期刊
JOURNAL OF APPLIED PHYSICS
卷 120, 期 19, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.4967991
关键词
-
资金
- National Natural Science Foundation of China [61201064]
Na0.5Bi2.5Nb2O9 (NBN) based high temperature piezoelectric ceramics with A-site vacancies have been synthesized by the conventional solid state reaction method. Rietveld refinements and in-situ X-ray diffraction were performed to explore the influence of A-site vacancies on the crystalline structure and the phase evolution of NBN based ceramics with temperature, respectively. Pseudo-tetragonal distortion induced by A-site vacancies or temperature was found for the first time in the Aurivillius family, and this structural distortion might be responsible for the improvement of piezoelectric activity and the stability of piezoelectric property against thermal depolarization temperature (T-d). The composition with 12mol. % A-site vacancies exhibited good integrated performance, piezoelectric coefficient d(33) and T-c were about 24.8 pC/N and 770 degrees C, respectively, together with excellent resistance to the thermal depolarization behavior (d(33) decreased by 3% even if T-d reached up to Curie temperature T-C). This high temperature piezoelectric ceramics show potential applications in high temperature environments. Published by AIP Publishing.
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