期刊
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
卷 38, 期 5, 页码 1258-1262出版社
HIGHER EDUCATION PRESS
DOI: 10.1007/s40242-022-2202-y
关键词
Single atom catalyst; Ball milling; ZIF-8; Ethylbenzene oxidation
资金
- National Key Research and Development Program Nanotechnology Specific Project, China [2020YFA0210900]
- Science and Technology Key Project of Guangdong Province, China [2020B010188002]
- Guangdong Natural Science Funds for Distinguished Young Scholar, China [2022B1515020035]
- Guangdong Provincial Key R&D Programme, China [2019B110206002]
- National Natural Science Foundation of China [22078371, 21938001, 21961160741]
- Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program, China [2017BT01C102]
- Natural Science Foundation of Guangdong Province, China [2020A1515011141]
- Science and Technology Project of Guangzhou City, China [202102020461]
Ce-1/NC catalyst prepared by ball milling method exhibits exceptional performance in the selective oxidation of saturated C-H bonds in aromatic compounds.
Through screening Ce precursors and pyrolysis temperatures [Ce(acac)(3) as Ce precursors and pyrolysis at 900 degrees C], zeolitic imidazolate framework-8(ZIF-8) derived nitrogen-doped carbon supported cerium single atom catalyst(Ce-1/NC) is successfully prepared by ball milling method. The Ce-1/NC catalyst exhibits exceptional catalytic performance in the selective oxidation of saturated C-H bonds in aromatic compounds, e.g., 91% conversion and 99% selelctivity can be achieved in the oxidation of ethylbenzene to acetophenone under mild reaction conditions.
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