4.6 Article

Facile fabrication of binary BiOCl-Cu2CoSnS4 and ternary BiOCl-Cu2CoSnS4-TiO2 heterojunction nano photocatalyst for efficient sunlight-driven removal of direct blue 71 in an aqueous medium

出版社

ELSEVIER
DOI: 10.1016/j.colsurfa.2022.129841

关键词

Heterojunction; Nanocomposite; Photodegradation; DB-71 dye; Radical scavenging mechanism; Fermi level

向作者/读者索取更多资源

In this study, a novel BiOCl-Cu2CoSnS4-TiO2 ternary heterojunction nanocomposite was synthesized using a simple chemical precipitation method. Characterization results showed that the as-synthesized composite exhibited high photocatalytic activity for the degradation of organic dyes.
We report a novel BiOCl-Cu2CoSnS4-TiO2 ternary heterojunction nanocomposite fabricated via a simple chemical precipitation method by anchoring Cu2CoSnS4 and TiO2 on the surface of spherical BiOCl particles using ethylene glycol as a solvent at an ambient temperature (100 degrees C, 4 h). The as-synthesized BiOCl-Cu2CoSnS4-TiO2 nanocomposite was examined by transmission electron microscopy, UV-visible NIP spectroscopy, X-ray diffraction (XRD), time-resolved fluorescence (TRF), photoluminescence spectroscopy (PL), and N-2 adsorption-desorption tests. XRD spectra of BiOCl-Cu2CoSnS4-TiO2 heterojunction show the diffraction peaks corresponding to tetragonal Cu2CoSnS4 nanoparticles and the tetragonal phase of BiOCl. The peaks of TiO2 are not viewed in the XRD pattern of BiOCl-Cu2CoSnS4-TiO2 nanocomposite which may be due to the presence of a low concentration of TiO2 in the composite. PL and time-resolved fluorescence confirm the separation of electron-hole pairs which could aggressively participate in the direct blue 71 dye degradation. The BiOCl-Cu2CoSnS4-TiO2-1 heterojunction degraded 91.48% direct blue 71 under natural sunlight which is higher than the bare BiOCl, Cu2CoSnS4 nanoparticles and TiO2 nanoparticles, and binary BiOCl-Cu2CoSnS4 composite. The electron-hole pair's separation leads to higher photoactivity driven by the heterojunction interface between BiOCl, Cu2CoSnS4 nanoparticles, and TiO2 nanoparticles. The photogenerated h(+), O-2(center dot-) and center dot OH radicals were responsible for the degradation of direct blue 71 over BiOCl-Cu2CoSnS4-TiO2 heterojunction as confirmed by the radical capture experiment.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Magnetically separable indium doped ZnS-NiFe2O4 heterostructure photocatalyst for mineralization of acid violet 7 dye

Ashok G. Shende, Sachin G. Ghugal, Devthade Vidyasagar, Suresh S. Umare, Sanjay B. Kokane, Rajamma Sasikala

MATERIALS CHEMISTRY AND PHYSICS (2019)

Article Materials Science, Ceramics

Synthesis and characterization of BiOCl-CoWO4 nanocomposites with improved photocatalytic activity

Arpita Paul Chowdhury, Baban H. Shambharkar

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY (2020)

Article Chemistry, Multidisciplinary

Europium Doped TiO2-Ta2O5 Heterostructure for Photodegradation of Dyes

Sachin G. Ghugal, Devthade Vidyasagar, Sandip G. Ghugal, Ashok G. Shende, Toshali Bhoyar, Suresh S. Umare

CHEMISTRYSELECT (2020)

Article Chemistry, Physical

Unveiling morphology altered photoactivity of microspherical carbon nitride scaffolds

Devthade Vidyasagar, Vinita Kumari, Toshali Bhoyar, Suresh S. Umare

APPLIED SURFACE SCIENCE (2020)

Article Materials Science, Multidisciplinary

Chlorophyllin sensitized carbon nitride scaffolds for photocatalytic application

Toshali Bhoyar, Devthade Vidyasagar, Suresh S. Umare

MATERIALS TODAY COMMUNICATIONS (2020)

Article Engineering, Mechanical

Production, structural and corrosion protection study of electroactive polyamide/alumina nanocomposites

Jitendra Chavhan, Ramesh Rathod, Jeetendra Kumar Malav, Suresh Umare

SURFACE TOPOGRAPHY-METROLOGY AND PROPERTIES (2020)

Article Chemistry, Multidisciplinary

Exciton Dissociation on Double Z-scheme Heterojunction for Photocatalytic Application

Ashok G. Shende, Toshali Bhoyar, Devthade Vidyasagar, Jaspreet Singh, Prakash T. Kosankar, Suresh S. Umare

Summary: Constructing heterojunction is a promising method to achieve enhanced photocatalysts. The Fe2O3-PrFeO3/g-C3N4 ternary heterostructure showed significantly improved photocatalytic degradation and ammonia generation under visible-light irradiation. The double Z-scheme heterojunction formed in the ternary structure plays a key role in facilitating interfacial electron transfer and promoting charge separation, leading to enhanced photocatalytic performance.

CHEMISTRYSELECT (2021)

Article Chemistry, Physical

Structural and physico-chemical properties of electroactive polyamide/multi-walled carbon nanotubes nanocomposites

Jitendra Chavhan, Ramesh Rathod, Vipin Tandon, Suresh Umare, Awanikumar Patil

Summary: Electroactive Polyamide/Multi-walled carbon nanotube nanocomposites were synthesized using in-situ oxidative coupling polymerization method, exhibiting increased roughness and hydrophobicity, decreased diffusion coefficient, and excellent anticorrosion properties.

SURFACES AND INTERFACES (2022)

Article Multidisciplinary Sciences

Accelerating NADH oxidation and hydrogen production with mid-gap states of nitrogen-rich carbon nitride photocatalyst

Toshali Bhoyar, Dong Jin Kim, B. Moses Abraham, Akanksha Gupta, Nagesh Maile, Nilesh R. Manwar, Surendar Tonda, Devthade Vidyasagar, Suresh S. Umare

Summary: This study demonstrates a sustainable strategy for the regeneration of NAD(+) as an electron carrier via photon-assisted heterogeneous catalysis. The use of NPCN as a photocatalyst shows excellent photooxidation efficiency of NADH and high hydrogen production rate, outperforming other metal-free photocatalysts.

ISCIENCE (2022)

Article Environmental Sciences

Mitigating phytotoxicity of tetracycline by metal-free 8-hydroxyquinoline functionalized carbon nitride photocatalyst

Toshali Bhoyar, Devthade Vidyasagar, Suresh S. Umare

Summary: This study found that the photooxidation of the common antibiotic tetracycline hydrochloride over a metal-free carbon nitride photocatalyst significantly reduces its phytotoxic effect, providing insights for the design of metal-free photocatalysts for environmental remediation.

JOURNAL OF ENVIRONMENTAL SCIENCES (2023)

Article Materials Science, Multidisciplinary

Highly efficient and recyclable quaternary Ag/Ag3PO4-BiOBr-C3N4 composite fabrication for efficient solar-driven photocatalytic performance for anionic pollutant in an aqueous medium and mechanism insights

Himadri Priya Gogoi, Gourab Bisoi, Pranjit Barman, Anurag Dehingia, Subhajit Das, Arpita Paul Chowdhury

Summary: A simple chemical precipitation method was used to synthesize a quaternary composite photocatalyst Ag/Ag3PO4-BiOBr-C3N4 with tuned band gap for enhanced photocatalytic performance. The as-prepared photocatalysts were characterized and evaluated for the degradation of reactive red (RR 120) under visible-light illumination. The Ag/Ag3PO4-BiOBr-C3N4 composite exhibited significantly higher degradation efficiency compared to pristine Ag/Ag3PO4, BiOBr, and C3N4 particles. The work has provided important guidance in designing photocatalysts with surface plasmon effect.

OPTICAL MATERIALS (2023)

Article Chemistry, Applied

Structural, physical, wear and anticorrosive properties of electroactive polyamide/Ti3C2Tx MXene nanocomposite

Jitendra Chavhan, Ramesh Rathod, Suresh Umare, Jay Desai, Sanjay Sapate, Yogesh Mahajan

Summary: The 2D few-layered Ti3C2Tx MXene nanosheets were prepared through etching and delamination of aluminium layers from the Ti3AlC2 MAX phase. The electroactive polyamide (EPA)/Ti3C2Tx MXene nanocomposites (NCs) containing various amounts of MXene were synthesized via in-situ oxidative coupling polymerization. The NCs showed improved physical properties such as electrical conductivity, thermal stability, and adhesion strength due to the close interaction between EPA and MXene. The addition of Ti3C2Tx MXene did not affect the surface roughness and water contact angle of the EPA matrix. The NCs coated samples exhibited improved tribological properties, and the corrosion study demonstrated excellent corrosion protection ability of EPA/Ti3C2Tx MXene NCs containing 1.2 wt% MXene.

PROGRESS IN ORGANIC COATINGS (2023)

Article Nanoscience & Nanotechnology

Nitrogen-Doped Graphitic Carbon Dots Embedded in Carbon Nitride Scaffolds for Water Decontamination

Toshali Bhoyar, Nishprah Saraswat, M. V. Jyothirmai, Akanksha Gupta, Sunita Kumari Malla, Jiyeon Park, Devthade Vidyasagar, Suresh S. Umare

Summary: Functionalized carbon dots (CDs) can donate or accept electrons depending on their functional groups and electrostatic characteristics. In this study, nitrogen doped graphitic carbon dots (N-g-CDs) were used to improve charge carrier separation in a polymeric carbon nitride (PCN) photocatalyst. The N-g-CDs/PCN hybrid catalyst showed enhanced photocatalytic activity for chromium reduction and degradation of tetracycline and rhodamine B dye.

ACS APPLIED NANO MATERIALS (2023)

Article Chemistry, Physical

BiOCl as the role of cleaner for the fabrication of self-cleaning PES membranes based on the RTIPS method

Wenjing Tan, Chunmei Gao, Shifeng Ji, Yunqing Xing, Yi Guo, Baogui Liang

Summary: Membrane separation technology is widely used in wastewater treatment due to its cost-effectiveness and productivity. However, organic membrane fouling caused by humic acid is a major barrier to its further development. This study successfully addressed this issue through the production of composite materials and self-cleaning membranes, providing beneficial strategies and solutions for membrane contamination problems.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Low-temperature plasma-induced porous Sb2WO6 microspheres with rich oxygen vacancies to promote high-performance photocatalytic activity

Qichang Peng, Qingdong Ruan, Bin Wang, Jinyuan Liu, Chao Huang, Xingwang Zhu, Dan Li, Liangliang Liu, Yinchuan Wang, Xiaolin Zhang, Jia Yan, Paul K. Chu, Hui Xu

Summary: The escalating issue of water pollution has led to significant attention in the field of photocatalysis. In this study, OV-Sb2WO6-X photocatalyst with oxygen vacancies was synthesized, which exhibited enhanced charge separation efficiency and improved photocatalytic activity. The introduction of oxygen vacancies was successfully controlled and characterized, and the modified photocatalyst showed superior degradation efficiency for dye wastewater treatment.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Preparation and application of self-emulsifying curing agent for CO2 high-pressure corrosion-resistant resin cement

Wangcheng Zhang, Cunchuan Zheng, Hu Xie, Weichao Du

Summary: By using a specific curing agent ETB, the problem of dispersion and stability for oily epoxy resin in cement slurry system has been successfully solved. The application of the emulsified curing agent ETB in oilfield cement slurry system shows good rheological performance, resistance to high temperature and high pressure water loss, and corrosion resistance.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

New approaches for regulation of structure and adsorption properties of biochar based on freshwater sediments (sapropels)

O. I. Krivonos, A. Babenko, O. B. Belskaya

Summary: This study synthesized biochar based on sapropel and investigated the effects of chemical modification on its textural characteristics, acid-base properties, and adsorption properties. The results showed that the chemical modification increased the fraction of micropores, specific surface area, and changed the surface properties of biochar. The experiment also revealed that biochar pretreated with alkali exhibited the maximum adsorption capacity for copper ions. A conceptual model identifying the mechanisms of copper adsorption on sapropel-based biosorbent was proposed.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Detailed experimental performance of two new pyrimidine-pyrazole derivatives as corrosion inhibitors for mild steel in HCl media combined with DFT/MDs simulations of bond breaking upon adsorption

H. Lachhab, N. Benzbiria, A. Titi, S. Echihi, M. E. Belghiti, Y. Karzazi, A. Zarrouk, R. Touzani, C. Jama, F. Bentiss

Summary: The corrosion inhibitory potency of two new pyrimidine-pyrazole derivatives, PPA and PPC, was evaluated for mild steel in 1 M HCl. The results showed enhanced inhibition activities with increased concentration, reaching maximal values of 91.15% and 92.39% for PPA and PPC, respectively. However, the mitigation potency decreased with increasing temperature. SEM and XPS analysis revealed that PPA and PPC adsorbed on the mild steel surface, forming a shielding layer that prevented the dissolution of the steel in the acidic solution.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Encapsulation of essential oil to prepare environment friendly nanobio-fungicide against Fusarium oxysporum f.sp. lycopersici: An experimental and molecular dynamics approach

Shanmugapriya Sivalingam, D. Jeya Sundara Sharmila, Goutham Golla, Lakshmanan Arunachalam, Tarunendu Singh, G. Karthikeyan, A. Shanthi, Kannan Malaichamy

Summary: This study aims to develop a nano-biofungicide comprising of volatile essential oil molecules to enhance its efficacy in the field of agriculture through easily scalable green synthesis technique. The nano biofungicide was prepared through one pot hot melt ultrasonication technique with easy water dispersibility and long term stability. The physico-chemical analysis revealed that, nano bio-fungicides were amorphous sphere-shaped nanoparticles with low melting point. The encapsulation efficiency of major components of essential oil was determined, and it was found that they followed Higuchi model of release kinetics. The essential oil loaded nanostructured lipid carrier showed significantly higher mycelial growth inhibition compared to pure essential oil, indicating enhanced bio-efficacy.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Waterborne epoxy composite coating with long-term corrosion resistance through synergy of MXene nanosheets and ZnO quantum dots

Yinlong Li, Yingqing Zhan, Yiwen Chen, Hongshan Jia, Ximin Chen, Fei Zhu, Xulin Yang

Summary: In this study, ZnO quantum dots decorated MXene nanosheets were used as a functional filler for waterborne epoxy coating. The improved dispersion and synergy of ZnO QDs and MXene nanosheets enhanced the anticorrosion performance of the coating.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Alginate-based aerogel fibers with a sheath-core structure for highly efficient methylene blue adsorption via directed freezing wet-spinning

Fucheng Guan, Jing Tao, Qiang Yao, Zheng Li, Yihang Zhang, Shi Feng, Jianbin Sun, Qiang Yang, Xuecui Song, Jing Guo, Yuanfa Liu

Summary: This paper presents a method for preparing adsorbent materials based on biomass that can efficiently adsorb methylene blue. The experimental results show that the material has a hierarchical structure, high adsorption capacity, and reusability.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

In-situ study on the heterocoagulation between fine coal particles and coarse glass beads by the particle vision and measurement (PVM) techniques

Pengfei Hu, Zuli Mo, Weiliang Wang, Chengzhe Li, Zhaojia Guo, Guanqing Lin, Zhimin Guo

Summary: This study developed a novel in-situ particle vision and measurement (PVM) system to investigate heterocoagulation between coarse and fine particles in mineral processing. The experimental results showed that the degree of heterocoagulation decreased with increasing pH and stirring speed. Furthermore, under certain hydrodynamic conditions, coal particles were more distributed at the rear of the glass bead.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Label-free immunosensor for detection of hepatitis C (HCV) core antigen using ternary polypyrrole-Ag doped ZnO-exfoliated graphene nanocomposite

Tanveer ul Haq Zia, Anwar ul Haq Ali Shah, Behisht Ara, Kashif Gul

Summary: A label-free immunosensor for detection of hepatitis C core antigen was fabricated using a ternary nanocomposite based on polypyrrole, silver doped zinc oxide, and exfoliated graphene. The immunosensor demonstrated low detection limit, high selectivity, and stability.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Zwitterionic polymers as high-performance coatings for hemoperfusion adsorbents and their chemisorption of protein-bound toxins through computational simulations

Xiaoyan Feng, Jiachen Li, Lijun Liang, Linli Zhu, Sa Liu, Li Ren

Summary: In this study, polystyrene divinylbenzene microspheres were surface-modified by poly(carboxybetaine methacrylate) to develop an efficient hemoperfusion adsorbent for the removal of protein-bound toxins. The modified microspheres showed increased adsorption capacity and better biocompatibility, making them promising for clinical hemoperfusion therapy.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

A flexible high-efficiency approach to preparing a durable flame-retardant cellulosic fabric as well as the research of the property

Xiaoye Bi, Dong Xue, Yunpeng Wang, Chencheng Lv, Zexiong Li, Tao Zhao

Summary: This research aimed to develop a durable and formaldehyde-free flame retardant treatment for cotton fabrics. The results demonstrated successful grafting of phosphorous acid (PA) onto cotton fabrics, leading to enhanced flame resistance while maintaining the desired fabric characteristics.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Inhibiting mechanisms and applications of novel Al-starch for ultrafine gangue minerals based on experimental and computational study

Ruolin Wang, Wenjuan Sun, Haisheng Han, Dongping Tao

Summary: This study finds that Al-starch colloidal depressants can effectively inhibit the flotation of ultrafine calcite and chlorite, and increase the grade of valuable minerals. The chemisorption of Al-starch on mineral surface changes the functional group peaks and generates new O-Al functional groups.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Tuneable functionalized biochar for simultaneous removal of pharmaceuticals from binary mixture

Wondimu K. Wakejo, Ali Maged, Beteley T. Meshesha, Joon W. Kang, Abayneh G. Demesa, Sandip Chakrabarti, Thallada Bhaskar, Ashok Kumar Gupta, Amit Bhatnagar

Summary: Simultaneously removing different pharmaceutical pollutants from wastewater is an important environmental issue, and the use of a system that can remove multiple contaminants at once is necessary. Functionalized biochar (FBC) has been found to be effective in simultaneously removing acetaminophen and ciprofloxacin and other pharmaceutical pollutants.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)

Article Chemistry, Physical

Full utilization of Cu single atoms on carbon nitride nanofibers for enhanced Fenton-like degradation of methylene blue

Yu Wang, Fengwen Yan, Jie Wu, Zhijun Huang, Liuting Song, Shunda Yuan

Summary: In this study, Cu single atoms are anchored on the external surface of g-C3N4 nanofibers to maximize atom utilization. This catalyst exhibits excellent Fenton-like catalytic activity and good stability due to the full utilization of Cu active sites.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2024)