期刊
ENERGY & ENVIRONMENTAL MATERIALS
卷 6, 期 2, 页码 -出版社
WILEY
DOI: 10.1002/eem2.12342
关键词
ammonium ion battery; Iron(III) hexacyanoferrate; reversible Fe-N interaction; stability
The interaction between electrode materials and charge carriers is crucial for energy storage mechanisms. In this study, a weak and reversible Fe-N interaction was introduced and utilized to address the volume changes during intercalation or formation. X-ray absorption spectroscopy confirmed the balanced Fe-N interaction between the nitrogen of ammonium ions and high-spin Fe in FeHCF. The resulting material exhibited stable energy storage and high-rate performance.
The interaction between electrode materials and charge carriers is one of the central issues dominating underlying energy storage mechanisms. To address the notoriously significant volume changes accompanying intercalation or formation of alloy/compounds, we aim to introduce and utilize a weak, reversible Fe-N interaction during the (de)intercalation of ammonium ions (NH4+) within iron(III) hexacyanoferrate (FeHCF), inspired by manipulating the electrostatic adsorption between N and Fe in the early stages of ammonia synthesis (Bosch-Harber Process, Chemical Engineering) and steel nitriding processes (Metal Industry). Such strategy of switching well-balanced Fe-N interaction is confirmed in between the nitrogen of ammonium ions and high-spin Fe in FeHCF, as observed by using X-ray absorption spectroscopy. The resulting material provided an extremely stable energy storage (58 mAh g(-1) after 10 000 cycles at current density of 1 A g(-1)) as well as high-rate performance (23.6 mAh g(-1) at current density of 10 A g(-1)).
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