Article
Materials Science, Multidisciplinary
Huayin Wen, Min Wang, Shikai Luo, Yuanlin Zhou, Tao Liu
Summary: A scalable and blending route using silicone rubber (SR) with different crosslinking temperature compared to EPDM was developed to improve the mechanical properties of EPDM foams. The addition of SR in the pre-crosslinking process of EPDM forms a complete crosslinking network, enhancing the compatibility between EPDM and SR and improving the mechanical properties of EPDM foams. When comparing SR/EPDM foam with traditional EPDM foam, the former shows significantly increased tensile strength and compressive strength at similar foam densities, reaching a maximum tensile strength and compressive strength of 3.58 MPa and 0.59 MPa, respectively.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2021)
Article
Polymer Science
Xiaoping Yang, Jianfeng Tian, Jun Dong
Summary: By adding n-CuO, the friction mechanism of fluorosilicone rubber is changed, resulting in reduced friction coefficient and wear loss, enhancing the friction properties of the rubber matrix. Additionally, the tearing property of FVMQ is improved by altering the crosslinking density with the addition of n-CuO.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Zhaoyang Wang, Yankai Lin, Zhanxu Li, Yumeng Yang, Jun Lin, Shaojian He
Summary: To enhance the hydrophobicity and low-temperature resistance of silicone rubber, methyl vinyl silicone rubber and fluorosilicone rubber blend composites were prepared. The addition of a small amount of fluorosilicone rubber significantly improved the low-temperature resistance and hydrophobicity of the composites.
Article
Materials Science, Multidisciplinary
Shen Diao, Mingying Wang, Yuqiang Zhang
Summary: Vinyl silicone oil containing perfluorocyclobutyl aryl ether in the backbone (PFCB-VSO) was prepared and used as a non-telechelic crosslinker in the design of fluorosilicone rubber. The mechanical properties, thermal properties, and hydrophobic properties of the rubber were improved by the addition of PFCB-VSO. The study also investigated the cross-link network and demonstrated the effect of PFCB-VSO on cross-link density.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Materials Science, Multidisciplinary
Shen Diao, Mingying Wang, Yuqiang Zhang
Summary: PFCB-VSO has significant effects on the mechanical properties, thermal properties, and hydrophobic properties of fluorosilicone rubber, enhancing the non-telechelic cross-link network to improve mechanical performance, and increasing thermal stability and hydrophobicity.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Construction & Building Technology
Manjun Li, Hongyuan Fang, Chao Zhang, Mingrui Du, Fuming Wang
Summary: Two-component polyurethane with different foaming ratios was obtained by adjusting the ratio of each component and foaming in water. The polyurethane with a foaming ratio of 16 was selected as the most suitable for foaming in water and its mechanical properties were deeply studied. The results showed that the strength of polyurethane increased with density and decreased with soaking time.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Chemistry, Physical
Xiaomin Liu, Zhao Chen, Zhenggang Cui
Summary: This paper proposes a mixed surfactant system that can achieve both ultralow oil/water interfacial tension and high foaming performance simultaneously. Under the reservoir conditions of Daqing oilfield, the ternary surfactant mixture SDS/DTAB/APG was found to be the optimal surfactant system. The study demonstrates that this surfactant system can achieve ultralow interfacial tension and high foaming performance over a wide range of total concentrations.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Polymer Science
Jae Il So, Chung Soo Lee, Byeong Seok Kim, Hyeon Woo Jeong, Jin Sung Seo, Sung Hyeon Baeck, Sang Eun Shim, Yingjie Qian
Summary: This study successfully prepared F-LSR-POSS by using POSS-V as a chemical crosslinking agent. Various testing methods such as FT-IR, H-1-NMR, SEM, and XRD confirmed the uniform dispersion of POSS-V in F-LSR-POSS. The mechanical strength and crosslinking density of F-LSR-POSS were determined using UTM and DMA, respectively, showing a significant improvement in heat resistance compared to conventional F-LSR. The introduction of POSS-V as a chemical crosslinking agent overcame the poor heat resistance of F-LSR.
Article
Chemistry, Multidisciplinary
Kesong Yu, Yi Wu, Xiaoli Zhang, Junji Hou, Jingbo Chen
Summary: This study successfully prepared high-expansion poly(lactic acid)/poly(lactic acid) foam with excellent oil-water separation performance, and demonstrated its advantages in adsorption capacity, adsorption-desorption cycles, and heat resistance.
JOURNAL OF CO2 UTILIZATION
(2022)
Article
Engineering, Environmental
Xu Zhao, Rongcheng Du, Xuelian Chen, Xiangyue Wei, Yuwei Long, Xuehui Liu, Li Chen, Shimei Xu, Yu-Zhong Wang
Summary: High-efficiency and energy-saving conversion of epoxy thermosets into high value, high quality, and high-performance products is desired for environmental protection and resource utilization. A new strategy for mild degradation of epoxy thermosets and in situ preparation of polyurethane foam from degradation solutions is demonstrated. The degradation solution contains unreacted solvent polyethylene glycol and polyol degradation products, which can react with isocyanate to produce polyurethane. The use of an insoluble catalyst enables in-situ foaming of the degradation solution, allowing for direct and full utilization of degradation products. The rigid epoxy skeleton of the degradation products contributes to the high mechanical properties, thermal insulation performance, low water absorption, regular pore structure, and thermal stability of the obtained polyurethane foam, making it a promising candidate for building insulation materials.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Applied
S. Padma Ishwarya, P. Nisha
Summary: The study isolated foaming fractions from spent coffee grounds to investigate their foam properties. Results showed that a high molecular weight foaming fraction from defatted robusta spent coffee grounds exhibited higher surface activity, comparable foam stability, and greater foamability than synthetic surfactants. Additionally, coffee oil was found to act as an antifoam agent by retarding the foam-forming and stabilizing activities of both spent coffee grounds-based and synthetic foaming agents.
FOOD HYDROCOLLOIDS
(2021)
Article
Construction & Building Technology
Kirubajiny Pasupathy, Sayanthan Ramakrishnan, Jay Sanjayan
Summary: This study investigates the method of enhancing the foaming behavior in geopolymer foam concrete using a superplasticizer. The results show that the dosage of superplasticizer significantly affects the expansion behavior of the concrete.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jiawei Lu, Hong Zhang, Yuemiao Chen, Yukai Ge, Tao Liu
Summary: Thermoplastic polyether ester elastomer (TPEE) foams were studied in this research, focusing on the effect of chain entanglement on mechanical properties, viscoelasticity, and CO2-foaming behavior. It was found that samples with stronger chain entanglement exhibited increased rigidity and reduced ductility, along with improved linear and nonlinear viscoelasticity. Additionally, the modified TPEE samples showed a higher expansion ratio and a wider foaming temperature window during the CO2-foaming process.
JOURNAL OF CO2 UTILIZATION
(2022)
Article
Materials Science, Multidisciplinary
Pengwei Song, Yuan Zhang, Yong Luo, Xia Liao, Wanyu Tang, Jianming Yang, Chenxu Tian, Guangxian Li
Summary: In this study, silicone rubber foams with different cell sizes were designed using supercritical CO2 foaming technology. The correlations between cellular structure and compression properties were investigated, and it was found that increasing the cell size can improve deformation recovery capability, reduce permanent compression set, and shorten recovery time of silicone rubber foams.
JOURNAL OF MATERIALS SCIENCE
(2022)
Article
Chemistry, Physical
Fujun Sheng, Jie Zhang, Shuang Yang, Guangyu Sun, Chuanxian Li, Fei Yang, Bo Yao, Xiaobin Jiang, Yangyang Zhou
Summary: In this study, the effects of crude oil viscosity and wax precipitation on foaming characteristics were investigated using the depressurization method. The results showed that the foamability of crude oil tends to decrease with increasing temperature below the wax appearance temperature (WAT). However, above the WAT, the foamability weakens drastically and remains relatively constant with temperature. The dominant factor affecting foamability was found to be the temperature-induced change in oil phase viscosity. Additionally, the foam stability decreased significantly with increasing temperature, which was attributed to the decrease in interfacial dilational modulus and the weakened film strength at the crude oil-CO2 interface.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Review
Engineering, Chemical
Jun Yan, Qin Su, Wei Xiao, Zefeng Wu, Lanfen Chen, Longcheng Tang, Nan Zheng, Jiefeng Gao, Huaiguo Xue
Summary: This article provides a summary of the latest developments in solar interface evaporation (SIE) materials based on nanofiber membranes. The mechanism, difficulties, and solutions in material preparation, light absorption, thermal management, water transportation, and multifunctionalization are discussed. The review primarily focuses on the evaporation efficiency, salt resistance performance, corrosion resistance, and long-term stability of SIE materials. Finally, the challenges and outlook of nanofiber-based SIE materials are proposed.
Article
Nanoscience & Nanotechnology
Cheng-Fei Cao, Bin Yu, Zuan-Yu Chen, Yong-Xiang Qu, Yu-Tong Li, Yong-Qian Shi, Zhe-Wen Ma, Feng-Na Sun, Qing-Hua Pan, Long-Cheng Tang, Pingan Song, Hao Wang
Summary: In this study, a smart fire alarm sensor (FAS) material with mechanically robust, excellent flame retardancy, and ultra-sensitive temperature-responsive capability was developed. By decorating graphene oxide (GO) sheets with a multi-amino molecule, the optimized GO/HCPA hybrid network exhibited significant improvement in mechanical strength and comprehensive fire safety performance. Furthermore, a fireproof coating based on the GO/HCPA network showed exceptional fire shielding performance when applied in polymer foam.
NANO-MICRO LETTERS
(2022)
Review
Chemistry, Multidisciplinary
Lei Liu, Jiabing Feng, Yijiao Xue, Venkata Chevali, Yubai Zhang, Yongqian Shi, Long-Cheng Tang, Pingan Song
Summary: Frequent fire disasters have caused significant impacts on the environment, humans, and the economy. MXene is a potential flame retardant that can provide passive fire protection and active fire response through its physical barrier and thermoelectric effect. This article provides an overview of passive flame-retardant materials and next-generation smart fire warning materials/sensors based on MXene, discussing their design, characterization, performance, applications, and challenges for future practical use.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Engineering, Multidisciplinary
Yang Li, Man Li, Yong-Cheng Zhu, Seunghyun Song, Shi-Neng Li, Jolyon Aarons, Long-Cheng Tang, Joonho Bae
Summary: This study reports a multifunctional separator composed of DNA-carbon nanotube (CNT) and Ti3C2Tx MXene hybrid-modified polypropylene (PP) for lithium-sulfur (Li-S) batteries. The optimized 3D interconnected networks formed by DNA, CNT, and MXene exhibit excellent capability for shuttled polysulfides and improved electrolyte wettability. Additionally, they demonstrate high-temperature tolerance and flame retardancy, making them suitable for stable and high-safety Li-S batteries.
COMPOSITES PART B-ENGINEERING
(2023)
Article
Materials Science, Composites
Zhi-Hao Wu, Xiao-Lan Feng, Yong-Xiang Qu, Li-Xiu Gong, Kun Cao, Guo-Dong Zhang, Yongqian Shi, Jie-Feng Gao, Pingan Song, Long-Cheng Tang
Summary: In this study, silane modified MXene and polybenzazole (F-MP) nanocomposite aerogels were prepared using sol-gel, freeze-dry, and thermal treatment methods. The nanocomposite aerogel showed low density, good surface hydrophobicity, flame retardancy, and thermal insulation performance. The optimized FMP aerogel exhibited low density, good surface hydrophobicity, and mechanical robustness. Additionally, it displayed reliable flame resistance and structural stability, and superior thermal insulation compared to traditional polymer foam materials. This work presents an innovative strategy for developing hydrophobic, flame retardant, and thermal insulating aerogel materials with promising applications.
COMPOSITES COMMUNICATIONS
(2023)
Article
Engineering, Chemical
Lanfen Chen, Yongchuan Wu, Wenqian Xing, Qin Su, Longcheng Tang, Huaiguo Xue, Jiefeng Gao
Summary: Three dimensional composite hydrogels have been developed for solar-driven interfacial evaporation, addressing the challenges of high-performance hydrogel evaporators in terms of mechanical properties, evaporation efficiency, and durability. The composite hydrogel evaporator, with uniformly dispersed acidified carbon nanotubes (ACNTs), exhibits excellent mechanical properties and has high evaporation rate and photothermal conversion efficiency. It demonstrates outstanding salt rejection performance and long-term durability, making it a promising candidate for solar desalination applications.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Green & Sustainable Science & Technology
Guojun Deng, Mengnan Sun, Yongqian Shi, Yuezhan Feng, Yuancai Lv, Longcheng Tang, Jiefeng Gao, Pingan Song
Summary: In this study, PU-Ti3C2Tx-MOF sponges with superior hydrophobicity and adsorption capacity were prepared. They exhibited rapid adsorption ability for liquid hazardous chemicals and maintained good reusability. This work provides a new pathway for the design of functional polymer sponges and their potential application in rapid elimination of leaked hazardous chemicals.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Materials Science, Multidisciplinary
Miao Liu, Kexin Chen, Yongqian Shi, Hengrui Wang, Shijie Wu, Ruizhe Huang, Yuezhan Feng, Longcheng Tang, Xiaohuan Liu, Pingan Song
Summary: This study developed multifunctional polymeric materials with high fire safety, excellent mechanical performances, and electromagnetic interference shielding properties, which have great potential for practical applications.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Biochemistry & Molecular Biology
Tian-Long Han, Bi-Fan Guo, Guo-Dong Zhang, Long-Cheng Tang
Summary: We report a green, simple and low-cost strategy to synthesize ultra-low-density porous silicone composite materials using Si-H cross-linking and foaming chemistry. Sialylation-modified hollow glass microspheres were used to promote the compatibility between hollow microspheres and polydimethylsiloxane (PDMS). The modified PDMS foam composites showed excellent mechanical flexibility and good thermal insulation.
Article
Polymer Science
Mengmeng Zhou, Xiaohui Liu, Fengjiao Xu, Yongbing Pei, Lianbin Wu, Long-Cheng Tang
Summary: A durable superhydrophobic fabric was successfully fabricated through a facile UV-induced surface covalent modification strategy. The strategy involved the covalent grafting of 2-isocyanatoethylmethacrylate (IEM) and dodecafluoroheptyl methacrylate (DFMA) onto the fabric's surface, resulting in the formation of rough structures and the grafting of low-surface-energy substances. The modified fabric exhibited excellent superhydrophobicity and durability, making it promising for efficient oil-water separation.
Article
Engineering, Multidisciplinary
Miao Liu, Kexin Chen, Yongqian Shi, Shijie Wu, Yuezhan Feng, Libi Fu, Jiefeng Gao, Longcheng Tang, Fuqiang Yang
Summary: Researchers have developed a feasible and low-cost method to prepare mechanically robust TPU/PZM@CP/CF nanocomposites, which possess enhanced fire retardancy and EMI shielding performances. The nanocomposites exhibit excellent mechanical toughness and superior EMI shielding effectiveness. Furthermore, the thermal stability and fire resistance of the nanocomposites are significantly improved.
COMPOSITES PART B-ENGINEERING
(2023)
Article
Chemistry, Physical
Jun Yan, Yongchuan Wu, Zheng Guo, Qin Su, Wenqian Xing, Jing Wen, Longcheng Tang, Junwei Zha, Jiefeng Gao
Summary: Chemical spills, especially oil spills, are becoming an increasingly serious environmental issue. In this study, an environmentally friendly emulsion spray-coating method is proposed to fabricate durable foam composites with asymmetric wettability for oil-water separation. The foam composite exhibits gradient wettability and can separate oils with different densities, with a high separation efficiency for chloroform.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Wen-Yu Hu, Ke-Xin Yu, Qi-Na Zheng, Qi-Liang Hu, Cheng-Fei Cao, Kun Cao, Weifu Sun, Jie-Feng Gao, Yongqian Shi, Pingan Song, Long-Cheng Tang
Summary: An intelligent fire warning material based on montmorillonite has been developed, which shows excellent cyclic warning performance and reliable flame retardancy.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Yang Tang, Jun Yan, Wei Xiao, Xuewu Huang, Longcheng Tang, Yongqian Shi, Pingan Song, Jiefeng Gao
Summary: In this study, an asymmetric nanofibrous membrane (ANM) with unidirectional water transport capability was reported. The membrane consists of a superhydrophilic MXene/Chitosan/Polyurethane nanofiber membrane and an ultrathin hydrophobic Polyurethane/Polyvinylpyrrolidone layer with a bead-on-string structure. The ANM exhibits long-term stability and can withstand cyclic stretching, abrasion, and ultrasonic washing tests. It also serves as a temperature sensor and displays unique anti-gravity behavior when attached to the skin. The stretchable, wearable, and multi-functional nanofibrous composite membrane shows potential applications in flexible electronics, wearable devices, and health monitoring.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)