期刊
ENERGY STORAGE MATERIALS
卷 45, 期 -, 页码 568-577出版社
ELSEVIER
DOI: 10.1016/j.ensm.2021.12.002
关键词
Vanadium oxide; Zn-ion battery; Ion-intercalation regulation; V- 2 CT (x) MXene; High-rate
资金
- National Natural Science Foundation of China [51972064]
MXene-derived hydrated vanadates, designed through ion intercalation and phase transition, exhibit superior electrochemical performance and cycling stability in Zn-ion batteries. The concept can also be generalized to fabricate other MXene derivatives.
Vanadium oxides are promising cathode materials for Zn-ion batteries (ZIBs) because of their high electrochemical performance. However, its low conductivity remains to be the major obstacle for further utilization. Even the conventional introduction of conductive substrate cannot maintain the structural stability of the composite during cycling. Herein, a universal strategy is proposed to fabricate high-rate cathodes by rationally designing the heterostructure through one-step ion intercalation and phase transition of MXene-derived hydrated vanadates. The hydrated vanadate inherits the intrinsic conductivity from MXene, which can promote faster Zn2+ diffusion kinetics. Therefore, Mn2+-intercalated V10O24.nH(2)O derived from V2CTx as the prototype cathode material shows superior rate capacity and cycling stability (289.6 mAh g(-1) at 10 A g(-1) after 25,000 cycles with 92.9% retention). Furthermore, the derivatization strategy is extended to Li(+ )and Al3+ intercalated hydrated vanadates, which also present excellent electrochemical performances. Successful extension indicates that the concept not only presents a blueprint for the development of robust multi-valent ion batteries but also can be generalized to fabricate varied MXene derivatives for wider applications.
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