Article
Optics
Aleksandar Ciric, Jovana Perisa, Ivana Zekovic, Zeljka Antic, Miroslav D. Dramicanin
Summary: This study overcomes the sensitivity limit of Boltzmann's thermometers by utilizing seven thermalized Dy3+ excited states in the Lu1.5Y1.5Al5O12 host. By extending the conventional two-thermalized level Boltzmann-type luminescence intensity ratio (LIR) to seven thermalized levels, the approach provides higher energy differences and enables a five times larger sensitivity than the conventional LIR.
JOURNAL OF LUMINESCENCE
(2022)
Article
Chemistry, Inorganic & Nuclear
Sabina Svava Mortensen, Thomas Just Sorensen
Summary: The structures of two compounds were determined using single crystal X-ray diffraction, and their luminescence properties were compared. It was found that the samples were actually mixtures, which required further analysis for quantification.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Physical
I. Kalinovskaya, A. N. Zadorozhnaya
Summary: This study focuses on the spectral luminescence of complex compounds of europium(III) with o-methylbenzoic acid and nitrogen- and phosphorus-containing neutral ligands. The research reveals that the luminescence of o-methylbenzoates of europium(III) is higher than that of m-europium(III)-methylbenzoates.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
(2022)
Article
Chemistry, Multidisciplinary
Shiori Miyazaki, Kenichi Goushi, Yuichi Kitagawa, Yasuchika Hasegawa, Chihaya Adachi, Kiyoshi Miyata, Ken Onda
Summary: Trivalent lanthanide complexes are attractive light emitters due to their high color purity. Sensitization using ligands with high absorption efficiency can enhance photoluminescence intensity, but the development of antenna ligands is limited. A system composed of triazine-based host molecules and Eu(hfa)(3)(TPPO)(2) significantly increased the total photoluminescence intensity compared to conventional luminescent Eu(iii) complexes. Energy transfer from the host molecules to Eu(iii) occurs via triplet states with nearly 100% efficiency, as shown by time-resolved spectroscopic studies. This discovery enables efficient light harvesting of Eu(iii) complexes through a simple solution process.
Article
Chemistry, Multidisciplinary
Gang Yu, Huanyu Liu, Wenchao Yan, Ruoyao Guo, Aoben Wu, Zifeng Zhao, Zhiwei Liu, Zuqiang Bian
Summary: A new heteronuclear Eu-II-Mn-II complex [Eu(N2O6)]MnBr4 has been designed and synthesized, exhibiting intense green emission with near-unity photoluminescence quantum yield. The sensitization process from Eu-II to Mn-II, representing the first example of f -> d molecular sensitization, is demonstrated through measurement of excited-state dynamics. Due to the large optical absorption cross-section of the Eu-II center, [Eu(N2O6)]MnBr4 shows significantly higher emission intensity compared to the Sr-II-Mn-II control complex [Sr(N2O6)]MnBr4 when excited by near ultraviolet to blue light.
MATERIALS HORIZONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Qi Zhou, Guojian Ren, Yonghang Yang, Cong Wang, Guang Che, Meiling Li, Mei-Hui Yu, Jiyang Li, Qinhe Pan
Summary: In this study, a new coordination polymer HNU-76 was synthesized and demonstrated to function as a fluorescence thermometer. By embedding DMSP, the sensing range of HNU-76 was extended. Both materials showed excellent performance and had the potential to be used in fluorescence thermometers.
INORGANIC CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
B. Berzina, R. Ruska, J. Cipa, L. Trinkler, A. Sarakovskis, J. Grabis, I Steins
Summary: The luminescence processes of AlN:Eu ceramics, prepared by high temperature spark plasma sintering method, were studied by measuring photoluminescence and excitation spectra at different fixed temperatures and analyzing luminescence kinetics. The dominant emission in this material is from Eu2+ ions at 530 nm, accompanied by a weak emission from Eu3+ ions at ~600 nm. Excitation of Eu2+ emission occurs at 360 nm and 260 nm. The results suggest the presence of two luminescence mechanisms, with the 360 nm excitation representing the intra-center mechanism and the 260 nm excitation representing recombination luminescence. Additionally, an excitation line at 464 nm was found for Eu3+ ions, along with an emission at 614 nm. Persistent luminescence from Eu ions in AlN was also observed.
Article
Chemistry, Analytical
Manisha Bedi, Monika Punia, Vinod Bala Taxak, Satyender Pal Khatkar, Priti Boora Doon
Summary: A series of red luminescent europium complexes were synthesized and characterized for their potential use in organic light-emitting diodes. The complexes demonstrated good thermal stability and luminescent properties, making them suitable for wide band-gap semiconductors. The study also revealed a characteristic red emission peak in the complexes.
Article
Materials Science, Ceramics
Ying Li, Jia Liu, Xiwei Qi, Aihua Mao, YongHong Ma
Summary: A series of transparent (3-x) Sr3Al2O6-xSm2O3 amorphous spheres were successfully fabricated with an x-value ranging from 0 to 0.065 using an aerodynamic levitation furnace. In the visible light region, the maximum transmittance was approximately 80% for x = 0, 82% for x = 0.025 and 85% for x = 0.055. The excitation peak located at 405 nm was the strongest, and the maximum intensity of the photoluminescence spectra appeared at 0.045. The chromatic coordinates of the CIE were all in the orange region.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Luca Bellucci, Gregorio Bottaro, Luca Labella, Fabio Marchetti, Simona Samaritani, Daniela Belli Dell'Amico, Lidia Armelao
Summary: Two homometallic Coordination Polymers (CPs) were used to develop a family of ratiometric luminescent thermometers with Eu3+ and Tb3+ emitting as red and green colors respectively. The thermometric properties were studied in different mixtures of CPs, showing broad applicative temperature ranges and high relative thermal sensitivity values in the physiological temperature range. These samples exhibited continuous color variation from green to red that can be utilized as a colorimetric temperature indicator.
Article
Engineering, Environmental
Jenny Jessat, Henry Moll, Warren A. John, Marie -Louise Bilke, Rene Hubner, Jerome Kretzschmar, Robin Steudtner, Bjorn Drobot, Thorsten Stumpf, Susanne Sachs
Summary: Daucus carota suspension cells exhibit a high affinity towards Eu(III) and U(VI) and interact with them through a bio-association process. The uptake of U(VI) involves the Ca ion channels and leads to bioprecipitation in the vacuole. Local concentration of Eu(III) is observed in the cell wall and cytoplasm, co-localized with phosphorous and oxygen.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Physical
Sabina Svava Mortensen, Malthe Asmus Marciniak Nielsen, Patrick Nawrocki, Thomas Just Sorensen
Summary: By studying the photophysics of samarium(III) solvates, this work mapped the energy levels and calculated the transition probabilities, revealing the differences in electronic structures among samarium(III) solvates in different solvents.
JOURNAL OF PHYSICAL CHEMISTRY A
(2022)
Article
Materials Science, Multidisciplinary
S. H. Nandyala, G. Hungerford, J. D. Santos, B. M. Walsh, L. Di Silvio, A. Stamboulis
Summary: This study investigated the time-resolved luminescence and excitation-emission matrix measurements of three boro-silicate host glasses doped with Eu3+, as well as the influence of zinc and tellurium oxide addition on the photoluminescence and time-resolved emission spectra of the glasses. The findings revealed that different additives affect the emission peak wavelength and lifetime of Eu3+ in the glasses, possibly due to different environments or interactions experienced by the ions.
MATERIALS RESEARCH BULLETIN
(2021)
Article
Biochemical Research Methods
Manisha Bedi, Pooja Chhillar, Priyanka Dhankhar, Jyoti Khanagwal, V. B. Taxak, S. P. Khatkar, Priti Boora Doon
Summary: This study synthesized Eu(III) complexes based on 5-(4-methylphenyl)-2-furoic acid and characterized their spectroscopic and photophysical features using different investigative techniques. The complexes showed good thermal stability and excellent optoelectronic properties, making them suitable for applications in wide band gap semiconductors.
JOURNAL OF FLUORESCENCE
(2022)
Article
Materials Science, Multidisciplinary
Joe Hayashi, Sunao Shoji, Yuichi Kitagawa, Koji Fushimi, Yasuchika Hasegawa
Summary: A novel lanthanide coordination polymer Eu-dpba composed of Eu(III) ion, low-vibrational frequency hfa, and phosphine oxide ligand with amide groups is reported, showing phase transition behavior. Another lanthanide coordination polymer Eu-dph with alkyl groups is prepared as a reference sample, which does not exhibit phase transition behavior. The smooth surface and unchanged emission quantum yield of Eu-dpba after heat treatment are observed.
Article
Materials Science, Multidisciplinary
Albano N. Carneiro Neto, Ekaterina Mamontova, Alexandre M. P. Botas, Carlos D. S. Brites, Rute A. S. Ferreira, Jerome Rouquette, Yannick Guari, Joulia Larionova, Jerome Long, Luis D. Carlos
Summary: Luminescence thermometry enables remote temperature monitoring and has the potential to drive the next generation of nano or micrometric devices. Through a combination of experiment and theoretical calculations, a new energy-driven luminescent molecular thermometer displaying exceptional thermal cyclability around room temperature is reported, providing comprehensive guidelines for smart engineering of sensing devices.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Physics, Applied
M. A. Hernandez-Rodriguez, S. F. H. Correia, R. A. S. Ferreira, L. D. Carlos
Summary: The luminescent solar concentrator (LSC) is a promising approach to integrate photovoltaic elements into the built environment invisibly. LSCs are devices that convert incident radiation to a specific wavelength and transfer it to photovoltaic cells. The search for environmentally-friendly materials is crucial for the future development of LSCs.
JOURNAL OF APPLIED PHYSICS
(2022)
Article
Chemistry, Physical
Paulo M. C. de Oliveira, Jessica I. R. de Souza, Juliana A. B. da Silva, Ricardo L. Longo
Summary: Topological analyses were conducted to investigate the hydrogen bond networks in liquid water at different temperatures using complex network and island statistics. Through Metropolis Monte Carlo simulations with the TIP4P/2005 potential model, the influence of temperature on the structures and topological properties of the hydrogen bond networks was studied. The simulations properly reproduced the bilinear behavior of the second peak in the radial distribution function with temperature. The average connectivity and semiglobal average path length descriptors displayed bilinear behavior and unprecedented trimodal distribution respectively, indicating the heterogeneities of liquid water.
JOURNAL OF PHYSICAL CHEMISTRY B
(2023)
Article
Optics
Miguel. A. A. Hernandez-Rodriguez, Sofia Zanella, Lianshe Fu, Albano N. Carneiro Neto, Luis D. Carlos, Carlos D. S. Brites
Summary: The increasing demand for computing power has pushed current lithographic methods to their limits, hindering further shrinkage of silicon chips using top-down approaches. The recent chip shortage has highlighted the world's excessive reliance on silicon and emphasized the need for silicon-free computing technologies, preferably at the molecular level. This study demonstrates an all-photonic device based on the emission dynamics of Eu3+ and Tb3+ ions in a Eu3+/Tb3+ co-doped organic-inorganic di-ureasil hybrid, showcasing a temperature-reprogrammable shift from a low-pass filter to a high-pass filter and paving the way for molecular analogs of conventional circuit components.
LASER & PHOTONICS REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Carlos D. S. Brites, Riccardo Marin, Markus Suta, Albano N. Carneiro Neto, Erving Ximendes, Daniel Jaque, Luis D. Carlos
Summary: Luminescence (nano)thermometry is a remote sensing technique that utilizes the temperature dependency of luminescence features to measure temperature. It has potential applications in various fields and requires the establishment of a theoretical background, standardized practices, and improved readouts through multiparametric analysis and artificial intelligence algorithms. Challenges in luminescence thermometry and the need for continuous innovation are also discussed.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Sofia Zanella, Maxime Aragon-Alberti, Carlos D. S. Brite, Fabrice Salles, Luis D. Carlos, Jerome Long
Summary: Luminescent thermometry enables remote temperature detection and has great potential in future technological applications. We demonstrate for the first time that luminescence thermometry can be combined with a complementary temperature readout related to a different property. By taking advantage of the temperature dependence of magnetic and luminescence features in Single-Molecule Magnets (SMM), we develop original dual magneto-optical molecular thermometers that offer a 10-fold improvement in relative thermal sensitivity over the whole temperature range.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Fernando E. E. Maturi, Anuraag Gaddam, Carlos D. S. Brites, Joacilia M. M. Souza, Hellmut Eckert, Sidney J. L. Ribeiro, Luiis D. Carlos, Danilo Manzani
Summary: Glasses with tunable properties are versatile materials for optical technologies. To design new optical glasses, understanding the correlation between their chemical composition and physical properties is crucial. We demonstrate the feasibility of using fluoride phosphate glasses co-doped with Pr3+ and Yb3+ ions for temperature sensing. These glasses have high stability and act as luminescent thermometers without the need for recurring calibration. They exhibit competitive thermal sensitivity and uncertainty, making them promising for cost-effective and accurate temperature probes, advancing photonic technologies.
CHEMISTRY OF MATERIALS
(2023)
Article
Physics, Multidisciplinary
Augusto C. L. Moreira, Juliana A. B. da Silva
Summary: In this work, we demonstrate that in the non-interacting limit, the classical master equation (CME) with electron transfer rates obtained via Fermi golden rule and the elastic scattering approach are equivalent. This finding provides a theoretical basis for incorporating elastic mechanisms into quantum transport, allowing the description of weak and strong quantum transport regimes within the same theory.
Article
Spectroscopy
Fernanda Sodre Rodrigues, Victor Agostinho Marques da Silva, Graziella Borges Queiroz Segovia, Adailton Joao Bortoluzzi, Alexandre Cuin, Jessica I. R. de Souza, Juliana A. B. da Silva, Leonis Lourenco da Luz, Severino Alves Junior, Eduardo Tonon de Almeida, Maryene Alves Camargo
Summary: Three new lanthanide complexes Na[Ln(pic)(4)]center dot.2.5H(2)O (Ln = Tb, Eu, or Gd; pic = picolinate) were synthesized and characterized. The crystal structures of the complexes were determined by single-crystal X-ray diffraction. The photoluminescent properties and theoretical studies of the complexes were investigated.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Materials Science, Multidisciplinary
Sofia Zanella, Miguel A. Hernandez-Rodriguez, Lianshe Fu, Rui Shi, Luis D. Carlos, Rute A. S. Ferreira, Carlos D. S. Brites
Summary: Computers and computing systems are playing an increasingly important role in society, especially with the emergence of Artificial Intelligence. The development of innovative computing systems with higher processing speeds and lower costs is necessary due to the increasing number of computer systems and the digitalization of society. Quantum computing has seen remarkable advancements in the past five years, but photonic and molecular computing also show potential in achieving maximum miniaturization by using molecules as building blocks for logic systems.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Arnab De, Miguel A. Hernandez-Rodriguez, Carneiro N. Neto Albano, Vivek Dwij, Vasant Sathe, Luis D. Carlos, Rajeev Ranjan
Summary: It is generally known that the emission intensity of trivalent lanthanide ions (Ln(3+)) increases on cooling, but recent studies have shown that the intensity of Eu3+ photoluminescence decreases on cooling. In this study, the mechanism underlying this anomalous behaviour was investigated using experimental and theoretical approaches. It was found that off-resonance excitation enhanced the Eu3+ emissions with increasing temperature, and the temperature dependence of the emission intensity could be tuned by varying the bandpass of the excitation source.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Talita J. S. Ramos, Ricardo L. Longo, Carlos D. S. Brites, Rute A. S. Ferreira, Oscar L. Malta, Luis D. Carlos
Summary: Low-power near-infrared lasers can drive upconversion broadband white light emission. Despite the sensitizer and activator being in different particles, efficient continuous upconversion emissions were observed. The synthesized nanoparticles also functioned as luminescent thermometers with potential applications in remote temperature sensing.
Article
Materials Science, Multidisciplinary
Luan N. Passini, Fernando E. Maturi, Roberta S. Pugina, Eloisa G. Hilario, Marina Fontes, Hernane S. Barud, Luis D. Carlos, Jose Mauricio A. Caiut, Danilo Manzani
Summary: Choosing a suitable host matrix for temperature sensing in biomedical applications requires low cytotoxicity, easy synthesis, and the ability to be doped with light-emitting ions. Indium-based halide double perovskites, namely Cs2AgIn0.9Bi0.1Cl6, Cs2Ag0.6Na0.4InCl6, and Cs2Ag0.6Na0.4In0.9Bi0.1Cl6, were selected as host materials to develop lanthanide-based primary thermometers due to their low phonon energy and ease of synthesis. These perovskite samples demonstrated excellent thermal stability and were able to withstand temperatures as high as 500 degrees C. A temperature-dependent green emission of Er3+ was observed in the co-doped samples, exhibiting a relative thermal sensitivity of 1.3% K-1 and an uncertainty in temperature values of 0.3 K. Incorporating these perovskites into L2929 cells resulted in high cell viability, highlighting the advantages of using low-cytotoxicity materials for biological applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Inorganic & Nuclear
Julio Corredoira-Vazquez, Cristina Gonzalez-Barreira, Matilde Fondo, Ana M. Garcia-Deibe, Jesus Sanmartin-Matalobos, Miguel A. Hernandez-Rodriguez, Luis D. Carlos
Summary: The study successfully synthesized and characterized a Dy-4 SMM complex, which exhibits multiple relaxation pathways and a high anisotropic energy barrier, as well as functioning as a luminescent thermometer.
DALTON TRANSACTIONS
(2022)