Effect of Bi3+ ions substitution on the structure, morphology, and magnetic properties of Co-Ni spinel ferrite nanofibers

In this study, various Co0.5Ni0.5BixFe2-xO4 (x <= 0.10) spinel ferrite nanofibers (CoNiBi SFNFs) have been synthesized by electrospinning technique. The structure, morphological, and magnetic features of CoNiBi SFNFs was investigated. XRD analysis demonstrated the formation of single-phase cubic spinel structure for all samples. The cell parameter is increasing with the increase of Bi3+ content. The cubic morphology of all products was also verified by SEM and TEM microscopies. Mo spacing diaeresis ssbauer analysis was used to determine the hyperfine parameters by fitting room temperature mosspectra. The Bi3+ ions occupy mainly the B site. Vibrating sample magnetometry (VSM) was applied to get magnetic data for CoNiBi SFNFs at 300 and 10 K. The characteristics of the recorded magnetic hysteresis curves revealed the existence of just ferrimagnetic phases for all fabricated spinel nanofiber samples at both temperatures. The remanent magnetization Mr, saturation magnetization MS, magnetic moment per formula nB, coercivity Hc have been determined. Bi3+ ion substitution commonly diminishes the magnetic data except the content of x = 0.04. The maximum and minimum magnitude of magnetic parameters belong to Co0.5Ni0.5Bi0.04Fe1.96O4 and Co0.5Ni0.5Bi0.10Fe1.90O4 SFNFs, respectively. Pristine Co0.5Ni0.5Fe2O4 and Bi3+ ion doped samples exhibit soft magnetic at 300 K and hard magnetic nature at 10K conditions. Squareness ratio (SQR = Mr/Ms) provided extra information about the domain structure of fabricated nanofiber samples. At 10K conditions, SQR of the sample Co0.5Ni0.5Bi0.04Fe1.96O4 is almost equal to 0.5 and this critical value is assigned to the formation of single domains with uniaxial symmetry for this nanofiber. This one only and all others have SQRs that are much lower (0.073-0.366) at 300K or higher (0.620-0.781) at 10K. Those ranges specify the multi-domain wall structure for samples.

Automated summary

In this study, various Co0.5Ni0.5BixFe2-xO4 spinel ferrite nanofibers were synthesized and their structure, morphology, and magnetic properties were investigated. The results showed that all samples exhibited a single-phase cubic spinel structure, with Bi3+ ions mainly occupying the B site. The magnetic measurements indicated the presence of ferrimagnetic phases in all samples, except for one. The substitution of Bi3+ ions generally decreased the magnetic properties, except for the sample with x = 0.04. Additionally, the squareness ratio provided information about the domain structure of the nanofiber samples.