Single-Atom Catalysis: Insights from Model Systems

Highly Stable and Reactive Platinum Single Atoms on Oxygen Plasma‐Functionalized CeO 2 Surfaces: Nanostructuring and Peroxo Effects

(2022) Weiming Wan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Adatom and Nanoparticle Dynamics on Single-Atom Catalyst Substrates

(2022) Matteo Farnesi Camellone et al.   ACS Catalysis

CO oxidation by Pt 2 /Fe 3 O 4 : Metastable dimer and support configurations facilitate lattice oxygen extraction

(2022) Matthias Meier et al.   Science Advances

Role of Polarons in Single-Atom Catalysts: Case Study of Me1 [Au1, Pt1, and Rh1] on TiO2(110)

(2022) Panukorn Sombut et al.   TOPICS IN CATALYSIS

Unraveling CO adsorption on model single-atom catalysts

(2021) Jan Hulva et al.   SCIENCE

Directly Probing the Local Coordination, Charge State, and Stability of Single Atom Catalysts by Advanced Electron Microscopy: A Review

(2021) Peter Tieu et al.   Small

Surface Reduction State Determines Stabilization and Incorporation of Rh on α‐Fe 2 O 3 (11¯02)

(2021) Florian Kraushofer et al.   Advanced Materials Interfaces

Polarons in materials

(2021) Cesare Franchini et al.   Nature Reviews Materials

Catalytic CO Oxidation on MgAl2O4-Supported Iridium Single Atoms: Ligand Configuration and Site Geometry

(2021) Jiamin Wang et al.   Journal of Physical Chemistry C

Interplay between invasive single atom Pt and native oxygen vacancy in rutile TiO2(110) surface: A theoretical study

(2021) Xiaoyang Wang et al.   Nano Research

First-principles design of a single-atom–alloy propane dehydrogenation catalyst

(2021) Ryan T. Hannagan et al.   SCIENCE

A DFT+U study about agglomeration of Au atoms on reduced surface of rutile TiO2 (110)

(2021) Lei Li et al.   MATERIALS CHEMISTRY AND PHYSICS

Vibrational Properties of CO Adsorbed on Au Single Atom Catalysts on TiO2(101), ZrO2(101), CeO2(111), and LaFeO3(001) Surfaces: A DFT Study

(2021) Ho Viet Thang et al.   TOPICS IN CATALYSIS

Single Rh Adatoms Stabilized on α-Fe2O3(11̅02) by Coadsorbed Water

(2021) Florian Kraushofer et al.   ACS Energy Letters

Heterogeneous Single Atom Electrocatalysis, Where “Singles” Are “Married”

(2020) Wenjie Zang et al.   Advanced Energy Materials

Dual Metal Active Sites in an Ir 1 /FeO x Single‐Atom Catalyst: A Redox Mechanism for the Water‐Gas Shift Reaction

(2020) Jin‐Xia Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications

(2020) Chao Gao et al.   CHEMICAL REVIEWS

Surface Reactivity of Ag-Modified Ceria to Hydrogen: A Combined Experimental and Theoretical Investigation

(2020) Stefania Benedetti et al.   ACS Applied Materials & Interfaces

Single-Atom Alloy Catalysis

(2020) Ryan T. Hannagan et al.   CHEMICAL REVIEWS

Growth and Atomic‐Scale Characterization of Ultrathin Silica and Germania Films: The Crucial Role of the Metal Support

(2020) Adrian Leandro Lewandowski et al.   CHEMISTRY-A EUROPEAN JOURNAL

Interaction of CO and O2 with supported Pt single-atoms on TiO2(110)

(2020) Shi-hui Dong et al.   CHINESE JOURNAL OF CHEMICAL PHYSICS

Recent Developments on the Single Atom Supported at 2D Materials Beyond Graphene as Catalysts

(2020) Rui Gusmão et al.   ACS Catalysis

Single-Atom Catalysts across the Periodic Table

(2020) Selina K. Kaiser et al.   CHEMICAL REVIEWS

Bonding Properties of Isolated Metal Atoms on Two-Dimensional Oxides

(2020) Sergio Tosoni et al.   Journal of Physical Chemistry C

Tracking the formation, fate and consequence for catalytic activity of Pt single sites on CeO2

(2020) Florian Maurer et al.   Nature Catalysis

Partially Dissociated Water Dimers at the Water–Hematite Interface

(2019) Zdenek Jakub et al.   ACS Energy Letters

In Situ/Operando Techniques for Characterization of Single-Atom Catalysts

(2019) Xuning Li et al.   ACS Catalysis

Reducibility of Ag- and Cu-modified Ultrathin Epitaxial Cerium Oxide Films

(2019) Gabriele Gasperi et al.   Journal of Physical Chemistry C

Identification of Two-dimensional FeO2 Termination of Bulk Hematite ɑ-Fe2O3(0001) Surface

(2019) Jesús Redondo et al.   Journal of Physical Chemistry C

Structural evolution of atomically dispersed Pt catalysts dictates reactivity

(2019) Leo DeRita et al.   NATURE MATERIALS

Local Structure and Coordination Define Adsorption in a Model Ir₁/Fe₃O₄ Single-Atom Catalyst

(2019) Zdenek Jakub et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoresponses of Supported Au Single Atoms on TiO2(110) through the Metal-Induced Gap States

(2019) Shihui Dong et al.   Journal of Physical Chemistry Letters

Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts

(2019) Nathan Daelman et al.   NATURE MATERIALS

Understanding Heterolytic H2 Cleavage and Water-Assisted Hydrogen Spillover on Fe3O4(001)-Supported Single Palladium Atoms

(2019) Nassar Doudin et al.   ACS Catalysis

High-Density Isolated Fe1O3 Sites on a Single-Crystal Cu2O(100) Surface

(2019) Chunlei Wang et al.   Journal of Physical Chemistry Letters

Rh single atoms on TiO2 dynamically respond to reaction conditions by adapting their site

(2019) Yan Tang et al.   Nature Communications

Low-Temperature Oxidation of Methanol to Formaldehyde on a Model Single-Atom Catalyst: Pd Atoms on Fe3O4(001)

(2019) Matthew D. Marcinkowski et al.   ACS Catalysis

Importance of Size and Contact Structure of Gold Nanoparticles for the Genesis of Unique Catalytic Processes

(2019) Tamao Ishida et al.   CHEMICAL REVIEWS

The role of H2 on the stability of the single-metal-site Ir1/AC catalyst for heterogeneous methanol carbonylation

(2019) Siquan Feng et al.   JOURNAL OF CATALYSIS

Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles

(2018) Lichen Liu et al.   CHEMICAL REVIEWS

Water activation by single Pt atoms supported on a Cu 2 O thin film

(2018) Andrew J. Therrien et al.   JOURNAL OF CATALYSIS

Diffusion Kinetics of Gold and Copper Atoms on Pristine and Reduced Rutile TiO2 (110) Surfaces

(2018) Mathilde Iachella et al.   Journal of Physical Chemistry C

Atomic-Scale Structure of the Hematite α-Fe2O3(11̅02) “R-Cut” Surface

(2018) Florian Kraushofer et al.   Journal of Physical Chemistry C

The Surface Structure of Cu2O(100): Nature of Defects

(2018) Heloise Tissot et al.   Journal of Physical Chemistry C

A systematic theoretical study on FeOx-supported single-atom catalysts: M1/FeOx for CO oxidation

(2018) Jinxia Liang et al.   Nano Research

Probing the geometry of copper and silver adatoms on magnetite: quantitative experiment versus theory

(2018) Matthias Meier et al.   Nanoscale

Stability investigation of a high number density Pt1/Fe2O3 single-atom catalyst under different gas environments by HAADF-STEM

(2018) Sibin Duan et al.   NANOTECHNOLOGY

Structural and optical properties of Ni atoms and Ni55 cluster adsorbed on a rutile TiO2 (110) surface

(2018) José M. Castillo-Robles et al.   THEORETICAL CHEMISTRY ACCOUNTS

Heterogeneous single-atom catalysis

(2018) Aiqin Wang et al.   Nature Reviews Chemistry

Reactivity of Single-Atom Heterogeneous Catalysts: Unique and Multifaceted

(2018) Sharon Mitchell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Premodified Surface Method to Obtain Ultra-highly Dispersed Metals and their 3D Structure Control on an Oxide Single-crystal Surface

(2018) Satoru Takakusagi et al.   CHEMICAL RECORD

Surface organometallic chemistry in heterogeneous catalysis

(2018) Manoja K. Samantaray et al.   CHEMICAL SOCIETY REVIEWS

Nature of stable single atom Pt catalysts dispersed on anatase TiO2

(2018) Ho Viet Thang et al.   JOURNAL OF CATALYSIS

Gold-Decorated Biphase α-Fe2O3(0001): Activation by CO-Induced Surface Reduction

(2018) Hengshan Qiu et al.   Journal of Physical Chemistry C

Direct Visualization of Au Atoms Bound to TiO2(110) O-Vacancies

(2017) Andrew Mellor et al.   Journal of Physical Chemistry C

Formaldehyde Adsorption on the Anatase TiO2(101) Surface: Experimental and Theoretical Investigation

(2017) Martin Setvin et al.   Journal of Physical Chemistry C

Catalyst Architecture for Stable Single Atom Dispersion Enables Site-Specific Spectroscopic and Reactivity Measurements of CO Adsorbed to Pt Atoms, Oxidized Pt Clusters, and Metallic Pt Clusters on TiO2

(2017) Leo DeRita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The local electronic properties of individual Pt atoms adsorbed on TiO2(110) studied by Kelvin probe force microscopy and first-principles simulations

(2017) Ayhan Yurtsever et al.   Nanoscale

Two-dimensional silica opens new perspectives

(2017) Christin Büchner et al.   PROGRESS IN SURFACE SCIENCE

Activation of surface lattice oxygen in single-atom Pt/CeO2for low-temperature CO oxidation

(2017) Lei Nie et al.   SCIENCE

Single-Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis

(2017) Huabin Zhang et al.   Advanced Energy Materials

Oxide-based nanomaterials for fuel cell catalysis: the interplay between supported single Pt atoms and particles

(2017) Yaroslava Lykhach et al.   Catalysis Science & Technology

Polaron-Driven Surface Reconstructions

(2017) Michele Reticcioli et al.   Physical Review X

Redox-mediated conversion of atomically dispersed platinum to sub-nanometer particles

(2017) Yaroslava Lykhach et al.   Journal of Materials Chemistry A

DFT + U investigation on the adsorption and initial decomposition of methylamine by a Pt single-atom catalyst supported on rutile (110) TiO 2

(2016) Cun-Qin Lv et al.   APPLIED SURFACE SCIENCE

Reduction of Pt 2+ species in model Pt–CeO 2 fuel cell catalysts upon reaction with methanol

(2016) Armin Neitzel et al.   APPLIED SURFACE SCIENCE

Nanoscale Patterns on Polar Oxide Surfaces

(2016) Mikołaj Lewandowski et al.   CHEMISTRY OF MATERIALS

Co on Fe3O4(001): Towards precise control of surface properties

(2016) Raquel Gargallo-Caballero et al.   JOURNAL OF CHEMICAL PHYSICS

Experimental and Theoretical Study on the Electronic Interaction between Rh Adatoms and CeOx Substrate in Dependence on a Degree of Cerium Oxide Reduction

(2016) Klára Ševčíková et al.   Journal of Physical Chemistry C

A New Indicator for Single Metal Dispersion on a TiO2(110) Surface Premodified with a Mercapto Compound

(2016) Satoru Takakusagi et al.   Journal of Physical Chemistry C

Atomically Dispersed Pd, Ni, and Pt Species in Ceria-Based Catalysts: Principal Differences in Stability and Reactivity

(2016) Armin Neitzel et al.   Journal of Physical Chemistry C

Adsorption sites of single noble metal atoms on the rutile TiO2(1 1 0) surface influenced by different surface oxygen vacancies

(2016) Katsuyuki Matsunaga et al.   JOURNAL OF PHYSICS-CONDENSED MATTER

Reactivity of atomically dispersed Pt2+ species towards H2: model Pt–CeO2 fuel cell catalyst

(2016) Yaroslava Lykhach et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Diffusion Barriers Block Defect Occupation on ReducedCeO2(111)

(2016) P. G. Lustemberg et al.   PHYSICAL REVIEW LETTERS

Dual role of CO in the stability of subnano Pt clusters at the Fe3O4(001) surface

(2016) Roland Bliem et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Atomic structure and stability of magnetite Fe 3 O 4 (001): An X-ray view

(2016) Björn Arndt et al.   SURFACE SCIENCE

Iron oxide surfaces

(2016) Gareth S. Parkinson   SURFACE SCIENCE REPORTS

Creating single-atom Pt-ceria catalysts by surface step decoration

(2016) Filip Dvořák et al.   Nature Communications

Catalysis by Supported Single Metal Atoms

(2016) Jingyue Liu   ACS Catalysis

Towards stable single-atom catalysts: strong binding of atomically dispersed transition metals on the surface of nanostructured ceria

(2016) Alberto Figueroba et al.   Catalysis Science & Technology

The Power of Single-Atom Catalysis

(2015) Suxia Liang et al.   ChemCatChem

Little do more: a highly effective Pt1/FeOx single-atom catalyst for the reduction of NO by H2

(2015) Jian Lin et al.   CHEMICAL COMMUNICATIONS

Ag Nanoparticles on Reducible CeO2(111) Thin Films: Effect of Thickness and Stoichiometry of Ceria

(2015) Shanwei Hu et al.   Journal of Physical Chemistry C

Energetics of Cu Adsorption and Adhesion onto Reduced CeO2(111) Surfaces by Calorimetry

(2015) Trevor E. James et al.   Journal of Physical Chemistry C

A Multitechnique Study of CO Adsorption on the TiO2 Anatase (101) Surface

(2015) Martin Setvin et al.   Journal of Physical Chemistry C

Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials

(2015) Andrea Zitolo et al.   NATURE MATERIALS

Pt atoms adsorbed onTiO2(110)−(1×1)studied with noncontact atomic force microscopy and first-principles simulations

(2015) Delia Fernández-Torre et al.   PHYSICAL REVIEW B

Adsorption and incorporation of transition metals at the magnetiteFe3O4(001) surface

(2015) Roland Bliem et al.   PHYSICAL REVIEW B

Characterization of O−-Centers on Single Crystalline MgO(001)-Films

(2015) A. Gonchar et al.   TOPICS IN CATALYSIS

Dynamic formation of single-atom catalytic active sites on ceria-supported gold nanoparticles

(2015) Yang-Gang Wang et al.   Nature Communications

Highly Efficient Catalysis of Preferential Oxidation of CO in H2-Rich Stream by Gold Single-Atom Catalysts

(2015) Botao Qiao et al.   ACS Catalysis

Cluster Nucleation and Growth from a Highly Supersaturated Adatom Phase: Silver on Magnetite

(2014) Roland Bliem et al.   ACS Nano

Maximum Noble-Metal Efficiency in Catalytic Materials: Atomically Dispersed Surface Platinum

(2014) Albert Bruix et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleation and growth of Pt nanoparticles on reduced and oxidized rutile TiO2 (110)

(2014) F. Rieboldt et al.   JOURNAL OF CHEMICAL PHYSICS

Adsorption of Au and Pd on Ruthenium-Supported Bilayer Silica

(2014) Christin Büchner et al.   Journal of Physical Chemistry C

Surface sites on Pt–CeO2mixed oxide catalysts probed by CO adsorption: a synchrotron radiation photoelectron spectroscopy study

(2014) Armin Neitzel et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Order-disorder phase transition on the (100) surface of magnetite

(2014) Norman C. Bartelt et al.   PHYSICAL REVIEW B

Subsurface cation vacancy stabilization of the magnetite (001) surface

(2014) R. Bliem et al.   SCIENCE

Surface preparation of TiO2 anatase (101): Pitfalls and how to avoid them

(2014) Martin Setvín et al.   SURFACE SCIENCE

Exploration of High-Performance Single-Atom Catalysts on Support M1/FeOx for CO Oxidation via Computational Study

(2014) Fengyu Li et al.   ACS Catalysis

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis

(2013) Xiao-Feng Yang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Gold Adsorption on CeO2 Thin Films Grown on Ru(0001)

(2013) Yi Pan et al.   Journal of Physical Chemistry C

Understanding the Nucleation and Growth of Metals on TiO2: Co Compared to Au, Ni, and Pt

(2013) Randima P. Galhenage et al.   Journal of Physical Chemistry C

Characterisation of paramagnetic Mo impurities on MgO(100) single-crystalline films grown on Mo(100)

(2013) A. Gonchar et al.   MOLECULAR PHYSICS

Direct Imaging of Pt Single Atoms Adsorbed on TiO2 (110) Surfaces

(2013) Teng-Yuan Chang et al.   NANO LETTERS

Carbon monoxide-induced adatom sintering in a Pd–Fe3O4 model catalyst

(2013) Gareth S. Parkinson et al.   NATURE MATERIALS

Titration ofCe3+Ions in theCeO2(111)Surface by Au Adatoms

(2013) Yi Pan et al.   PHYSICAL REVIEW LETTERS

Reaction of O2 with Subsurface Oxygen Vacancies on TiO2 Anatase (101)

(2013) M. Setvin et al.   SCIENCE

Copper-ceria interaction: A combined photoemission and DFT study

(2012) Lucie Szabová et al.   APPLIED SURFACE SCIENCE

Preparation and structure of a single Au atom on the TiO2(110) surface: control of the Au–metal oxide surface interaction

(2012) Kiyotaka Asakura et al.   FARADAY DISCUSSIONS

Environmentally dependent stability of low-index hematite surfaces

(2012) Haibo Guo et al.   JOURNAL OF COLLOID AND INTERFACE SCIENCE

Interactions of Ni Nanoparticles with Reducible CeO2(111) Thin Films

(2012) Yinghui Zhou et al.   Journal of Physical Chemistry C

Ordered Array of Single Adatoms with Remarkable Thermal Stability:Au/Fe3O4(001)

(2012) Zbyněk Novotný et al.   PHYSICAL REVIEW LETTERS

(Sub)Surface Mobility of Oxygen Vacancies at theTiO2Anatase (101) Surface

(2012) Philipp Scheiber et al.   PHYSICAL REVIEW LETTERS

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations

(2012) Georgios Kyriakou et al.   SCIENCE

The reduction and oxidation of Fe2O3(0001) surface investigated by scanning tunneling microscopy

(2012) Yuanyuan Tang et al.   SURFACE SCIENCE

Formation of One-Dimensional Electronic States along the Step Edges of CeO2(111)

(2011) Niklas Nilius et al.   ACS Nano

Tailoring the Shape of Metal Ad-Particles by Doping the Oxide Support

(2011) Xiang Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Initial Formation of Positively Charged Gold on MgO(001) Thin Films: Identification by Experiment and Structural Assignment by Theory

(2011) Matthew A. Brown et al.   Journal of Physical Chemistry C

Growth, Structure, and Stability of Ag on CeO2(111): Synchrotron Radiation Photoemission Studies

(2011) Dandan Kong et al.   Journal of Physical Chemistry C

Nature of Ag Islands and Nanoparticles on the CeO2(111) Surface

(2011) Paola Luches et al.   Journal of Physical Chemistry C

Theoretical Studies of the Stability and Oxidation of Pdn (n = 1–7) Clusters on Rutile TiO2(110): Adsorption on the Stoichiometric Surface

(2011) S. Vincent Ong et al.   Journal of Physical Chemistry C

Single-atom catalysis of CO oxidation using Pt1/FeO x

(2011) Botao Qiao et al.   Nature Chemistry

Direct Measurement of the Attractive Interaction Forces on F0 Color Centers on MgO(001) by Dynamic Force Microscopy

(2010) Thomas König et al.   ACS Nano

Formation of alumina–ceria mixed oxide in model systems

(2010) Tomáš Skála et al.   APPLIED SURFACE SCIENCE

Ag Adsorption on Reduced CeO2(111) Thin Films

(2010) Jason A. Farmer et al.   Journal of Physical Chemistry C

Enhanced Bonding of Silver Nanoparticles on Oxidized TiO2(110)

(2010) Jonas Ø. Hansen et al.   Journal of Physical Chemistry C

Geometric structure ofTiO2(110)(1×1): Confirming experimental conclusions

(2010) W. Busayaporn et al.   PHYSICAL REVIEW B

Thermally-driven processes on rutile TiO2(110)-(1×1): A direct view at the atomic scale

(2010) Zdenek Dohnálek et al.   PROGRESS IN SURFACE SCIENCE

On the difficulties of present theoretical models to predict the oxidation state of atomic Au adsorbed on regular sites of CeO[sub 2](111)

(2009) María Marta Branda et al.   JOURNAL OF CHEMICAL PHYSICS

Interaction of Gold with Cerium Oxide Supports: CeO2(111) Thin Films vs CeOx Nanoparticles

(2009) M. Baron et al.   Journal of Physical Chemistry C

Modifying the Adsorption Characteristic of Inert Silica Films by Inserting Anchoring Sites

(2009) Stefan Ulrich et al.   PHYSICAL REVIEW LETTERS

Morphology of step structures on CeO2(111)

(2008) Stefan Torbrügge et al.   APPLIED PHYSICS LETTERS

A photoemission study of the interaction of Ga with CeO2(111) thin films

(2008) Tomáš Skála et al.   APPLIED SURFACE SCIENCE

Chemical reactions on rutile TiO2(110)

(2008) Chi Lun Pang et al.   CHEMICAL SOCIETY REVIEWS

Structure of gold atoms on stoichiometric and defective ceria surfaces

(2008) Changjun Zhang et al.   JOURNAL OF CHEMICAL PHYSICS

Cerium oxide stoichiometry alteration via Sn deposition: Influence of temperature

(2008) Tomáš Skála et al.   JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA

Growth and Characterization of Rh and Pd Nanoparticles on Oxidized and Reduced CeOx(111) Thin Films by Scanning Tunneling Microscopy

(2008) Jing Zhou et al.   Journal of Physical Chemistry C

Small Au and Pt Clusters at the Anatase TiO2(101) Surface:  Behavior at Terraces, Steps, and Surface Oxygen Vacancies

(2007) Xue-Qing Gong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY