Ferric oxide nanoclusters with low-spin FeIII anchored g-C3N4 rod for boosting photocatalytic activity and degradation of diclofenac in water under solar light

Fe2O3, as an earth-abundant photocatalyst for water purification, has attracted great attention. However, the high-spin FeIII in traditional Fe2O3 restricts its catalytic performance. In this work, based on the nanocrystal size alteration strategy, cubic Fe2O3 nanoclusters (3-4 nm) with low-spin FeIII were successfully anchored on six-fold cavities of the supramolecular condensed g-C3N4 rod (FCN) through the impregnation-coprecipitation method. FCN showed high photocatalytic activity, as the d band center of Fe 3d orbital (-1.79 eV) in low-spin Fe-III shifted closer to Femi level, generating a weaker antibonding state. Then, the enhanced bonding state strengthened the interaction between Fe and O, further accelerating the charge carrier separation and enhancing its ability to capture OH- . Thus, low-spin FeIII enhanced the production of dominant reactive oxygen species (.OH/.O2(-)), promoting diclofenac photocatalytic degradation under solar light, with a kinetic rate constant (0.206 min(-1)) of similar to 5 times compared with that of pristine g-C3N4.

Automated summary

By using the nanocrystal size alteration strategy, a new photocatalyst FCN was developed by anchoring low-spin FeIII Fe2O3 nanoclusters on g-C3N4 rods. FCN showed high photocatalytic activity by enhancing the bonding state and promoting the production of reactive oxygen species, resulting in improved degradation efficiency of diclofenac under solar light.