期刊
SCIENCE CHINA-CHEMISTRY
卷 65, 期 6, 页码 1196-1203出版社
SCIENCE PRESS
DOI: 10.1007/s11426-022-1267-5
关键词
metal nanocluster; ultraviolet laser dissociation; mass spectrometry; global property profiling; size- and charge-hierarchy
资金
- National Natural Science Foundation of China [32088101, 21872145, 22172167]
- Original Innovation Project of CAS [ZDBS-LY-SLH032]
- Chinese National Innovation Foundation [18-163-14-ZT-002-001-02]
- DICP [DICP I202007]
This study establishes a new method to generate and study metal nanoclusters with different sizes, constitutions, and charge states. The research reveals distinct reactivity differences among clusters of different sizes and charges, which is of great significance for the development and application of metal nanoclusters.
Metal nanoclusters are promising nanomaterials with unique properties, but only a few ones with specific numbers of metal atoms can be obtained and studied up to now. In this study, we establish a new paradigm of in-situ generation and global study of metal nanoclusters with different sizes, constitutions, and charge states, including both accurate constitution characterization and global activity profiling. The complex mixtures of metal nanoclusters are produced by employing single-pulsed 193-nm laser dissociation of monolayer-protected cluster (MPC) precursors within a high-resolution mass spectrometry (HRMS). More than 400 types of bare gold nanoclusters including novel multiply charged (2+ and 3+), S-/P-doped, and silver alloy ones can be efficiently generated and accurately characterized. A distinct size (1 to 142 atoms)- and charge (1+ to 3+)-hierarchy reactivity is clearly observed for the first time. This global cluster study might greatly promote the developments and applications of novel metal nanoclusters.
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