期刊
ACS APPLIED MATERIALS & INTERFACES
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c12445
关键词
lithium metal battery; self-healing behavior; deep eutectic solvent; fire-resistant; solid-state electrolyte
资金
- National Natural Science Foundation of China
- [21975180]
This study presents a novel DES-based rapid self-healing gel electrolyte for lithium metal batteries, which can achieve high specific capacity and durable cyclic stability by solidifying the electrolyte and enhancing its electrochemical stability.
A deep eutectic solvent (DES) is a promising electrolyte choice for lithium metal batteries. However, the DES liquid electrolyte causes safety concerns and side reactions with the lithium anode. Therefore, it is necessary to solidify the DES-based electrolyte and enhance its electrochemical stability. Herein, we present a novel DES-based rapid self-healing gel electrolyte, which is able to self-smooth its surface cracks in only 30 min. The electrolyte exhibits noncombustibility (SET = 4 s g-1), high ionic conductivity (1.1 x 10-3 S cm-1 at 25 degrees C), and a wide electrochemical voltage window (4.5 V vs Li/Li+). As a result, the solid-state lithium batteries coupling the gel electrolyte with the Li anode and LiFePO4 cathode deliver a high specific capacity of 135.4 mA h g-1 with durable cyclic stability (>1200 h). This work provides valuable insights for design of fire-resistant and high-solid-state lithium batteries.
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