期刊
ENVIRONMENTAL SCIENCE & TECHNOLOGY
卷 56, 期 12, 页码 8034-8042出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.est.2c00992
关键词
hyperaccumulator; single-atom catalyst; photocatalysis; organic pollution remediation
资金
- National Key Research and Development Program of China [2020YFC1806801]
- National Natural Science Foundation of China [42077145, 42107045, 41701359]
- Natural Science Foundation of Jiangsu Province [BK20211400]
Phytoremediation is an environmentally friendly and cost-effective method for environmental pollution remediation. However, the utilization of harvested biomass poses challenges in practical applications. This study presents a novel approach using a manganese-carbon-based single-atom catalyst method to enhance the potential utilization of biomass for phytoremediation and demonstrates its high efficiency and stability in the degradation of organic pollutants.
Phytoremediation is a potentially cost-effective and environmentally friendly remediation method for environmental pollution. However, the safe treatment and resource utilization of harvested biomass has become a limitation in practical applications. To address this, a novel manganese-carbon-based single-atom catalyst (SAC) method has been developed based on the pyrolysis of a manganese hyperaccumulator, Phytolacca americana. In this method, manganese atoms are dispersed atomically in the carbon matrix and coordinate with N atoms to form a Mn-N-4 structure. The SAC developed exhibited a high photooxidation efficiency and excellent stability during the degradation of a common organic pollutant, rhodamine B. The Mn-N-4 site was the active center in the transformation of photoelectrons via the transfer of photoelectrons between adsorbed O-2 and Mn to produce reactive oxygen species, identified by in situ X-ray absorption line structure spectroscopy and density functional theory calculations. This work demonstrates an approach that increases potential utilization of biomass during phytoremedi a..on and provides a promising design strategy to synthesize cost-effective SACs for environmental applications.
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