期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 463, 期 -, 页码 118-127出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2015.10.047
关键词
Activated carbon; Nitric acid; Microwave heating; Heavy metal ions; Adsorption kinetics
资金
- National Natural Science Foundation of China [51476034]
- National Basic Research Program of China (973 Program) [2012CB215306]
- State Key Laboratory of Motor Vehicle Biofuel Technology [KFKT2014002]
The rice husk based activated carbon (RI-AC) was treated by nitric acid under microwave heating, in order to improve its capability for the removal of heavy metal ions from water. The optimal conditions for the modification of RH-AC (M-RH-AC) were determined by means of orthogonal array experimental design, giving those as the concentration of nitric acid of 8 mol/L, modification time of 15 min, modification temperature of 130 degrees C and microwave power of 800 W. The characteristics of the M-RH-AC and RH-AC were examined by BET, XRD, Raman spectrum, pH titration, zeta potential, Boehm titration and FTIR analysis. The M-RH-AC has lower pore surface area, smaller crystallite, lower pH(IEP) and more oxygen-containing functional groups than the RH-AC. Removal capacity of Pb(II) ions by the M-RH-AC and RH-AC from water solution was estimated concerning the influence of contact time, pH value, and initial concentration. The equilibrium time of Pb(II) removal was found to be around 90 min after modification process. Two kinetic models are adopted to describe the possible Pb(II) adsorption mechanism, finding that the adsorption rate of Pb(II) ions by the M-RH-AC is larger than that of RH-AC. (C) 2015 Elsevier Inc. All rights reserved.
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