4.8 Article

Flexible electrode material of V2O5 carbon fiber cloth for enhanced zinc ion storage performance in flexible zinc-ion battery

期刊

JOURNAL OF POWER SOURCES
卷 533, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.jpowsour.2022.231358

关键词

Flexible electrode material; Flexible zinc-ion battery; V2O5 hybrid nanofibers; Carbon fiber cloth; Electrospinning

资金

  1. National Natural Science Foundation of China [21773203]
  2. Priority Academic Program Development of Jiangsu Higher Education Institutions
  3. Young Scientist Exchange Program the Republic of Korea
  4. Young Scientist Exchange Program People's Republic of China

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This paper successfully synthesizes a new flexible anode material V2O5-CFC through electrospinning and high-temperature calcination, and demonstrates its high specific capacity and excellent cycling performance in aqueous zinc-ion batteries. The use of a composite fiber structure alleviates the volume effect in the charge/discharge process and shows the potential application of this material as a flexible energy storage device.
As a new generation of electrode material, flexible electrode material can effectively broaden the application area and scope of energy storage devices. In this paper, a new vanadium pentoxide carbon fiber cloth (V2O5-CFC) is successful synthesized by means of electrospinning and high-temperature calcination. As a cathode material for aqueous zinc-ion batteries, V2O5-CFC possesses significantly increased specific capacity (132 mA h g(-1) at 1 A g(-1)) and good cycling ability (154 mA h g(-1) at 0.5 A g(-1) after 1000 cycles). The volume effect in the charge/ discharge process can be alleviated by using a composite fiber structure to avoid agglomeration of V2O5 nano sheets. Most important, V2O5-CFC displays the flexible property and demonstrates its potential applications as a high-energy density and flexible energy storage device with good reversibility. Therefore, the design and synthesis strategy of flexible nanofibers film is prospective for applications in next-generation flexible aqueous zinc ion batteries.

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