Review
Chemistry, Multidisciplinary
Maksim Rodin, Jie Li, Dirk Kuckling
Summary: Supramolecular chemistry offers dynamic interactions for polymeric gels, providing reversibility and responsiveness to external stimuli, addressing the limitations of traditional cross-linked polymers. By combining different types of cross-links in a single gel, researchers have created versatile materials with improved mechanical performance and multifunctionality for applications in various fields.
CHEMICAL SOCIETY REVIEWS
(2021)
Article
Chemistry, Physical
Maxim D. Malyshev, Daria Guseva, Valentina V. Vasilevskaya, Pavel Komarov
Summary: This study investigated the mechanical properties of epoxy resin filled with clay nanoparticles of various shapes and contents. It was found that the chemical cross-linking between nanoparticles and the polymer matrix enhanced the composite material's performance, with different nanoparticle shapes showing distinct effects on the elastic modulus.
Article
Polymer Science
Xiangrui Zheng, Yafang Guo, Jack F. Douglas, Wenjie Xia
Summary: To understand the structure-property relationships of cross-linked thermosetting polymers, this study investigates the effect of cohesive energy and cross-link density on their segmental dynamics and mechanical properties. Increasing cross-link density leads to higher glass transition temperature and fragility of glass formation, while increasing cohesive energy decreases fragility. Additionally, the macroscopic mechanical properties are strongly correlated with the local molecular stiffness. These findings provide insights for the molecular design of cross-linked thermosets.
Article
Multidisciplinary Sciences
Hui Tan, Luzhi Zhang, Xiaopeng Ma, Lijie Sun, Dingle Yu, Zhengwei You
Summary: In this study, the authors report fibers prepared with dynamic covalent bonds, which can reversibly dissociate for processing and maintain improved mechanical properties. This technology provides a simple and effective method for producing adaptable fibers.
NATURE COMMUNICATIONS
(2023)
Article
Polymer Science
Cagla Erkoc, Erol Yildirim, Mine Yurtsever, Oguz Okay
Summary: This study investigates the mechanical properties and influencing factors of hydrogels with different compositions of copolymer monomers through experimental verification and simulation calculations. The study finds that the hydrophobicity of the major copolymer monomer, ionic H-bonds, formation of strong H-bonded nanoaggregates, and stronger and higher inter-chain H-bonding and electrostatic interactions are critical factors determining the mechanical performance of the hydrogels.
Article
Chemistry, Physical
Andrey V. Shibaev, Alexander I. Kuklin, Vladimir N. Torocheshnikov, Anton S. Orekhov, Sebastien Roland, Guillaume Miquelard-Garnier, Olga Matsarskaia, Ilias Iliopoulos, Olga E. Philippova
Summary: Interpenetrating networks of a polymer network with dynamic cross-links and a supramolecular network can lead to hydrogels with significantly enhanced mechanical properties. In this study, binary hydrogels composed of a dynamically cross-linked polymer network and a transient network of entangled highly charged mixed wormlike micelles were prepared and found to exhibit significantly improved rheological properties. These materials have great potential for applications in various fields.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Polymer Science
Soheil Sharifi, Isabel Asenjo-Sanz, Ester Verde-Sesto, Jon Maiz, Jose A. Pomposo, Angel Alegria
Summary: In this study, the dissimilar dynamic properties of PTHF-based materials prepared through intra-vs intermolecular click chemistry were investigated. Although the segmental relaxation time and glass transition temperature value were similar, there were evident differences in dynamic heterogeneities, which were attributed to the peculiar morphology of the intra-chain collapsed polymer chains.
Article
Materials Science, Multidisciplinary
Kimberly Miller McLoughlin, Amin Jamei Oskouei, Michelle K. Sing, Alireza Bandegi, Sarah Mitchell, Jayme Kennedy, Thomas G. Gray, Ica Manas-Zloczower
Summary: Cross-linked EVA is widely used in demanding applications and its thermomechanical properties are influenced by various factors. The content of vinyl acetate, molecular weight, and chain topology affect the crystallinity and crystallite size of the material. Cross-linking reduces the crystallinity compared to un-cross-linked EVA. By controlling the properties and degree of cross-linking, the performance properties of cross-linked EVA can be adjusted. Understanding these effects enables material selection and property adjustment to meet the demands of different applications.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Polymer Science
Katsumi Hagita, Takahiro Murashima, Minami Ebe, Takuya Isono, Toshifumi Satoh
Summary: This study aims to create a tough polymer network material using rings as movable crosslinks and explores the preparation methods of materials in which linear chains penetrate rings and ring complexes. Through the correspondence between simulations and experiments, we found that the ring size is crucial for achieving novel mechanical properties. In addition, we introduced the concept of ring-bridge probability and investigated the dependence of trapping probability and ring-bridge probability on the ring size. By establishing a close correspondence between experimental and simulation results, we were able to predict the bridge and trapping probabilities of spiro-multicyclic polymers. The findings highlight the significant contribution of simulation-based prediction in the development of polymer network materials with ring-linear blends.
Article
Polymer Science
Yangke Xiao, Pingwei Liu, Wen-Jun Wang, Bo-Geng Li
Summary: This study demonstrates a method for preparing polyolefin elastomers with tunable dynamic chemical cross-linking, compatible with industrial production, showing high mechanical performance and thermal stability. After multiple reprocessing, the elastomers maintain high performance, indicating the potential for developing high-performance polyolefins with good reprocessability and recyclability in the future.
Article
Chemistry, Physical
Tongfei Wu, Ping Zhang
Summary: The incorporation of dynamic covalent bonds is an attractive strategy for synthesizing adaptive solid polymer electrolytes. This study investigates the relationship between ion transport and segmental dynamics in dynamic covalent cross-linked PEO-Li+ SPEs using molecular dynamics simulations. The dynamics of the network topology, facilitated by the reshuffling of dynamic covalent bonds, is analyzed using graph theory. Comparisons with conventionally cross-linked counterparts reveal the effect of dynamic-bond reshuffling on ion transport in terms of self-diffusivities, cation transference number, and ionic conductivity.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Physical
Gabriele Kloker, Syed A. Pervez, Alexander Hoefling, Maximilian Fichtner
Summary: This study focuses on solid-state batteries based on composite polymer electrolytes, which utilize nano-LLZO particles to enhance the performance of the cells. The addition of 5 wt % nano-LLZO improves the voltage stability, electrochemical window, and limiting current density of the cells.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Polymer Science
Jiaxin Shi, Tianze Zheng, Yao Zhang, Baohua Guo, Jun Xu
Summary: Polyurethanes with covalent adaptive network (CAN) have attracted attention for their recyclability and self-healing properties. By adjusting the chemical structure of aliphatic isocyanates, the dynamics of the dynamic covalent network can be regulated, resulting in improved thermodynamic and kinetic feasibility. This method shows potential for developing self-healing and recyclable cross-linked polyurethanes with variable properties.
Article
Polymer Science
Yasir Mehmood, Hira Shahid, Numera Arshad, Akhtar Rasul, Talha Jamshaid, Muhammad Jamshaid, Usama Jamshaid, Mohammad N. Uddin, Mohsin Kazi
Summary: In this study, hydrogel films containing amikacin were successfully developed by cross-linking chitosan with folic acid, methacrylic acid, ammonium peroxodisulfate, and methylenebisacrylamide. The films demonstrated regulated and controlled release of the antibiotic, as well as effective antibacterial activity and cytocompatibility, showing great potential for wound healing applications.
Article
Chemistry, Physical
Evangelia Vasilaki, Gabriela Gaj, Sylwia Wrobel, George Karchilakis, Joanna Pietrasik, Maria Vamvakaki
Summary: This work presents a method for synthesizing non-cross-linked, spherical, hollow polymer nanocapsules of low dispersity in aqueous media. The nanocapsules were obtained by growing well-defined diblock copolymer brushes from the surface of silica spheres via surface-initiated atom transfer radical polymerization (SI-ATRP). The hollow polymer nanocapsules demonstrated high yields, tunable sizes, and low dispersity without the need for chemical cross-links.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)