期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 688, 期 -, 页码 51-54出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2016.06.268
关键词
Mossbauer spectroscopy; Neutron Diffraction; Magnetic structure; Europium compounds
资金
- Natural Sciences and Engineering Research Council of Canada
- Fonds Quebecois de la Recherche sur la Nature et les Technologies
- University of New South Wales
- UNSW Canberra
The magnetic ordering of the trigonal compound EuGe2 has been studied using Eu-151 Mossbauer spectroscopy and neutron powder diffraction. The europium in EuGe2 is divalent and orders antiferromagnetically (AF) below T-N similar to 49 K giving a hyperfine field of 24.4(1) T at 4.6 K. The thermal evolution of the spectra shows no evidence for changes to the structure or slow paramagnetic dynamics as T-N is approached from below. Analysis of the neutron diffraction data shows that EuGe2 orders as an A-type AF with the 7.1(2)mu(B) Eu2+ moments ordered as ferromagnetic sheets within the ab-plane and AF coupled along the c-axis, forming a magnetic cell that is doubled along the crystallographic c-axis. (C) 2016 Elsevier B.V. All rights reserved.
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