Article
Chemistry, Multidisciplinary
Jaschar Atik, Diddo Diddens, Johannes Helmut Thienenkamp, Gunther Brunklaus, Martin Winter, Elie Paillard
Summary: The study demonstrates that incorporating a pyrrolidinium cation with an oligo(ethylene oxide) substituent in SPEs can enhance lithium-ion transport speed. This not only accelerates the conduction modes of PEO, but also enables new conduction modes associated with the solvation of lithium by a single IL cation, leading to improved performance on lithium-metal polymer batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Florian Gebert, Jonathan Knott, Robert Gorkin, Shu-Lei Chou, Shi-Xue Dou
Summary: The paper reviews the development of solid-polymer and gel-polymer electrolytes for sodium-ion batteries as a way to enhance competitiveness. It discusses the targeted manipulation of these electrolytes and their significance for practical applications, as well as the interdependence of various electrochemical and mechanical properties. Additionally, a quantitative comparison of reported values across different polymer classes is conducted for the first time.
ENERGY STORAGE MATERIALS
(2021)
Article
Engineering, Environmental
N. F. Mazuki, M. Z. Kufian, Y. Nagao, A. S. Samsudin
Summary: In this study, hybrid gel polymer electrolytes (HGPEs) composed of PMMA-PLA with LiTFSI were investigated. The addition of LiTFSI decreased the glass transition temperature of HGPEs and enhanced the amorphous phase, resulting in increased ionic conductivity. The dielectric response approach revealed that the ion dissociation and transport properties of the PMMA-PLA-LiTFSI systems followed the trend of ionic conductivity.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2022)
Article
Chemistry, Multidisciplinary
Taeyoon Ki, Changhoon Lee, Jehan Kim, In-Wook Hwang, Chang-Mok Oh, Kiyoung Park, Sanseong Lee, Ju-Hyeon Kim, Chandran Balamurugan, Jaemin Kong, Hyeon-Seok Jeong, Sooncheol Kwon, Kwanghee Lee
Summary: This study demonstrates a novel strategy of eliminating problematic organic metal-binding ligands in TMO precursors through an anion-induced catalytic reaction (ACR) at room temperature, promoting the formation of a metal-oxygen network. The ACR-derived TMO thin film on top of a photoactive layer shows excellent electrical conductivity and work function tunability, leading to higher efficiency and longer stability in inverted device configurations.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
Polymer Science
Jayeeta Chattopadhyay, Tara Sankar Pathak, Diogo M. F. Santos
Summary: This review summarizes the applications and advantages of polymer electrolytes in lithium-ion batteries, and discusses the ion transport mechanisms, preparation methods, and recent advancements in specific battery systems. Moreover, it proposes strategies for developing novel polymer electrolytes for high-performance lithium-ion batteries.
Article
Polymer Science
Tugce P. Ozturk, Onur B. Ozdemir, Ali Gelir, Nahid A. Keshtiban, Oender Yargi, Selin Piravadili Mucur, Alper Secgin
Summary: The use of solid-state electrolytes, such as in supercapacitors, is of significant importance due to their advantages over liquid electrolytes. This study investigates the electrochemical performance of supercapacitors with graphene coated electrodes and binary PVA gel electrolytes, focusing on the effects of a conductive layer and KOH concentration. The results show that the conductive layer influences the charging behavior, with specific capacitance values being dependent on the sweep rate.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Haoyue Liang, Shuhao Wang, Qi Ye, Cheng Zeng, Zhaoming Tong, Ying Ma, Huiqiao Li
Summary: By introducing g-C3N4 as a mediator into the PEO electrolyte, the interface with the lithium metal anode is stabilized, resulting in improved interface stability and a longer cycle life of over 900 hours for the symmetric cell.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Mohammadjavad Eslamian, Fereshtehsadat Mirab, Vijay Krishna Raghunathan, Sheereen Majd, Mohammad Reza Abidian
Summary: Electrochemical actuators made from organic semiconductors demonstrate high performance with fast ion transport and accumulation capability. These devices have low power consumption, large deformation, fast response, and excellent actuation stability, making them suitable for various applications.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Juanjuan Han, Wenfeng Song, Xueqi Cheng, Qiang Cheng, Yangyang Zhang, Chifeng Liu, Xiaorong Zhou, Zhandong Ren, Meixue Hu, Tianshu Ning, Li Xiao, Lin Zhuang
Summary: The study highlights the impact of different types of cations on AEMs performance, emphasizing the need to select suitable backbones to match the cations for improved membrane performance.
Article
Chemistry, Physical
Maria Martinez-Ibanez, Nicola Boaretto, Alexander Santiago, Leire Meabe, Xiaoen Wang, Oihane Zugazua, Inigo Raposo, Maria Forsyth, Michel Armand, Heng Zhang
Summary: This paper reports a highly-concentrated FSI-based ternary gel polymer electrolyte (TGPE) with high lithium-ion conductivities, wide electrochemical stability, and superior compatibility with lithium metal electrode. The TGPE enables stable Li plating and stripping processes, as well as high discharge capacity of a Li||Li(Ni0.6Mn0.2Co0.2)O2 cell at ambient temperatures. This study not only provides safe and highly conductive polymer electrolytes but also enhances our understanding of the role of FSI anions in high-energy lithium metal batteries.
JOURNAL OF POWER SOURCES
(2023)
Review
Chemistry, Physical
Shuai Tang, Wei Guo, Yongzhu Fu
Summary: Composite polymer electrolytes (CPEs) show promising applications in batteries with unique advantages like low interfacial resistance, high ionic conductivity, and flexible characteristics.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Laiqiang Xu, Xuhuan Xiao, Hanyu Tu, Fangjun Zhu, Jing Wang, Huaxin Liu, Weiyuan Huang, Wentao Deng, Hongshuai Hou, Tongchao Liu, Xiaobo Ji, Khalil Amine, Guoqiang Zou
Summary: Research has found that by regulating functional groups in metal-organic frameworks, it is possible to alter the distribution of surface charges, limit the movement of anions, and enhance ionic conductivity, providing a feasible direction for high-performance solid-state batteries.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Laiqiang Xu, Xuhuan Xiao, Hanyu Tu, Fangjun Zhu, Jing Wang, Huaxin Liu, Weiyuan Huang, Wentao Deng, Hongshuai Hou, Tongchao Liu, Xiaobo Ji, Khalil Amine, Guoqiang Zou
Summary: Solid-state batteries can provide high energy density and safety, while polymer electrolytes face challenges due to slow ion kinetics and low selective transport of Li+. Metal-organic frameworks (MOFs) are proposed as fillers for solid-state electrolytes, but developing functionalized MOFs and understanding their role in ion transfer is difficult. This study demonstrates that functional group regulation in MOFs can effectively control charge distribution and limit anion movement, leading to improved performance in composite electrolytes for high-performance solid-state batteries.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Jan-Philipp Hoffknecht, Alina Wettstein, Jaschar Atik, Christian Krause, Johannes Thienenkamp, Gunther Brunklaus, Martin Winter, Diddo Diddens, Andreas Heuer, Elie Paillard
Summary: Lithium salts with low coordinating anions such as bis(trifluoromethanesulfonyl)imide (TFSI) have been widely used in polyethylene oxide (PEO)-based dry polymer electrolytes. Recent research has shown that plasticizing PEO with TFSI-based ionic liquids (ILs) can increase conductivity and Li+ diffusivity. However, the Li+ transport mechanism remains unchanged and is limited by the polymer host matrix. This study suggests a new paradigm of using more coordinating anions such as trifluoromethanesulfonyl-N-cyanoamide (TFSAM) to enhance Li+ transport and achieve higher Li+ transference number.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Marta Alvarez-Tirado, Laurent Castro, Shuai Qian, Jason E. Bara, Marco Di Gennaro, Konstantinos Gkagkas, Aurelie Gueguen, David Mecerreyes
Summary: A greener glyme derived from bio-sourced glycerol, TMP, shows promising performance as a solvent in Li-O-2 battery electrolytes, with high ionic conductivity and improved discharge capacity.
Article
Chemistry, Physical
Ju Sun, Isuru E. Gunathilaka, Luke A. O'Dell, Patrick C. Howlett, Maria Forsyth
Summary: The relationship between formation procedure and interfacial characteristics of electrodes in sodium-ion batteries is crucial for cell performance. We successfully shortened the formation time and improved the cycling performance of the sodium-ion half cell through optimized formation protocols in superconcentrated ionic liquid electrolytes. Our findings show that high C-rate formation contributes to a highly conductive and thinner solid-electrolyte interphase (SEI) layer, facilitating Na+ diffusion kinetics. This work provides a cost-effective and time efficient formation protocol for NIBs.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Maria Martinez-Ibanez, Nicola Boaretto, Alexander Santiago, Leire Meabe, Xiaoen Wang, Oihane Zugazua, Inigo Raposo, Maria Forsyth, Michel Armand, Heng Zhang
Summary: This paper reports a highly-concentrated FSI-based ternary gel polymer electrolyte (TGPE) with high lithium-ion conductivities, wide electrochemical stability, and superior compatibility with lithium metal electrode. The TGPE enables stable Li plating and stripping processes, as well as high discharge capacity of a Li||Li(Ni0.6Mn0.2Co0.2)O2 cell at ambient temperatures. This study not only provides safe and highly conductive polymer electrolytes but also enhances our understanding of the role of FSI anions in high-energy lithium metal batteries.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Gregorio Guzman-Gonzalez, Marta Alvarez-Tirado, Jorge L. Olmedo-Martinez, Matias L. Picchio, Nerea Casado, Maria Forsyth, David Mecerreyes
Summary: This article demonstrates the use of single-component electrolytes in lithium batteries based on new lithium borate ionic liquids at room temperature. The optimized lithium ionic liquids (LiILs) show high ionic conductivity, lithium transference numbers, and electrochemical stability. These LiILs also exhibit high compatibility with lithium-metal electrodes, resulting in excellent electrochemical performance in lithium-metal battery cells.
ADVANCED ENERGY MATERIALS
(2023)
Review
Nanoscience & Nanotechnology
Julen Castillo, Jose Antonio Coca-Clemente, Jokin Rikarte, Amaia Saenz de Buruaga, Alexander Santiago, Chunmei Li
Summary: Lithium-sulfur batteries (LSBs) are expected to enhance current lithium-ion devices, but the use of lithium metal as anode leads to degradation issues. Protecting the lithium metal anode has become a priority, and recent advancements in protection techniques are reviewed in this perspective. Strategies for achieving long-cycle-life, high-energy-density, and commercial LSBs are suggested, with a focus on scalability from laboratory to industry.
Article
Chemistry, Physical
Mojtaba Eftekharnia, Robert Kerr, Maria Forsyth, Patrick C. Howlett
Summary: In order to utilize the advantages of high energy density lithium-metal batteries, their cycle life and safety need to be improved. External compression has been shown to enhance the performance of these batteries by reducing dendrite growth and improving lithium deposition morphology. This study investigates the behavior of high-capacity Li||LFP pouch cells in pyrrolidinium-based ionic liquid electrolytes under different levels of compression and discusses the mechanisms that affect the cell performance and failure. The results indicate that higher compression leads to more uniform and less dendritic lithium deposition.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Julen Castillo, Alexander Santiago, Xabier Judez, Jose Antonio Coca-Clemente, Amaia Saenz de Buruaga, Juan Luis Gomez-Urbano, Jose Antonio Gonzalez-Marcos, Michel Armand, Chunmei Li, Daniel Carriazo
Summary: The increasing demand for electrical energy storage has led to the exploration of alternative battery technologies that can overcome the limitations of lithium-ion batteries. Lithium-sulfur batteries have attracted attention due to their low cost, high theoretical capacity, and sustainability. However, there are intrinsic limitations that need to be addressed for their commercialization. In this study, different formulations with functional carbonaceous additives were used to develop high-performing lithium-sulfur batteries. The additives improved the electrochemical properties of the sulfur cathodes, resulting in remarkable capacity and excellent C-rate response.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Biochemistry & Molecular Biology
Sharon Monaci, Daniela Minudri, Lorenzo Guazzelli, Andrea Mezzetta, David Mecerreyes, Maria Forsyth, Anthony Somers
Summary: Corrosion is a major problem that affects structures and buildings, leading to premature failure and economic loss. Biobased lignin and ionic liquids have shown potential as corrosion inhibitors. This study investigated the inhibitory properties of new biobased lignin ionic liquids and found that one of them exhibited promising performance.
Article
Multidisciplinary Sciences
Ziyu Song, Fangfang Chen, Maria Martinez-Ibanez, Wenfang Feng, Maria Forsyth, Zhibin Zhou, Michel Armand, Heng Zhang
Summary: The authors provide a personal reflection on the structural design of polymer electrolytes and propose possible ways to enhance their performance in rechargeable batteries. They emphasize the characteristics of solid polymer electrolytes and discuss the concept of coupled and decoupled electrolytes. The article aims to highlight the gaps in building ideal solid-state lithium metal batteries and stimulate research towards innovative electrolyte materials.
NATURE COMMUNICATIONS
(2023)
Article
Electrochemistry
Rafael Del Olmo, Gregorio Guzman-Gonzalez, Ilda O. Santos-Mendoza, David Mecerreyes, Maria Forsyth, Nerea Casado
Summary: Ion transport in composite electrodes is crucial for the performance of lithium-metal batteries, and the use of ionic conducting polymers as binders has been suggested. In this study, two poly(ionic liquid) polymers were analyzed as binders in LiFePO4 cathodes, and PMTFSI-Li showed the best performance with high specific capacity and long lifespan. Surprisingly, the presence of ionic binders also affected the lithium metal deposition morphology, leading to a more homogeneous plating and mitigating mossy lithium growth.
BATTERIES & SUPERCAPS
(2023)
Article
Chemistry, Physical
Letao Jin, Ziyu Song, Heng Zhang, Zhibin Zhou, Wenfang Feng
Summary: Alkali metal salts with trifluoromethanesulfonimide anions are potential electrolyte components for high-performance rechargeable batteries due to their stability. This study investigates the chemical properties of a crucial precursor H [ClTFSI] and discovers various reaction pathways, leading to the formation of new compounds, especially those with high thermal stability. It provides valuable guidance for the utilization of H [ClTFSI] as a building block for battery electrolytes.
Article
Materials Science, Multidisciplinary
Leire Meabe, Itziar Aldalur, Simon Lindberg, Mikel Arrese-Igor, Michel Armand, Maria Martinez-Ibanez, Heng Zhang
Summary: This strategic review critically analyzes the design strategies in the field of solid-state electrolytes (SSEs), summarizing the advantages and disadvantages of organic, inorganic, and hybrid/composite electrolytes, and provides a future perspective on the rapid development of solid-state lithium metal battery (SSLMB) technology.
Article
Chemistry, Physical
Brigette Althea Fortuin, Jon Otegi, Juan Miguel Lopez del Amo, Sergio Rodriguez Pena, Leire Meabe, Hegoi Manzano, Maria Martinez-Ibanez, Javier Carrasco
Summary: Model validation is used to predict the ionic structure and dynamics of alternative alkali metal ions in solid polymer electrolytes. A comprehensive study based on molecular dynamics is conducted to understand the ion coordination and transport properties. This approach can be extended to predict the performance of different alkali metal-based solid polymer electrolytes.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
