Review
Chemistry, Inorganic & Nuclear
Yujie Zhang, Francisco de Azambuja, Tatjana N. Parac-Vogt
Summary: Group (IV) metal oxo clusters are a diverse class of compounds with unique structural stability, reactivity and electronic properties. Despite their potential applications in catalysis, materials chemistry, electronics and optics, gaps in fundamental understanding about their structure, intrinsic features, and nuances in their synthesis hinder their full exploration. Through a critical overview of the chemistry of discrete zirconium, hafnium, and titanium metal oxo clusters reported in the literature, important insights on their properties, reactivity, and potential applications have been provided.
COORDINATION CHEMISTRY REVIEWS
(2021)
Article
Engineering, Environmental
Chiao-Wen Chien, Namasivayam Dhenadhayalan, King-Chuen Lin
Summary: Zirconium dioxide-incorporated bismuth sulfide (Bi2S3/ZrO2) and bismuth tungstate (Bi2WO6/ZrO2) heteronanostructures were synthesized and used as photocatalysts for the visible light-driven degradation of chloramphenicol. Both heteronanostructures exhibited excellent catalytic activity, and the degradation rate was greatly enhanced when peroxymonosulfate was used as an activator. The generation and separation of photoinduced charge carriers played a crucial role in the improved catalytic activity. These inorganic heteronanostructures have great potential in the field of contaminated water remediation and provide a platform for the fabrication of photocatalyst materials.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Tatsuya Fujii, Takashi Nakamura, Shin-ichiro Kawasaki
Summary: In this study, the effects of temperature, simultaneous modification, and precursors on the solvothermal synthesis of organic-modified nano-sized zirconia particles were investigated. The results showed that the formation of nanoparticles was faster under lower temperature conditions, and the size of zirconia could be controlled by modifying the chemical structure on the surface of the nanoparticles.
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
(2022)
Article
Energy & Fuels
Nagaraju Pasupulety, Abdurahim A. Al-zahrani, Muhammad A. Daous, Hafedh Driss, Hesham Alhumade
Summary: Mesoporous tantalum-zirconium oxide (TZ) solid acid catalysts were synthesized and employed for biodiesel production from higher water and palmitic acid added oil feedstocks. The results showed that the yield of methyl palmitate and soybean oil fatty acid methyl ester (FAME) was significantly improved with the addition of tantalum to ZrO2. The high ester yield on TZ catalysts was attributed to the improved acidity and interaction between the catalyst and methanol and triglycerides.
Article
Chemistry, Multidisciplinary
Chengkai Xia, Heng Wang, Jung Kyu Kim, Jingyu Wang
Summary: The research focuses on the rational design of metal oxide heterostructures to enhance photo-to-chemical energy conversion efficiency using photocatalytic and photoelectrochemical systems. Strategies to improve conversion efficiency include surface modification, surface regulation, and interfacial assembly with various materials. The underlying reaction mechanisms and challenges in developing metal oxide-based heterostructures for photo-to-chemical devices are also discussed.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Masoud Emami Mehr, Hossein Maleki-Ghaleh, Mohadeseh Yarahmadi, Majid Kavanlouei, M. Hossein Siadati
Summary: In this study, core/shell ZnO/TiO2 nanocomposite samples were prepared using the sol-gel method at different time spans. The sample prepared in the 15-minute time span (ZnTi15) exhibited the highest photocatalytic activity and charge carrier density, making it the optimal sample. The formation of a heterojunction at the ZnO/TiO2 interface could be attributed to the increased photocurrent density observed for the ZnTi15 sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Zuoyan Chen, Xuechang Ren, Linhai Yang, Ning Fu, Xingcai An
Summary: The microstructure of TiO2 hollow microspheres has a significant impact on the photocatalytic activity. The researchers propose a self-template synthesis strategy to prepare hollow TiO2 hydrate microspheres with different sizes and structures, by controlling the H2O/TBOT molar ratio in the synthesis process.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Yingdi Ma, Yanli Liu
Summary: In this study, a composite photocatalyst of rGO-ZnO was prepared and characterized. The results showed that the rGO-ZnO composites exhibited significantly enhanced photocatalytic activity in the degradation of methyl orange, which was attributed to the high specific surface area and conductivity of rGO, facilitating efficient charge separation in the rGO-ZnO nanocomposite.
Article
Chemistry, Physical
Shiwei Ma, Yunyun Huang, Ruoyu Hong, Xuesong Lu, Jianhua Li, Ying Zheng
Summary: The study focused on modifying zinc oxide (ZnO) nanoparticles using argon and hydrogen plasma, resulting in improved catalytic degradation performance on Rhodamine B. The treated ZnO exhibited significantly enhanced photocatalytic activity and stable reaction performance.
Article
Chemistry, Inorganic & Nuclear
Nabil Al-Zaqri, A. Muthuvel, M. Jothibas, Ali Alsalme, Fahad A. Alharthi, V. Mohana
Summary: The biosynthesis of ZrO2-NPs showed efficient photocatalytic and antibacterial activities, making it a promising alternative method for chemical synthesis systems.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Thieu Quang Quoc Viet, Vu Hoang Khoi, Nguyen Thi Huong Giang, Hoang Thi Van Anh, Nguyen Minh Dat, Mai Thanh Phong, Nguyen Huu Hieu
Summary: Zinc oxide and titanium dioxide co-doped reduced graphene was synthesized for effective treatment of methylene blue solution. The optimal conditions resulted in a high efficiency of MB treatment and significant potential for dye treatment in industrial effluent. The synthesized materials followed pseudo-second-order kinetics for MB adsorption and pseudo-first-order kinetics for MB photocatalytic degradation process.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Crystallography
Ewa Wierzbicka, Karolina Syrek, Klaudia Maczka, Grzegorz D. Sulka
Summary: High surface area, self-organized nanoporous ZrO2 arrays with perfect adhesion to Zr substrate were synthesized by anodization in an aqueous electrolyte. The obtained semiconductor materials were tested as photocatalysts for decolorization of methyl red. The photocatalytic efficiency could be improved by annealing at a relatively low temperature of 350 degrees C, but higher annealing temperatures caused a gradual drop in activity.
Article
Biochemistry & Molecular Biology
Sanjay S. Majani, Meghana, S. H. Sowmyashree, J. Sowjanyashree, Sahaja Umesh, Chandan Shivamallu, Muzaffar Iqbal, Raghavendra G. Amachawadi, K. N. Venkatachalaiah, Shiva Prasad Kollur
Summary: The present work describes the fabrication of Barium Lanthanum Oxide nanosheets via a simple precipitation method. The nanosheets exhibit an orthorhombic crystal system with an average crystallite size of 27 nm. They possess strong absorption and fluorescence properties, and demonstrate potential applications in fingerprint detection and dye degradation.
Article
Chemistry, Physical
C. Gomez-Polo, S. Larumbe, A. Gil, D. Munoz, L. Rodriguez Fernandez, L. Fernandez Barquin, A. Garcia-Prieto, M. L. Fdez-Gubieda, A. Muela
Summary: The study investigates the effects of Cr and N doping on the properties of TiO2 anatase nanoparticles, including adsorption capacity, photocatalytic performance, and antibacterial response. Doping with Cr and Cr/N enhances adsorption capacity and photocatalytic performance, with Cr-TiO2 nanoparticles exhibiting antibacterial activity under visible light. The differences in electrostatic charge and nanoparticle dispersion are suggested as the main reasons for the varied antibacterial response among the doped nanoparticles.
SURFACES AND INTERFACES
(2021)
Article
Materials Science, Multidisciplinary
F. Theska, R. F. Webster, S. R. Street, M. Lison-Pick, S. Primig
Summary: Polycrystalline superalloys are high-performance materials with complex microstructures that can be affected by micro-alloying elements such as B, C, or Zr. The addition of Zr can impact the morphology and dispersion of C16-M2B borides in the alloy.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Applied
E. I. Yanushevskaya, V. I. Suprunchuk, E. V. Ivanyuk
JOURNAL OF WATER CHEMISTRY AND TECHNOLOGY
(2016)
Article
Nanoscience & Nanotechnology
Tetiana A. Dontsova, Elena I. Yanushevskaya, Svitlana V. Nahirniak, Oksana V. Makarchuk, Andrei I. Ivanets, Marina Yu Roshchina, Anastasiya S. Kutuzova, Leonid M. Kulikov
JOURNAL OF NANOMATERIALS
(2018)
Article
Chemistry, Multidisciplinary
N. V. Vlasenko, P. I. Kyriienko, K. V. Valihura, O. I. Yanushevska, S. O. Soloviev, P. E. Strizhak
THEORETICAL AND EXPERIMENTAL CHEMISTRY
(2019)
Article
Chemistry, Physical
Nina V. Vlasenko, Pavlo I. Kyriienko, Olena I. Yanushevska, Karina V. Valihura, Sergii O. Soloviev, Peter E. Strizhak
Article
Chemistry, Physical
O. I. Yanushevska, T. A. Dontsova, A. I. Aleksyk, N. V. Vlasenko, O. Z. Didenko, A. S. Nypadymka
CLAYS AND CLAY MINERALS
(2020)
Article
Chemistry, Multidisciplinary
Tetiana A. Dontsova, Olena I. Yanushevska, Svitlana V. Nahirniak, Anastasiya S. Kutuzova, Grigory V. Krymets, Petro S. Smertenko
Summary: This article focuses on the creation of TiO2/ZnO nanocomposites by modifying a commercial TiO2/P90 product using the impregnation method, and examines the effects of the ZnO modifier on its properties. The synthesized nanocomposites have a homogeneous mesoporous structure, and their adsorption and photocatalytic properties depend on the specific surface area and electrostatic interaction with dyes. Additionally, the ZnO modifier affects the types of current carriers in the nanocomposites.
JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Nina V. Vlasenko, Olena I. Yanushevska, Olga Z. Didenko, Peter E. Strizhak
Summary: The possibility of using sulfated and carbon nanotube modified titania as catalysts for glycerol oligomerization has been investigated. It was found that the sulfated titania samples showed high activity in glycerol conversion, while the addition of carbon nanotubes reduced the conversion and yield but increased the selectivity for short-chain glycerides.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)