期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 301, 期 -, 页码 56-64出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2015.08.031
关键词
Graphene; gamma-MnO2; 4-Nitrophenol; Catalytic ozonation; Peroxymonosulfate
资金
- National Natural Science Foundation of China [21207133]
- National Science Fund for Distinguished Young Scholars of China [51425405]
Two-dimensional reduced graphene oxide (2D rGO) was employed as both a shape-directing medium and support to fabricate 2D gamma-MnO2/2D rGO nano-hybrids (MnO2/rGO) via a facile hydrothermal route. For the first time, the 2D/2D hybrid materials were used for catalytic ozonation of 4-nitrophenol. The catalytic efficiency of MnO2/rGO was much higher than either MnO2 or rGO only, and rGO was suggested to play the role for promoting electron transfers. Quenching tests using tert-butanol, p-benzoquinone, and sodium azide suggested that the major radicals responsible for 4-nitrophenol degradation and mineralization are O-2(-) and O-1(2), but not (OH)-O-center dot. Reusability tests demonstrated a high stability of the materials in catalytic ozonation with minor Mn leaching below 0.5 ppm. Degradation mechanism, reaction kinetics, reusability and a synergistic effect between catalytic ozonation and coupling peroxymonosulfate (PMS) activation were also discussed. (C) 2015 Elsevier B.V. All rights reserved.
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