期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 462, 期 -, 页码 191-199出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2015.09.067
关键词
Hierarchically porous structure; TS-1/modified-diatomite composite; In situ hydrothermal method; Synergistic effect; Methylene blue
资金
- Natural Science Foundation of Guangdong Province, China [S2013030014241]
- National Key Technology Research and Development Program of the Ministry of Science and Technology of China [2013BAC01B02]
- Natural Science Foundation of China [41202024]
- Science and Technology Program of Guangzhou, China [201510010138]
Hierarchically porous TS-1/modified-diatomite composites with high removal efficiency for methylene blue (MB) were prepared via a facile in situ hydrothermal route. The surface charge state of the diatomite was modified to enhance the electrostatic interactions, followed by in situ hydrothermal coating with TS-1 nanoparticles. The zeolite loading amount in the composites could be adjusted by changing the hydrothermal time. The highest specific surface area and micropore volume of the obtained composites were 521.3 m(2)/g and 0.254 cm(3)/g, respectively, with an optimized zeolite loading amount of 96.8%. Based on the synergistic effect of efficient adsorption and photocatalysis resulting from the newly formed hierarchically porous structure and improved dispersion of TS-1 nanoparticles onto diatomite, the composites' removal efficiency for MB reached 99.1% after 2 h of photocatalytic reaction, even higher than that observed using pure TS-1 nanoparticles. Moreover, the superior MB removal kinetics of the composites were well represented by a pseudo-first-order model, with a rate constant (5.28 x 10(-2) min(-1)) more than twice as high as that of pure TS-1 nanoparticles (2.43 x 10(-2) min(-1)). The significant dye removal performance of this novel TS-1/modified-diatomite composite indicates that it is a promising candidate for use in waste water treatment. (C) 2015 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据