期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 657, 期 -, 页码 626-630出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2015.10.086
关键词
Sulfur composite; Lithium; Batteries; Host material; Porous polymer frameworks; High surface area
资金
- One Hundred Talents Program of the Chinese Academy of Sciences
- National Natural Science Foundation of China [51342009]
- Natural Science Foundation of Fujian Province [2014J05027]
- Science and Technology Planning Project of Fujian Province, Grant [2014H2008]
Lithium-sulfur battery is one of the most promising energy storage systems for its high specific capacity. However, commercial development of lithium-sulfur batteries is severely hindered by the cathode host materials. To tackle this issue, we synthesized a new host material, high surface area, three-dimensional (3D) diamond-cage porous polymer frameworks PPN-13, to construct sulfur electrode by impregnating sulfur into its nano-pores. The PPN-13-S cathode deliveries a specific discharge capacity up to 606.4 mA h/g over 100 cycles at 0.1 C with a high coulombic efficiency. It demonstrates that the 3D porous structure PPN-13 as host material shows the high performance and a remarkable positive effect on the capacity retention as cathode materials in lithium-sulfur batteries. Due to the unique features of the material, our research provides a new type of materials for tailoring cathode materials in lithium-sulfur batteries. (C) 2015 Elsevier B.V. All rights reserved.
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