Aleksandra Gerus et al.   INORGANIC CHEMISTRY

Stepwise Helicity Inversions by Multisequential Metal Exchange

(2013) Shigehisa Akine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Chemistry and Applications of Metal-Organic Frameworks

(2013) H. Furukawa et al.   SCIENCE

Perfect encapsulation of a guanidinium ion in a helical trinickel(ii) metallocryptand for efficient regulation of the helix inversion rate

(2013) Shigehisa Akine et al.   Inorganic Chemistry Frontiers

A Propensity Scale for Type II Polyproline Helices (PPII): Aromatic Amino Acids in Proline-Rich Sequences Strongly Disfavor PPII Due to Proline–Aromatic Interactions

(2012) Alaina M. Brown et al.   BIOCHEMISTRY

Helicity inversion from left- to right-handed square planar Pd(ii) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism

(2012) Hiroyuki Miyake et al.   CHEMICAL COMMUNICATIONS

Transfer of chirality from ligands to metal centers: recent examples

(2012) Jeanne Crassous   CHEMICAL COMMUNICATIONS

Coordination chemistry strategies for dynamic helicates: time-programmable chirality switching with labile and inert metal helicates

(2012) Hiroyuki Miyake et al.   CHEMICAL SOCIETY REVIEWS

Donor-Induced Helical Inversion of 1,1′-Binaphthyl Connecting with Two Molybdenum Complexes

(2012) Li Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiroptical Switches: Applications in Sensing and Catalysis

(2012) Zhaohua Dai et al.   MOLECULES

The transformation of chiral signals into macroscopic properties of materials using chirality-responsive polymers

(2012) Guangyan Qing et al.   NPG Asia Materials

“Induced Fit” in Chiral Recognition: Epimerization upon Dimerization in the Hierarchical Self-Assembly of Helicate-type Titanium(IV) Complexes

(2011) Markus Albrecht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spontaneous enrichment of one-handed helices by dissolution of quasiracemic crystals of a tetranuclear single helical complex

(2011) Shigehisa Akine et al.   CHEMICAL COMMUNICATIONS

Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles

(2011) Rajesh Chakrabarty et al.   CHEMICAL REVIEWS

pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene withL- andD-Cysteine

(2011) Ran Lin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Synthesis of Octahedral Coordination Complexes

(2011) Eric Meggers   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Novel ion recognition systems based on cyclic and acyclic oligo(salen)-type ligands

(2011) Shigehisa Akine   JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY

Asymmetric Catalysis with Chiral Porous Metal–Organic Frameworks: Critical Issues

(2011) Cheng Wang et al.   Journal of Physical Chemistry Letters

A Molecular Leverage for Helicity Control and Helix Inversion

(2011) Shigehisa Akine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Planar-Chiral Macrocyclic Host Pillar[5]arene: No Rotation of Units and Isolation of Enantiomers by Introducing Bulky Substituents

(2011) Tomoki Ogoshi et al.   ORGANIC LETTERS

Dinuclear metal complexes composed of peptide chains: Solvent-induced switching and inversion of the metal-centered chirality

(2011) Naoki Ousaka et al.   Chemical Science

Recognition and regulation of unique nucleic acid structures by small molecules

(2010) Guangtao Song et al.   CHEMICAL COMMUNICATIONS

Reversible Mutarotation in a Macrocyclic Ytterbium Complex

(2010) Francesco P. Ballistreri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition metal-based chiroptical switches for nanoscale electronics and sensors

(2010) James W. Canary et al.   COORDINATION CHEMISTRY REVIEWS

Planar-Chiral Pillar[5]arene: Chiral Switches Induced by Multiexternal Stimulus of Temperature, Solvents, and Addition of Achiral Guest Molecule

(2010) Tomoki Ogoshi et al.   JOURNAL OF ORGANIC CHEMISTRY

Reversible, Solvent-Induced Chirality Switch in Atrane Structure: Control of the Unidirectional Motion of the Molecular Propeller

(2010) Alexandre Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Helical Polymers: Synthesis, Structures, and Functions

(2009) Eiji Yashima et al.   CHEMICAL REVIEWS

Redox-triggered chiroptical molecular switches

(2009) James W. Canary   CHEMICAL SOCIETY REVIEWS

Chiral transfer in coordination complexes: towards molecular materials

(2009) Jeanne Crassous   CHEMICAL SOCIETY REVIEWS

Metal–organic framework materials as catalysts

(2009) JeongYong Lee et al.   CHEMICAL SOCIETY REVIEWS

Chiral Auxiliaries as Emerging Tools for the Asymmetric Synthesis of Octahedral Metal Complexes

(2009) Eric Meggers   CHEMISTRY-A EUROPEAN JOURNAL

Controlling Helical Chirality in Atrane Structures: Solvent-Dependent Chirality Sense in Hemicryptophane-Oxidovanadium(V) Complexes

(2009) Alexandre Martinez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclic and acyclic oligo(N2O2) ligands for cooperative multi-metal complexation

(2009) Shigehisa Akine et al.   DALTON TRANSACTIONS

Conformational Control in Metallofoldamers: Design, Synthesis and Structural Properties

(2009) Galia Maayan   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Circularly Polarized Luminescence of Eu(III) Complexes with Point- and Axis-Chiral Ligands Dependent on Coordination Structures

(2009) Takashi Harada et al.   INORGANIC CHEMISTRY

Multiple Folding Structures Mediated by Metal Coordination of Acyclic Multidentate Ligand

(2009) Shigehisa Akine et al.   INORGANIC CHEMISTRY

Spontaneous formation of a chiral supramolecular superhelix in the crystalline state using a single-stranded tetranuclear metallohelicate

(2008) Shigehisa Akine et al.   CHEMICAL COMMUNICATIONS

A Chemical Device That Exhibits Dual Mode Motions: Dynamic Coupling of Amide Coordination Isomerism and Metal-Centered Helicity Inversion in a Chiral Cobalt(II) Complex

(2008) Hiroyuki Miyake et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantiopure, Supramolecular Helices Containing Three-Dimensional Tetranuclear Lanthanide(III) Arrays: Synthesis, Structure, Properties, and Solvent-Driven Trinuclear/Tetranuclear Interconversion

(2008) Marco Lama et al.   INORGANIC CHEMISTRY

Helical Lanthanide(III) Complexes with Chiral Nonaaza Macrocycle

(2008) Janusz Gregoliński et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Time-Programmed Peptide Helix Inversion of a Synthetic Metal Complex Triggered by an Achiral NO3-Anion

(2007) Hiroyuki Miyake et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chirality-Responsive Helical Polymers

(2007) Eiji Yashima et al.   MACROMOLECULES