4.7 Article

A novel blue-light excitable Pr3+doped (Sr,Ba)LaMgTaO6 phosphor for plant growth lighting

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JOURNAL OF RARE EARTHS
卷 41, 期 5, 页码 666-672

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ELSEVIER
DOI: 10.1016/j.jre.2022.04.014

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Phosphor; Luminescence properties; Plant -growth LEDs; Rare earths

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In this study, Pr3+ ions doped (Sr,Ba)LaMgTaO6 phosphors were prepared and used for plant growth lighting. The red emission of (Sr,Ba)LaMgTaO6:Pr3+ under 450 nm excitation was attributed to the 3P0/3F2 transition of Pr3+ ions. The optimal doping concentration of Pr3+ was found to be 2.5 mol%. The (Sr,Ba)LaMgTaO6:Pr3+ phosphors combined with a blue LED chip were used to package red light-emitting diodes (LEDs) for plant growth, showing good overlap with the absorption band of photosynthesis.
In this work, a series of Pr3+ ions doped (Sr,Ba)LaMgTaO6 phosphors were prepared and applied for plant growth lighting. Under 450 nm excitation, (Sr,Ba)LaMgTaO6:Pr3+ exhibits intense reddish emission at around 650 nm which is assigned to the 3P0/3F2 transition of Pr3+ ions. The luminescence intensity reaches to the maximum at 2.5 mol% Pr3+ doping content both in SrLaMgTaO6:Pr3+ and BaLaMgTaO6:Pr3+ systems. Meanwhile, the internal quantum efficiency (IQE) test shows that the IQE of the SrLaMgTaO6:0.025Pr3+ phosphor is 33.34% upon blue light excitation. The decay curves and temperature-dependent luminescence measurements of the (Sr,Ba)LaMgTaO6:Pr3+ phosphors were performed and investigated in detail. The red light emitting diodes (LEDs) were packaged using the SrLaMgTaO6:Pr3+ and BaLaMgTaO6:Pr3+ phosphors combined with a blue LED chip, which are well -overlapped with the absorption band of photosynthesis. Results indicate that the (Sr,Ba) LaMgTaO6:Pr3+ can serve as a component of the red light in plant-growth LEDs.(c) 2022 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.

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