High-specific-energy aqueous supercapacitor with extended operating potential using trichloroacetic acid electrolyte

Extending the operating potential of electrolytes is an efficient strategy to improving the energy density of aqueous supercapacitors. In this work, trichloroacetic acid (TCA) is firstly developed to be an efficient acid electrolyte with extended operating potential to improve the energy density of the aqueous carbon-based supercapacitors. Meanwhile, a hierarchical porous carbon (HPC) with a high specific surface area of up to 3356 m(2) g(-1) derived from inedible fruits of flowering plums is prepared to match the newly developed TCA electrolyte. The prepared HPC exhibits a high specific capacitance of up to 460 F g(-1) in the TCA electrolyte at 1 A g(-1). The symmetric supercapacitor device based on the prepared HPC and TCA electrolyte can stably work at 1.3 V with excellent cycle durability, more than 95.4% of initial specific capacitance is reserved after 20000 cycles. Meanwhile, high specific energy of 18.8 Wh kg(-1) is delivered at 203 W kg(-1), which value is 2.38 times higher than the device using H2SO4 electrolyte. Energy density of the acidic aqueous supercapacitors can be dramatically improved by employing the newly developed TCA electrolyte while the large power density and excellent cycle durability of carbon-based supercapacitors can be well retained.

Automated summary

Extending the operating potential of electrolytes is an efficient strategy to improve the energy density of aqueous supercapacitors. In this study, trichloroacetic acid (TCA) is developed as an efficient acid electrolyte with extended operating potential to enhance the energy density of aqueous carbon-based supercapacitors. Additionally, hierarchical porous carbon (HPC) with a high specific surface area is prepared to match the TCA electrolyte. The experimental results demonstrate that the prepared HPC exhibits a high specific capacitance in the TCA electrolyte. The symmetric supercapacitor device based on the prepared HPC and TCA electrolyte shows excellent cycle durability and high energy density.