Sulfonated calixarene modified Poly(methyl methacrylate) nanoparticles:A promising adsorbent for Removal of Vanadium Ions from aqueous media

The poly (methyl methacrylate) (PMMA)-based nanoparticle was synthesized by surfactant-free emulsion polymerization method and then post modified with Calixarene using (3-Aminopropyl)triethoxysilane organosilane as a linker after OH-treatment. The prepared structure was applied for efficient adsorption of Vanadium ions in the aqueous solution after characterization by FT-IR, SEM, TEM, DLS, and EDX. Additional investigations discovered that the prepared adsorbent has a good capacity to adsorb vanadium ions. The effect of key experimental factors was studied to find the optimal point of adsorbent efficiency including the initial concentration of analyte, sorbent dosage, pH of the solution, contact time, and type/quantity of the eluents. It was specified, the maximum adsorption capacity for the synthesized nanoparticles was obtained about 322 mg g(-1). The adsorption mechanism was revealed that the model of Langmuir isotherm well-matched compared to the others due to the calculated equilibrium data. Besides, the kinetics of the adsorption process was fitted with pseudo-second-order. Eventually, the prepared adsorbent was successfully applied in vanadium adsorption from real water media.

Automated summary

The PMMA-based nanoparticle was synthesized and post modified with Calixarene, showing good capacity to adsorb vanadium ions. The maximum adsorption capacity was found to be approximately 322 mg g(-1). The Langmuir isotherm model and pseudo-second-order kinetics provided the best fit for the adsorption mechanism.