4.6 Article

The Effect of (Mg, Zn)12Ce Phase Content on the Microstructure and the Mechanical Properties of Mg-Zn-Ce-Zr Alloy

期刊

MATERIALS
卷 15, 期 13, 页码 -

出版社

MDPI
DOI: 10.3390/ma15134420

关键词

Mg-Zn-Ce-Zr alloy; (Mg; Zn)(12)Ce phase; phase separation; thermal deformation; quantitative analysis

资金

  1. National Natural Science Foundation of China [51661025]
  2. Inner Mongolia Autonomous Region Science and Technology Project [2020GG0318]

向作者/读者索取更多资源

The quantitative study of rare earth compounds is crucial for the development of magnesium alloy systems. This study successfully separated the matrix and compound in Mg-Zn-Ce-Zr alloy and determined the mass fraction of (Mg, Zn)(12)Ce compound. The results showed that the amount of (Mg, Zn)(12)Ce phase significantly affected the heat deformation organization and properties. Increasing the amount of (Mg, Zn)(12)Ce phase reduced the critical conditions for dynamic recrystallization formation. The study also found that alloys with different Zn contents exhibited different softening mechanisms.
The quantitative study of rare earth compounds is important for the improvement of existing magnesium alloy systems and the design of new magnesium alloys. In this paper, the effective separation of matrix and compound in Mg-Zn-Ce-Zr alloy was achieved by a low-temperature chemical phase separation technique. The mass fraction of the (Mg, Zn)(12)Ce compound was determined and the effect of the (Mg, Zn)(12)Ce phase content on the heat deformation organization and properties was investigated. The results show that the Mg-Zn-Ce compound in both the as-cast and the homogeneous alloys is (Mg, Zn)(12)Ce. (Mg, Zn)(12)Ce phase formation depends on the content and the ratio of Zn and Ce elements in the initial residual melt of the eutectic reaction. The Zn/Ce mass ratios below 2.5 give the highest compound contents for different Zn contents, 5.262 wt.% and 7.040 wt.%, respectively. The increase in the amount of the (Mg, Zn)(12)Ce phase can significantly reduce the critical conditions for dynamic recrystallization formation. Both the critical strain and the stress decrease with increasing rare earth content. The reduction of the critical conditions and the particle-promoted nucleation mechanism work together to increase the amount of dynamic recrystallization. In addition, it was found that alloys with 6 wt.% Zn elements tend to undergo a dynamic recrystallization softening mechanism, while alloys with 3 wt.% Zn elements tend to undergo a dynamic reversion softening mechanism.

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Article Materials Science, Multidisciplinary

Quantitative analysis of rare earth elements in Mg-Zn-RE(Ce, Y, Gd)-Zr alloy

Yuguang Li, Feng Guo, Yiwei Wang, Huisheng Cai, Liang Liu

Summary: The existing forms of rare earth elements and their solid solution amount in ZK-RE(Ce, Y, Gd) alloy were studied quantitatively using low-temperature phase separation technology. The results showed that the solid solution amount of rare earth elements mainly depends on their addition amount, and the ability to form solid solutions differs among Gd, Y, and Ce. Rare earth elements are mostly distributed in Mg-Zn-RE compounds, and increasing the rare earth content facilitates the formation of more Mg-Zn-RE compounds. The solid solution ability of rare earth elements follows the order of Gd > Y > Ce, and the amount of solid solution directly affects the initial element content of compound precipitation in the remaining melt. The Zn/Ce ratio in the residual melt of ZK-Ce alloy and the Zn/Y(Gd) ratio in the residual melt of ZK-RE(Y, Gd) alloy determine the type and number of rare earth compounds.

MATERIALS RESEARCH EXPRESS (2022)

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