A General Strategy for the Asymmetric Preparation of α‐Stereogenic Allyl Silanes, Germanes, and Boronate Esters via Dual Copper Hydride‐ and Palladium‐Catalysis

Practical Synthesis of Chiral Allylboronates by Asymmetric 1,1‐Difunctionalization of Terminal Alkenes

(2022) Caocao Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Differential Dihydrofunctionalization: A Dual Catalytic Three‐Component Coupling of Alkynes, Alkenyl Bromides, and Pinacolborane

(2022) James E. Baumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C2-Allylation of Benzimidazoles Using 1,3-Diene Pronucleophiles

(2021) James Levi Knippel et al.   ORGANIC LETTERS

Asymmetric Synthesis of Chiral 1, 3‐Disubstituted Allylsilanes via Copper(I)‐Catalyzed 1, 4‐Conjugate Silylation of α, β‐Unsaturated Sulfones and Subsequent Julia‐Kocienski Olefination

(2021) Xian‐Liang Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Enantioselective Hydroalkenylation of Olefins with Enol Sulfonates Enabled by Dual Copper Hydride and Palladium Catalysis

(2021) Alexander W. Schuppe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Leiodermatolide A via Transfer Hydrogenative Allylation, Crotylation, and Propargylation: Polyketide Construction beyond Discrete Allyl- or Allenylmetal Reagents

(2021) Yuk-Ming Siu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Boryl Organometallic Reagents in Catalytic Asymmetric Synthesis

(2021) Chenlong Zhang et al.   ACS Catalysis

A Dual CuH- and Pd-Catalyzed Stereoselective Synthesis of Highly Substituted 1,3-Dienes

(2021) Chuan-Jin Hou et al.   ORGANIC LETTERS

CuH-Catalyzed Olefin Functionalization: From Hydroamination to Carbonyl Addition

(2020) Richard Y. Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Enantioselective Preparation of Arenes with β‐Stereogenic Centers: Confronting the 1,1‐Disubstituted Olefin Problem Using CuH/Pd Cooperative Catalysis

(2020) Zhaohong Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allylboronates from Vinyl Triflates and α-Chloroboronates by Reductive Nickel Catalysis

(2020) Jin-Bao Qiao et al.   ORGANIC LETTERS

Cobalt-Catalyzed Regio- and Enantioselective Markovnikov 1,2-Hydrosilylation of Conjugated Dienes

(2019) Huanan Wen et al.   ACS Catalysis

Ligand controlled cobalt catalyzed regiodivergent 1,2-hydroboration of 1,3-dienes

(2019) Sihan Peng et al.   Science China-Chemistry

Differential Dihydrofunctionalization of Terminal Alkynes: Synthesis of Benzylic Alkyl Boronates through Reductive Three-Component Coupling

(2019) Megan K. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles

(2017) Cristina García-Ruiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling

(2017) Julie L. Hofstra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand–Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

(2017) Gang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents

(2017) Emma K. Edelstein et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Accessing Both Retention and Inversion Pathways in Stereospecific, Nickel-Catalyzed Miyaura Borylations of Allylic Pivalates

(2016) Qi Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis

(2016) Colin Diner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis

(2016) Stig D. Friis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of α-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination

(2015) Daiki Nishikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of α-Aminosilanes by Copper-Catalyzed Hydroamination of Vinylsilanes

(2014) Nootaree Niljianskul et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonracemic Allylic Boronates through Enantiotopic-Group-Selective Cross-Coupling of Geminal Bis(boronates) and Vinyl Halides

(2014) Bowman Potter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise Synthesis and Antimalarial Activity of All Four Mefloquine Stereoisomers Using a Highly Enantioselective Catalytic Borylative Alkene Isomerization

(2013) Jinyue Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Regioselective Hydroamination of Styrenes with Polymethylhydrosiloxane and Hydroxylamines

(2013) Yuya Miki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products

(2013) Miguel Yus et al.   CHEMICAL REVIEWS

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

(2013) Yang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes

(2013) Shaolin Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Cross-Coupling of Allylboronic Acid Pinacol Ester Derivatives with Aryl Halides via Pd-PEPPSI-IPent

(2012) Jennifer L. Farmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

(2011) Ben W. Glasspoole et al.   CHEMICAL COMMUNICATIONS

An Efficient Copper(I)-Catalyst System for the Asymmetric Hydroboration of β-Substituted Vinylarenes with Pinacolborane

(2011) Dongwan Noh et al.   Chemistry-An Asian Journal

Asymmetric Synthesis of Allylsilanes by the Borylation of Lithiated Carbamates: Formal Total Synthesis of (−)-Decarestrictine D

(2010) Michael Binanzer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry

(2010) Martin Althaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vinylogous Aldol Products from Chiral Crotylsilanes Obtained by Enantioselective Rh(II) and Cu(I) Carbenoid Si−H Insertion

(2010) Jie Wu et al.   ORGANIC LETTERS

Cinchona Alkaloid Catalyzed Enantioselective Fluorination of Allyl Silanes, Silyl Enol Ethers, and Oxindoles

(2008) Takehisa Ishimaru et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION