From Styrenes to Fluorinated Benzyl Bromides: A Photoinduced Difunctionalization via Atom Transfer Radical Addition

Metal-free photosensitized oxyimination of unactivated alkenes with bifunctional oxime carbonates

(2021) Tuhin Patra et al.   Nature Catalysis

Photochemical C–H Activation Enables Nickel-Catalyzed Olefin Dicarbofunctionalization

(2021) Mark W. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox-Catalyzed Addition of Dibromofluoromethane to Alkenes: Direct Synthesis of 1-Bromo-1-fluoroalkanes

(2021) Feng Chen et al.   ORGANIC LETTERS

Bifunctional reagents in organic synthesis

(2021) Huan-Ming Huang et al.   Nature Reviews Chemistry

Alkene Difunctionalization Triggered by a Stabilized Allenyl Radical: Concomitant Installation of Two Unsaturated C−C Bonds

(2021) Yunlong Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Applications of Halogen-Atom Transfer (XAT) for the Generation of Carbon Radicals in Synthetic Photochemistry and Photocatalysis

(2021) Fabio Juliá et al.   CHEMICAL REVIEWS

Advances in [18F]Trifluoromethylation Chemistry for PET Imaging

(2021) Felix Francis et al.   MOLECULES

Nickel-Catalyzed α-Carbonylalkylarylation of Vinylarenes. Expedient Access to γ,γ-Diarylcarbonyl and Aryltetralone Derivatives

(2020) Shekhar KC et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective 1,2-Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis

(2020) Shang-Zheng Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Alkene Difunctionalization via Gold Catalyzed Oxyarylation

(2020) Shuyao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd‐Catalyzed Regioselective Olefination of N ‐Tosylhydrazones with Benzyl Bromides

(2020) Zhenze Sun et al.   ChemistrySelect

Formal Bromine Atom Transfer Radical Addition of Nonactivated Bromoalkanes Using Photoredox Gold Catalysis

(2020) Montserrat Zidan et al.   ORGANIC LETTERS

Three‐Component Alkene Difunctionalization via Direct and Selective Activation of Aliphatic C‐H Bonds

(2020) Sheng Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lanthanum‐Catalyzed Enantioselective Trifluoromethylation by Using an Electrophilic Hypervalent Iodine Reagent

(2019) Albert Granados et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkene Difunctionalization Using Hypervalent Iodine Reagents: Progress and Developments in the Past Ten Years

(2019) Lee et al.   MOLECULES

Light-Mediated Dual Phosphine-/Copper-Catalyzed Atom Transfer Radical Addition Reaction

(2019) Oleg V. Fedorov et al.   JOURNAL OF ORGANIC CHEMISTRY

Three-Component Olefin Dicarbofunctionalization Enabled by Nickel/Photoredox Dual Catalysis

(2019) Mark W. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal-Catalyzed Dicarbofunctionalization of Unactivated Olefins

(2018) Roshan K. Dhungana et al.   CHEMICAL RECORD

Carbocation Catalyzed Bromination of Alkyl Arenes, a Chemoselective sp 3 vs. sp 2 C−H functionalization.

(2018) Shengjun Ni et al.   ADVANCED SYNTHESIS & CATALYSIS

The Difluoromethyl Group as a Masked Nucleophile: A Lewis Acid/Base Approach

(2018) Jacob B. Geri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct and Regioselective C–H Oxidative Difluoromethylation of Heteroarenes

(2018) Sheng-Qing Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C -Glycosyl Styrene Type Compounds by Pd-Catalyzed Cross-Coupling Reactions of Anhydro-Aldose Tosylhydrazones with Benzyl Bromides

(2018) Tímea Kaszás et al.   ADVANCED SYNTHESIS & CATALYSIS

Taming Radical Intermediates for the Construction of Enantioenriched Trifluoromethylated Quaternary Carbon Centers

(2018) Roxan Calvo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Studies in Photocatalysis

(2018) Luca Buzzetti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Reaction between N-Tosylhydrazones and 2-Nitrobenzyl Bromide: Route to NH-Free C2-Arylindoles

(2018) Tourin Bzeih et al.   JOURNAL OF ORGANIC CHEMISTRY

CF2H, a Hydrogen Bond Donor

(2017) Chanan D. Sessler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox Divergent 1,2-Difunctionalization of Alkenes with gem-Dibromides

(2017) Jian Cheng et al.   ORGANIC LETTERS

Mechanism and Applications of the Photoredox Catalytic Coupling of Benzyl Bromides

(2016) Gyurim Park et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of 4-Vinyl-1H-1,2,3-triazoles on Solid Supports via Polystyrene-Bound But-3-ynyl Selenide

(2016) Peng Ming et al.   HETEROATOM CHEMISTRY

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

Fluorination methods in drug discovery

(2016) Damian E. Yerien et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Photoredox-Catalyzed Bromodifluoromethylation of Alkenes with (Difluoromethyl)triphenylphosphonium Bromide

(2016) Qing-Yu Lin et al.   ORGANIC LETTERS

Silica-Based Magnetic Manganese Nanocatalyst – Applications in the Oxidation of Organic Halides and Alcohols

(2016) Rakesh K. Sharma et al.   ACS Sustainable Chemistry & Engineering

Hypervalent iodine mediated alkene difunctionalization of vinylphenols: diastereoselective synthesis of substituted indoles and indolizines

(2015) Kai Zhang et al.   CHEMICAL COMMUNICATIONS

Polyfluorinated groups in medicinal chemistry

(2015) Marcella Bassetto et al.   Future Medicinal Chemistry

Donor/Acceptor Indenoperylene Dye for Highly Efficient Organic Dye-Sensitized Solar Cells

(2015) Zhaoyang Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterizing chain processes in visible light photoredox catalysis

(2015) Megan A. Cismesia et al.   Chemical Science

Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

(2014) Xiao Liu et al.   CHEMICAL REVIEWS

Recent Advances in Trifluoromethylation Reactions with Electrophilic Trifluoromethylating Reagents

(2014) Sebastián Barata-Vallejo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric photoredox transition-metal catalysis activated by visible light

(2014) Haohua Huo et al.   NATURE

Evolution of a strategy for preparing bioactive small molecules by sequential multicomponent assembly processes, cyclizations, and diversification

(2014) James J. Sahn et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts

(2012) Carl-Johan Wallentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts

(2011) John D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of benzyl bromides with hexabromoacetone: an alternative path to drug intermediates

(2010) Kara M. Joseph et al.   TETRAHEDRON LETTERS

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS