4.8 Article

Enable commercial Zinc powders for dendrite-free Zinc anode with improved utilization rate by pristine graphene hybridization

期刊

ENERGY STORAGE MATERIALS
卷 45, 期 -, 页码 465-473

出版社

ELSEVIER
DOI: 10.1016/j.ensm.2021.12.007

关键词

Pristine graphene; Zinc powder; Zinc anode; Aqueous zinc-ion batteries

资金

  1. National Natural Science Foundation of China [51971066, 51771058]
  2. Pearl River Tal-ent Program of Guangdong Province [2017GC010030]
  3. Guangdong Ba-sic and Applied Basic Research Foundation [21ZK0192]

向作者/读者索取更多资源

Uncontrollable dendrite growth and side reactions hinder the commercial applications of Zinc ion batteries. A practical non-dendrite zinc anode was designed by combining commercial zinc powders and pristine graphene. The anode exhibited low voltage hysteresis, long cycle life, and improved rate performance and energy density.
Uncontrollable dendrite growth and side reactions that arise at the Zn anode severely impede the commercial applications of Zinc ion batteries. In particular, the low utilization rate of Zinc metal often results in low energy density. Herein, a more practicable non-dendrite zinc anode was designed to replace traditional zinc foils by hybridization of commercial zinc powders and pristine graphene (PG). The formed three-dimensional PG net-work not only enhance adhesion between zinc powder particles forming stable Zn powder/PG hybrid electrode with enough mechanical strength but also uniformize the local electrical field as a redistributor, leading to non-dendritic Zinc metal plating/stripping in combination with crystalline plane induce effect of PG. As a result, extremely low voltage hysteresis of 89 mV and long cycle life over 360 h (vs. 349 mV and 30 h for zinc foil) at large current density of 5 mA cm(-2) are achieved for the Zn powder/PG anode. Notably, the Zn powder/PG anode can obviously enhance the rate performance and entire energy density of Zn||MnO2 full battery by nearly two times because of the higher utilization of Zn powder/PG anode. Therefore, this work provides new insight for designing practical zinc anode for high specific energy ZIB devices.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Mathematics, Interdisciplinary Applications

Carrier-Domain Method for high-resolution computation of time-periodic long-wake flows

Yang Liu, Kenji Takizawa, Tayfun E. Tezduyar, Takashi Kuraishi, Yufei Zhang

Summary: This article introduces a Carrier-Domain Method (CDM) for high-resolution computation of time-periodic long-wake flows, which is cost-effective and practical. The CDM utilizes a moving computational domain and high-resolution moving mesh to compute long-wake flows, providing a more cost-effective approach compared to fixed meshes. The results of the study demonstrate the effectiveness of CDM in high-resolution computation of time-periodic long-wake flows.

COMPUTATIONAL MECHANICS (2023)

Article Environmental Sciences

Biosolids and microorganisms synergistically enhance aggregate stability and organic carbon sequestration of bauxite residue

Tao Tian, Yufei Zhang, Feng Zhu, Wenshun Ke, Jiarong Fan, Zheng Liu, Shengguo Xue

Summary: Introducing biosolids and microorganisms into bauxite residue can improve aggregate stability and organic carbon content, promote plant growth, and facilitate ecological rehabilitation of bauxite residue.

LAND DEGRADATION & DEVELOPMENT (2023)

Article Chemistry, Multidisciplinary

Manipulating OW-Mediated Anode-Cathode Cross-Communication Toward Long-Life Aqueous Zinc-Vanadium Batteries

Dao-Sheng Liu, Zhaoyu Zhang, Yufei Zhang, Minghui Ye, Song Huang, Shunzhang You, Zijian Du, Jiangfeng He, Zhipeng Wen, Yongchao Tang, Xiaoqing Liu, Cheng Chao Li

Summary: The anode-cathode interplay is an important factor in the degradation of aqueous zinc ion batteries (AZIBs). In this study, Al-2(SO4)(3) is used as an electrolyte additive to manipulate OH-mediated communication between the Zn anode and NaV3O8.1.5H(2)O (NVO) cathode, improving the stability of V-based AZIBs. The hydrolysis of Al3+ creates a strong acidic environment, prolonging the anode lifespan and reducing interfacial OH accumulation. The acidified electrolyte alleviates undesired dissolution and phase transition, resulting in improved cycling stability for Zn parallel to NVO batteries.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Food Science & Technology

A novel and controllable method for simultaneous preparation of human milk fat substitutes (OPL, OPO and LPL): two-step enzymatic ethanolysis-esterification strategy

Yali Li, Yi Zhang, Yibin Zhou, Yufei Zhang, Mingming Zheng

Summary: This paper proposes a novel and effective two-step ethanolysis-esterification strategy for the controllable and simultaneous preparation of 1-oleoyl-2-palmitoyl-3-linoleoylglycerol (OPL), 1,3-dioleoyl-2-palmitoyl-glycerol (OPO), and 1,3-dilinoleoyl-2-palmitoyl-glycerol (LPL) with adjustable proportions. Enzymatic ethanolysis of fractionated palm stearin yields 2-monopalmitoylglycerol (79.4 +/- 0.6 %) with over 91.0 % purity. Using immobilized Candida sp. lipase (CSL) on octyl-functionalized ordered mesoporous silica (OMS-C8), 2-monopalmitoylglycerol is re-esterified with oleic acid and linoleic acid to produce OPL, OPO, and LPL simultaneously.

FOOD RESEARCH INTERNATIONAL (2023)

Article Agriculture, Multidisciplinary

D-Arabitol Ameliorates Obesity and Metabolic Disorders via the Gut Microbiota-SCFAs-WAT Browning Axis

Xiaolan Li, Jian Huang, Junhua Yun, Guoyan Zhang, Yufei Zhang, Mei Zhao, Hossain M. Zabed, Yuvaraj Ravikumar, Xianghui Qi

Summary: D-arabitol, found in mushrooms, lichens, and higher fungi, may alleviate visceral fat accumulation and insulin resistance due to its low calorie and glycemic index. This study reveals that D-arabitol improves body weight gain and fat accumulation through the gut microbiota-SCFAs-WAT browning axis, by increasing the abundance of certain genera and promoting the production of short-chain fatty acids.

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2023)

Article Green & Sustainable Science & Technology

Sustainable biosynthesis of 3-hydroxypropionic acid from crude glycerol: Metabolic engineering and process optimization

Yufei Zhang, Junhua Yun, Lei Zhou, Guoyang Zhang, Mei Zhao, Hossain M. Zabed, Xianghui Qi

Summary: To achieve carbon neutrality and carbon peaking goals, sustainable biomanufacturing of high-value chemicals such as 3-hydroxypropionic acid (3-HP) through metabolic engineering of Escherichia coli has been explored. Efforts were made to optimize the biosynthetic pathway, enhance glycerol uptake, and improve the production of 3-HP through genetic engineering and process optimization. The use of corn steep liquor as a cheap fermentation medium further enhanced the production of 3-HP. Co-fermentation of crude glycerol with glucose and acetic acid resulted in high yields and productivity of 3-HP.

JOURNAL OF CLEANER PRODUCTION (2023)

Article Chemistry, Analytical

A high-performance liquid chromatography-tandem mass spectrometry method for quantification of perampanel in human plasma: Effect of concomitant anti-seizure medications on perampanel concentration in patients with epilepsy

Yu-Fei Zhang, Yue Yu, Ming-Kang Zhong, Xun-Yi Wu, Chun-Lai Ma

Summary: A rapid and sensitive HPLC-MS/MS method was developed to quantify perampanel in human plasma. The method showed good linearity, accuracy, and precision, and successfully determined the plasma concentrations of perampanel in patients.

JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS (2023)

Article Chemistry, Physical

Unique interlayer chemical environment induced stable zinc plating/stripping via a Zn-based magadiite artificial interphase

Zijian Du, Yufei Zhang, Minghui Ye, Yongchao Tang, Xiaoqing Liu, Cheng Chao Li

Summary: A protective coating layer of zinc-based magadiite layered nanosheets (Mag-Zn) is developed to address the crucial drawbacks in aqueous zinc-ion batteries. The coating layer acts as a physical isolation to reduce corrosion and hydrogen evolution, and also inhibits the formation of by-products, mitigating dendrite growth for stable plating/stripping performance.

JOURNAL OF POWER SOURCES (2023)

Review Chemistry, Physical

Designing strategies of advanced electrode materials for high-rate rechargeable batteries

Jiaqi Ke, Yufei Zhang, Zhipeng Wen, Song Huang, Minghui Ye, Yongchao Tang, Xiaoqing Liu, Cheng Chao Li

Summary: Fast charging is crucial for the widespread adoption of electric vehicles and portable electronics, however, the range anxiety caused by limited range and long charging time hampers their adoption. The development of rechargeable batteries with structurally stable materials and high-rate performance is vital. This review provides an overview of advanced anode and cathode materials in recent years and summarizes design strategies for achieving high-rate charging performance. It also discusses modified design strategies for overcoming high-rate limitations and the development of charging protocols.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Physical

Cobalt-nickel bimetallic sulfide (NiS2/CoS2) based dual-carbon framework for super sodium ion storage

Qixiang Deng, Xinlong Liu, Zhiyong Li, Haosen Fan, Yufei Zhang, Hui Ying Yang

Summary: Designing hybrid metal sulfide-based anode materials is an effective method to enhance the performance of sodium-ion batteries (SIBs). However, the capacity of sulfide-based anodes decreases significantly due to volume expansion during charge/discharge processes. In this study, concaved NiS2@CoS2 nano-cubes (NCSC) were successfully prepared through chemical etching of Ni-Co coordination polymers (NiCoCP) precursor. The obtained NCSC anode materials exhibited a high specific sodium storage capacity of 848 mAh g-1 at 0.1 A g-1 and a stable cyclability of 572 mAh g-1 at 5 A g-1 after 830 cycles. This unique etching strategy provides a novel approach for the design and fabrication of high-performance anode materials for SIBs.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Environmental Sciences

Rapid conversion of alkaline bauxite residue through co-pyrolysis with waste biomass and its revegetation potential

Yujun Wu, Yufei Zhang, Qihou Li, Jun Jiang, Yifan Jiang, Shengguo Xue

Summary: In this study, co-pyrolysis of bauxite residue and sawdust was used to produce a soil-like matrix that supported plant growth. The treated samples were characterized to understand the changes in physicochemical, mineral weathering, and microbial communities. The results showed significant improvements in the properties of the treated bauxite residue, indicating its potential as an artificial soil substitute.

JOURNAL OF ENVIRONMENTAL SCIENCES (2023)

Article Chemistry, Physical

Diminishing Space-Charge Layer Effect of Zinc Anodes by an Anion-Immobilized Electrolyte Membrane

Yang Yang, Haiming Hua, Zeheng Lv, Weiwei Meng, Minghao Zhang, Hang Li, Pengxiang Lin, Jin Yang, Guanhong Chen, Yuanhong Kang, Zhipeng Wen, Jinbao Zhao, Cheng Chao Li

Summary: By immobilizing SO42- anions on amide groups of polymer chains, a Kevlar-derived hydrogel (KevlarH) electrolyte is proposed to reduce the space-charge layer effect and solve the Zn dendrite issue in Zn metal batteries. The relatively weak interaction between Zn2+ cations and carbonyl groups allows for redistribution of Zn2+-ion flux without sacrificing ion diffusion rate. The synergistic zincophilic and anionphilic building blocks enable dendrite-free Zn deposition and suppressed side reactions, extending the lifespan of a Zn metal anode up to 3500 h with an ultrahigh Coulombic efficiency of 99.87%. Importantly, the KevlarH electrolyte can be directly used in high-voltage bipolar ZMBs, breaking the 2 V barrier in aqueous ZMBs.

ACS ENERGY LETTERS (2023)

Article Chemistry, Physical

Designing Soft Solid-like Viscoelastic Zinc Powder Anode toward High-Performance Aqueous Zinc-Ion Batteries

Chuheng Cao, Keqin Zhou, Wencheng Du, Cheng Chao Li, Minghui Ye, Yufei Zhang, Yongchao Tang, Xiaoqing Liu

Summary: In this study, a soft solid-like viscoelastic Zn powder composite (ss-ZnP) anode based on a rheological oligomer (E-44) gluing strategy is proposed. The ss-ZnP anode exhibits enhanced ion/electron transport and alleviated volume effect, leading to excellent electrochemical performance in Zn-ion batteries. Furthermore, the excellent malleability of ss-ZnP greatly facilitates the assembly of various types of batteries.

ADVANCED ENERGY MATERIALS (2023)

Review Chemistry, Multidisciplinary

Renewable lignin and its macromolecule derivatives: an emerging platform toward sustainable electrochemical energy storage

Xueru Yang, Yufei Zhang, Minghui Ye, Yongchao Tang, Zhipeng Wen, Xiaoqing Liu, Cheng Chao Li

Summary: The conversion of natural renewable resources to high-value chemical products for electrochemical energy storage is an effective measure to alleviate the energy crisis. Lignin, as the second largest renewable biomass material, has been successfully utilized for constructing sustainable energy storage devices. This review provides a comprehensive overview of recent advances in lignin-based macromolecules as key components in energy storage devices, including organic electrodes, binders, electrolytes, and separators. The challenges and prospects in this area are also discussed, aiming to promote the rational design of advanced lignin-based materials for sustainable development.

GREEN CHEMISTRY (2023)

Article Chemistry, Physical

Quantifying the impact of operating temperature on cracking in battery electrodes, using super-resolution of microscopy images and stereology

Orkun Furat, Donal P. Finegan, Zhenzhen Yang, Matthias Neumann, Sangwook Kim, Tanvir R. Tanim, Peter Weddle, Kandler Smith, Volker Schmidt

Summary: The operating temperature has a significant impact on the degradation behavior of batteries. This study investigates the structural degradation of lithium-ion positive electrodes under different operating temperatures, and finds that particle porosity increases with higher cycling temperature, while particle surface area remains similar across different cycling-temperature aging conditions.

ENERGY STORAGE MATERIALS (2024)

Article Chemistry, Physical

Ion-intercalation architecture for robust functionalization of two-dimensional MXenes

Junyan Li, Ming Lu, Weijia Zheng, Wei Zhang

Summary: MXenes are two-dimensional materials with unique structures and properties, which have attracted significant scientific interest. Ion intercalation, as an important mechanism, plays a crucial role in regulating the electronic and chemical properties of MXene materials. This review provides an overview of the interaction events between ions and MXenes, including advanced characterization techniques, influencing factors, mechanisms, and functionalization roles of ion intercalation.

ENERGY STORAGE MATERIALS (2024)

Article Chemistry, Physical

Zwitterion as electrical double layer regulator to in-situ formation of fluorinated interphase towards stable zinc anode

Zhengtai Zha, Tianjiang Sun, Diantao Li, Tao Ma, Weijia Zhang, Zhanliang Tao

Summary: A novel zwitterion additive is developed to improve the electrochemical performance and cycling stability of aqueous zinc batteries. The zwitterion forms a stable solid electrolyte interphase on the electrode surface, isolating the zinc anode from the electrolytes and enabling fast zinc ion migration. The proposed electrolyte shows promising results in symmetric cells and full cells, with long cycling stability and high capacity retention.

ENERGY STORAGE MATERIALS (2024)

Article Chemistry, Physical

Promoting homogeneous lithiation of silicon anodes via the application of bifunctional PEDOT:PSS/PEG composite binders

Nyung Joo Kong, Myeong Seon Kim, Jae Hyun Park, Jongbok Kim, Jungho Jin, Hyun-Wook Lee, Seok Ju Kang

Summary: Polymeric conducting binders have significant research value as they can serve as both binders and conducting agents, increasing the proportion of active materials in batteries and the volumetric energy density. This study explores the potential of a composite of PEDOT:PSS and polyethylene glycol (PEG) as a high-performing binder for silicon anodes. The addition of PEG polymer enhances the conductivity of PEDOT:PSS and improves the mechanical properties of the silicon anode, resulting in extended cycle endurance. The use of operando optical microscopy allows for direct observation of the binder's operation. Consequently, the bifunctional PEDOT:PSS/PEG binder shows promise for high-performance lithium-ion battery binders.

ENERGY STORAGE MATERIALS (2024)

Article Chemistry, Physical

Temperature-dependent viscoelastic liquid MOFs based cellulose gel electrolyte for advanced lithium-sulfur batteries over an extensive temperature range

Yangze Huang, Lixuan Zhang, Jiawen Ji, Chenyang Cai, Yu Fu

Summary: This study proposed a novel temperature-dependent viscoelastic liquid electrolyte and a hollow transition bi-metal selenide as the sulfur host material to address the issues in Li-S batteries. The experiments showed promising results in stabilizing the anode and improving cycling performance.

ENERGY STORAGE MATERIALS (2024)

Article Chemistry, Physical

Recent advances in anode design for mild aqueous Zn-ion batteries

Ao Yu, Wei Zhang, Nimanyu Joshi, Yang Yang

Summary: This review provides a comprehensive overview of research progress in ZIB anodes, including protective coating layers on zinc surfaces and intercalated anode materials. By designing protective coating layers and selecting appropriate intercalated anode materials, the inherent limitations of zinc metal anode can be overcome, leading to improved reliability and performance of ZIBs.

ENERGY STORAGE MATERIALS (2024)

Article Chemistry, Physical

Sandwich-structured anode enables high stability and enhanced zinc utilization for aqueous Zn-ion batteries

Xin Wang, Yumiao Tian, Konghua Yang, Chenhui Ma, Wenqiang Lu, Xiaofei Bian, Nan Chen, Heng Jiang, Yan Li, Xing Meng, Pengyue Gao, Dong Zhang, Fei Du

Summary: Researchers developed a new sandwich deposition approach using boron nitride layer as a current collector, which enhances the performance of aqueous zinc-ion batteries.

ENERGY STORAGE MATERIALS (2024)

Article Chemistry, Physical

Stable sodium-metal batteries with a hierarchical structured electrode toward reversible confinement of Na dendrites

Sang Jun Lee, Dongwoo Kang, Dong Yeol Hyeon, Dong Seok Kim, Suyoon Eom, Su Hwan Jeong, Dong Park Lee, Dawon Baek, Jou-Hyeon Ahn, Gyeong Hee Ryu, Kwi-Il Park, San Moon, Joo-Hyung Kim

Summary: This study utilizes the ice-templating method to create a self-supporting three-dimensional hierarchical porous structure, which effectively inhibits sodium dendrite growth and improves the performance and longevity of sodium-metal batteries.

ENERGY STORAGE MATERIALS (2024)

Article Chemistry, Physical

Enable reversible conversion reaction of copper fluoride batteries by hydroxyl solution and anion acceptor

Yifan Yu, Meng Lei, Yangyang Liu, Keyi Chen, Chuanzhong Lai, Jiulin Hu, Chilin Li

Summary: Metal fluorides as conversion-reaction cathodes have advantages such as low cost, environmentally friendly, and high energy density. In this study, a hydroxyl-rich copper fluoride (Cu2(OH)3F) was proposed as a conversion cathode, coupled with an electrolyte additive engineering, to address the poor reversibility issue. The presence of OH in Cu2(OH)3F enables effective suppression of Cu+ dissolution, resulting in better reaction reversibility and kinetics.

ENERGY STORAGE MATERIALS (2024)