期刊
CHEMICAL ENGINEERING JOURNAL
卷 442, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2022.136368
关键词
Organic photovoltaics; Layer-by-layer; Solvent additive; Photon harvesting; Molecular arrangement
资金
- National Natural Science Foundation of China [62105017, 61975006, 62175011]
- Postdoctoral Innovative Talent Support Program [BX20200042]
- China Post-doctoral Science Foundation [2020M680327]
- Beijing Natural Sci-ence Foundation [4192049]
By incorporating DPE and DIO, the orientation of PNTB6-Cl and BTP-4F-12 can be improved, leading to enhanced performance of LbL type OPV devices and increased power conversion efficiency.
In this work, layer-by-layer (LbL) type OPVs are constructed with wide bandgap polymer PNTB6-Cl as donor and nonfullerene material BTP-4F-12 as acceptor. The layered optimization strategy is employed via separately incorporating the diphenyl ether (DPE) and 1,8-diiodooctane (DIO) into PNTB6-Cl chlorobenzene solution and BTP-4F-12 chloroform solution. A power conversion efficiency (PCE) of 17.81% was achieved from the optimal LbL type OPVs with two solvent additives, which should be among the top level for LBL type binary OPVs. The incorporation of DPE and DIO can separately induce more ordered PNTB6-Cl and BTP-4F-12 orientation, which should contribute to charge transport with suppressed charge recombination in active layers. Meanwhile, BTP4F-12 crystallization is strongly increased with the incorporation of DIO, which should facilitate more swell matrix for exciton diffusion in active layers. Over 13% PCE improvement can be realized in LbL type OPVs by incorporating two additives, benefiting from simultaneously improved short circuit current density (JSC) of 26.89 mA cm-2 and fill factor (FF) of 75.79%. Meanwhile, the PCE of optimized LbL type OPVs is higher than that of 17.33% for the optimized OPVs with bulk-heterojunction (BHJ) configuration, which reveals that layered optimization strategy should be a promising approach to achieve highly efficient LbL type OPVs.
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