Review
Chemistry, Multidisciplinary
Deepak Rawtani, Swath Satish, Piyush Rao
Summary: Industrial and academic communities are closely following the advancements in polymer nanocomposite technology, which aims to enhance specific characteristics through the combination of nanomaterials. The properties of resulting nanocomposites depend on factors such as the choice of clay, pretreatment, choice of polymers, and the method of incorporating polymers. The addition of nanoparticles to polymers significantly changes the properties of the composites, with the effects relying on the processing and surface treatment of the nanomaterials. Halloysite nanotubes (HNTs) have surface features that allow for surface modifications, and their inter-tubular and interfacial interactions with polymers enhance the thermal properties of the nanocomposites. Halloysite has been recognized as a suitable nanomaterial to improve the thermal stability and flame retardancy of resulting nanocomposites.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Ruina Zheng, Jiayu Hu, Zhichao Lin, Guozhang Wu, Yu Lin
Summary: In this study, lightweight and anisotropic PI/CNF composite aerogels with excellent thermal insulation and flame retardancy were successfully prepared using unidirectional drying and freeze drying methods. The composite aerogels exhibited a tube-like structure along the axial direction and a honeycomb-like pore structure along the radial direction, resulting in superior mechanical and elastic properties. The addition of CNF reduced the thermal conductivity of the composite aerogels. The composite aerogels also showed significant temperature reduction and flame retardant performance, making them promising for potential applications in the aerospace industry.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Construction & Building Technology
Xinhong Han, Shaoqiu Ding, Lingjun Zhu, Shurong Wang
Summary: Biomass aerogels with high porosity, low thermal conductivity, environmental friendliness, and sustainability have attracted attention. However, their general flammability limits their fire safety. This study proposes flame-retardant bio-based composite aerogels for building energy saving. Alginate is used as the basic skeleton, while noncombustible nano calcium carbonate and boric acid are introduced to enhance flame retardancy and thermal stability. The aerogels exhibit high porosity, excellent mechanical properties, and outstanding heat insulation. Natural shells, pearls, and eggshells are also used to substitute nano-CaCO3, showing potential fire resistance promotion. This biomass-derived material has the potential to be a significant green building material.
ENERGY AND BUILDINGS
(2023)
Article
Materials Science, Multidisciplinary
So-young Yoon, Hyewon Song, Sun Hwan Jeong, Yunchul Kim, Jun Hyuk Heo, Jung Heon Lee
Summary: This study fabricates a synergistic TA/ATP/CNF aerogel with exceptional features such as ultralightness, hydrophobicity, lipophilicity, fire resistance, and high thermal insulation by utilizing the unique properties of tannic acid (TA) and adenosine triphosphate (ATP) biomolecules. The aerogel outperforms other state-of-the-art aerogels and a computational algorithm using Python 3.6 is presented to analyze its highly porous structure. The study highlights the potential of using natural biomolecules to improve the properties of CNF aerogels.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Zhewen Ma, Xiaochen Liu, Xiaodong Xu, Lei Liu, Bin Yu, Cristian Maluk, Guobo Huang, Hao Wang, Pingan Song
Summary: This study presents a biomimetic strategy to design a polymeric coating with strong adhesion and flame-retardant properties, which can self-extinguish during vertical burning and release low heat and smoke, outperforming previous products.
Article
Nanoscience & Nanotechnology
Hai-Gang Shi, Hai-Bo Zhao, Bo-Wen Liu, Yu-Zhong Wang
Summary: The study reports a facile method to fabricate multifunctional EMI-shielding materials with a hybrid foam structure assembled with 3D MF foam, 1D AgNWs, and OD Fe3O4 nanoparticles, showing excellent absorption-dominant EMI-shielding performances. The hybrid foam also exhibits great flame retardancy, heat insulation, and potential for applications in both military and civilian fields. The coaction of AgNWs and Fe3O4 nanoparticles contributes to the high EMI-shielding effectiveness of the material.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Engineering, Environmental
Ying-Ming Li, Wen-Juan Hu, Shuang-Lin Hu, Yi-Ran Li, De-Yi Wang
Summary: Organic aerogels provide enhanced flame retardancy, thermal insulation, and mechanical properties for rigid polyurethane foam. The use of polyvinyl alcohol and adenosine triphosphate in the design of organic aerogels enables super thermal insulation, enhanced compressive strength, flame retardance, and smoke suppression.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Luhe Qi, Chang Chen, Lu Chen, Le Yu, Jing Huang, Sijun Wang, Zhen Wang, Xiaowen Shi, Chaoji Chen
Summary: A new type of bioplastic foam with low density, high compressive modulus, good thermal insulation performance, and superior fire resistance has been developed through an energy-efficient freeze-drying-free method. This foam is recyclable and biodegradable, making it a promising alternative to petroleum-based plastic foam.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Materials Science, Multidisciplinary
Chao Wei, Jinchuan Zhao, Guilong Wang, Jialong Chai, Zhanlin Shi, Peng Zhao, Yanxiang Wang
Summary: In this study, lightweight, thermally insulating, flame-retardant, and strong PVDF foams were prepared using microcellular foaming. The crystal forms, thermal insulation, flame retardancy, and compressive performance of the structure-tailored PVDF foams were investigated.
MATERIALS & DESIGN
(2022)
Article
Chemistry, Applied
Hualing He, Yushu Wang, Zhicai Yu, Jinru Liu, Yuhang Zhao, Yushi Ke
Summary: Bio-based aerogels show potential as eco-friendly, lightweight materials with excellent flame retardancy, offering promising prospects for applications in areas such as fire-protection clothing.
CARBOHYDRATE POLYMERS
(2021)
Article
Engineering, Environmental
Xuping Ni, Lingjie Wu
Summary: In this study, a novel flame retardant polyurethane phase change material was prepared by bonding polyethylene glycol with flame retardant element P. The results showed that the addition of flame retardant element P and polyethylene glycol improved the flame retardancy and thermal stability of the material, reaching a high level of flame retardant rating.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2023)
Article
Chemistry, Multidisciplinary
Jiaying Zhu, Yeling Zhu, Yuhang Ye, Zhe Qiu, Yifan Zhang, Zhengyang Yu, Xia Sun, David C. Bressler, Feng Jiang
Summary: A simple strategy for scalable production of hemp microfibers and their assembly into aerogels with interconnected porous structures via an ice-templating technique is reported. These aerogels demonstrate low density, high superelasticity, and over 80% compressive strain. They also exhibit low thermal conductivity due to high porosity and structural tortuosity, suggesting potential in thermal insulation applications. Hydrophobic modification further reduces water affinity of these aerogels.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Jiangan You, Jian Xue, Zhiwei Jiang, Tao Tang
Summary: The study successfully improved the cell density and thermal insulation performance of c-PVC foams using a combination of copper powder and molybdenum trioxide, achieving a high limiting oxygen index and reduced smoke density, which is beneficial for the design of high-performance c-PVC foams.
ADVANCED ENGINEERING MATERIALS
(2022)
Article
Engineering, Environmental
Hengrui Wang, Kexin Chen, Yongqian Shi, Yanjun Zhu, Songqiong Jiang, Yan Liu, Shijie Wu, Chenxin Nie, Libi Fu, Yuezhan Feng, Pingan Song
Summary: In this study, a new consolidating method was proposed to successfully fabricate flame-retardant thermoplastic polyurethane/bacterial cellulose/MXene/modified silicon carbide nanowires aerogel composites. The obtained composites exhibited excellent mechanical properties, electromagnetic interference shielding effectiveness, flame retardancy, and thermal insulation, making them suitable for various applications.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Hangzhen Zhang, Kun Wu, Enxiang Jiao, Yingchun Liu, Jun Shi, Mangeng Lu
Summary: This study presents a convenient and effective method for achieving high thermal conductivity and flame retardancy using precursor selection to prepare cellulose nanofiber/supramolecule-synthesized carbon nitride composites. The composites exhibited impressive thermal conductivity and enhanced flame retardancy, indicating potential for broader applications in thermal management.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Nadine J. Kanik, Artur Kuligiewicz, Jeffrey T. Cullen
Summary: This study examined the effects of different pre-treatments on the structural H-isotope composition of clay minerals. The results showed that different pre-treatments had varied impacts on different clay minerals, and the choice of pre-treatment should be based on the specific properties and mineralogy of the samples.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Lorenzo Lisuzzo, Giuseppe Cavallaro, Stefana Milioto, Giuseppe Lazzara
Summary: This study proposes Pickering emulsions based on wax and halloysite clay nanotubes for coating silk sutures to increase their loading capacity towards eosin. The presence of halloysite/wax microspheres on the surface of silk sutures has also been explored for controlled release of hydrophobic drugs. The influence of the coating on the thermal and mechanical properties of the sutures has been studied using various techniques. In conclusion, the wax/halloysite Pickering emulsions can successfully generate hydrophobic microdomains on the surface of silk sutures, leading to enhanced flexibility and improved loading capacity towards eosin.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Bruna F. Alves, Rita C. P. Nunes, Luiz C. Bertolino, Elizabete F. Lucas
Summary: Operational problems in the oil industry caused by the precipitation of paraffins can be prevented by using polymeric additives. This article evaluates the use of polymeric nanocomposites as pour point reducers in different types of crude oil and finds that they are more efficient than pure poly(ethylene-covinyl acetate) (EVA) in reducing the pour point. The nanocomposites also modify the wax crystals and reduce the viscosity of the oil samples.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
K. A. Daniels, C. C. Graham, A. C. Wiseall, J. F. Harrington, P. Sellin
Summary: Geological storage with clay buffer is widely preferred for removing hazardous radioactive waste. The impact of fluid salinity and void space on the swelling behavior of barrier bentonites was examined through experiments. The findings suggest that clay swelling is suppressed at higher salinities, which affects the void-filling process.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
N. Werling, A. Kuligiewicz, A. Steudel, R. Schuhmann, F. Dehn, K. Emmerich
Summary: Thermal treatment of clay minerals can be used to produce building materials and environmentally friendly binders. This process involves dehydration, dehydroxylation, breakdown of structure, and recrystallization of high temperature phases. Rehydration and rehydroxylation are important factors to consider for geopolymers and SCM.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Xuan Wang, Hao Ding, Zhuoqun Xu, Jianmeng Zhang, Yanbin Yao
Summary: Rutile nano-TiO2 was loaded onto the surface of sericite to prepare sericite-rutile composite particles, which were then modified with HDTMS and sprayed onto the substrates to form sericite-rutile/HDTMS composite coatings with UV shielding and superhydrophobic self-cleaning properties. The coating exhibited good UV shielding rate and remained superhydrophobic after UV irradiation. The hierarchical structure of the sericite-rutile composite and the low surface energy of HDTMS contributed to the superhydrophobicity and UV shielding effect of the coating.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Kailang Sun, Taojun Zhang, Jie Zhou, Yonghong Liu, Minfeng Zeng, Zhen Yang, Ruokun Feng, Xiaorong Ren, Peng Zhang, Baoyi Wang, Xingzhong Cao
Summary: Chitosan-Pd0 nano particles encapsulated in Al, Co-pillared montmorillonite nanocomposites were successfully synthesized using a facile one-pot heat treatment method. The Al, Co pillaring effectively expanded the surface area and generated numerous mesopores in the interlayer space of the MMt. The resultant nanocomposite exhibited similar high comprehensive catalytic performances as the one prepared by the regular divided-multistep method. The encapsulation of CS chains and doping of Co in the Al pillaring also contributed to the improved catalytic performance.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Nathalie Fagel, Isabel Israde-Alcantara, Reza Safaierad, Marttiina Rantala, Sabine Schmidt, Gilles Lepoint, Pierre Pellenard, Nadine Mattielli, Sarah Metcalfe
Summary: Environmental conditions significantly influence clay minerals, and studying clay sediments in tropical lakes can provide valuable insights into past environmental conditions. In this study, multiproxy records from sediment cores of three crater lakes in central Mexico were analyzed. The results showed that disordered kaolinite, formed through hydrolysis and hydrothermal alteration, was the predominant mineral in the sediments. The abundance of kaolinite varied in relation to organic carbon and organic matter-related elements, and showed opposite trends with lithogenic elements. Geochemical data suggested that the increase in kaolinite abundance is linked to the formation of organo-mineral aggregates and lake level changes in closed basins.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
M. J. Martin-Alfonso, A. Mejia, F. J. Martinez-Boza, P. Partal
Summary: The drilling industry is facing new challenges to develop eco-friendlier drilling fluids. Organic modified sepiolite dispersed in oil can be an excellent additive with suitable rheological properties. This study investigated the effect of alkyl ammonium modifiers on the microstructure and rheological properties of sepiolite-vegetable oil dispersions under high-temperature and high-pressure conditions.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Weiquan Zhan, Siyuan Yang, Shenxu Bao, Liuyi Ren, Cheng Liu
Summary: The interaction between talc and the depressor CMC was investigated through molecular dynamics simulation and density functional theory calculation. It was found that CMC showed stronger adsorption on the edge plane of talc due to enhanced interactions with polar groups and water molecules. The study also revealed specific interactions between H atoms in CMC and O atoms in the edge plane, as well as between O atoms in CMC and Si, Mg atoms in the edge plane. Hydration shells on the basal and edge planes of talc were examined to explain the phenomenon.
APPLIED CLAY SCIENCE
(2024)
Article
Chemistry, Physical
Pierre Dramou, Yiyang Sun, Xu Ni, Fangqi Wang, Hua He
Summary: In this study, a magnetic nanocomposite was prepared and used for the separation of rutin from real samples through magnetic solid phase extraction (MSPE). The nanocomposite exhibited high specific surface area, chemical and thermal stability, water solubility, and easy separation in aqueous solution. Characterization and experiments confirmed the successful synthesis and efficient enrichment ability of the nanocomposite.
APPLIED CLAY SCIENCE
(2024)