4.7 Article

Improving the performance of carbon/graphite composites through the synergistic effect of electrostatic self-assembled carbon nanotubes and nano carbon black

期刊

CERAMICS INTERNATIONAL
卷 48, 期 24, 页码 -

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ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.07.330

关键词

Carbon/graphite; Carbon nanotubes; Nano carbon black; Synergic effect; Coal tar pitch

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This study proposes a new method to improve the mechanical and electrical properties of carbon/graphite composites through the synergistic effect of NCB and CNTs. The results show that the synergistic effect significantly enhances the performance of the composites, reducing porosity and increasing interaction between CNTs and the matrix. The composites filled with CNTs/NCB also exhibit the lowest resistivity and highest thermal conductivity.
Superior performance fillers are considered as an effective means to enhance the performance of carbon/graphite composites. However, poor interfacial properties and incomplete filler networks limit the performance enhancement of the composites. In this study, a new method was proposed to weaken this impact through the synergistic effect of the electrostatic self-assembly of nano carbon black (NCB) onto carbon nanotubes (CNTs). The results showed that the synergistic effect between NCB and the CNTs significantly improved the mechanical and electrical properties of the composites. NCB reduces the porosity of the composites and increases the interaction between the CNTs and matrix. The compressive strength of the composite was 143.2 Mpa, and the flexural strength was 46.3 MPa, which is 210% higher than that of the pristine carbon/graphite composites. Moreover, NCB and CNTs form a globally connected synergistic network in the carbon skeleton. Composites filled with CNTs/NCB exhibited the lowest resistivity and highest thermal conductivity, with a resistance that was 42% lower than that of pristine carbon/graphite composites at 44.8 mu Omega m. All of these results suggest that the synergistic effect of CNTs/NCB show great potential to improve the performance of carbon/graphite composites.

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