4.7 Article

Comparison of toughening mechanisms in natural silk-reinforced composites with three epoxy resin matrices

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2021.106760

关键词

Biocomposite; Fracture toughness; Mechanical properties; Failure

资金

  1. National Natural Science Foundation of China [number51905019]
  2. China Postdoctoral Science Foundation [2019M650432]
  3. Fundamental Research Funds for the Central Universities

向作者/读者索取更多资源

Natural silk fibre can enhance the toughness and impact strength of composites when reinforced in polymer matrices, with the epoxy resin derived from bisphenol-A epoxy and aliphatic diamine precursors showing the highest performance in terms of tensile breaking energy and impact strength. The toughening mechanisms in these composites are mainly crack propagation and fiber pull-out, regardless of whether the matrix is brittle or ductile. The study aims to provide guidelines for designing matrices in silk fibre-reinforced plastics with optimal toughness by identifying key toughening mechanisms.
Natural silk fibre can reinforce the polymer matrix for composites with improved toughness and impact strength. However, the optimum selection of matrices for the mechanical performance of silk fibre reinforced plastics (SFRPs) is still unclear, especially with respect to toughness. Here Bombyx mori silk is applied to reinforce three epoxy resin matrices with various crosslinking structures. The epoxy resin from bisphenol-A epoxy and aliphatic diamine precursors that is the most ductile and the toughest leads to the SFRPs with the highest tensile breaking energy (14.1 MJ.m(-3)) and impact strength (110 kJ.m(-2)). Examination of the toughening mechanisms in these composites, which haveeither a brittle or ductile matrix, indicated the predominance of crack propagation and fibre pull-out to increase specific energy dissipation during the fracture processes. The rationale for this study is to provide guidelines for the design of matrices in SFRPs with optimal toughness, by identifying the salient toughening mechanisms in these tough and ductile fibre-reinforced composites.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Review Engineering, Biomedical

Processing, mechanical properties and bio-applications of silk fibroin-based high-strength hydrogels

Yu Zhao, Zhi Shou Zhu, Juan Guan, Su Jun Wu

Summary: Hydrogels are versatile materials in biomedical engineering with applications similar to wet tissues. Silk fibroin (SF) is a natural polymer with biocompatibility and tunable biodegradation, but its poor mechanical performance hinders its structural applications. Researchers are exploring strategies to enhance the strength of SF-based hydrogels for biomedical uses.

ACTA BIOMATERIALIA (2021)

Review Orthopedics

Systematic review of intervertebral disc repair: a bibliometric analysis of the 100 most-cited articles

Gang Xu, Xianglong Meng, Juan Guan, Yaozhong Xing, Zihe Feng, Yong Hai

Summary: This study aims to identify the most frequently cited articles in the field of intervertebral disc repair and summarize the key points and findings of these works. Analysis of influential articles can help clarify the most effective strategies for intervertebral disc repair and discover promising directions for future research.

JOURNAL OF ORTHOPAEDIC SURGERY AND RESEARCH (2021)

Article Chemistry, Multidisciplinary

A Stair-Building Strategy for Tailoring Mechanical Behavior of Re-Customizable Metamaterials

Xin Lin, Fei Pan, Kang Yang, Juan Guan, Bin Ding, Yizhe Liu, Kuijian Yang, Bin Liu, Yuli Chen

Summary: The study introduces a stair-building strategy for customizing and re-customizing the target mechanical behavior of mechanical metamaterials by stacking the loading curves of bistable units, proving its mechanical feasibility and proposing simple design schemes that are validated through experiments and finite element simulations.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Engineering, Manufacturing

Impact of hydration on the mechanical properties and damage mechanisms of natural silk fibre reinforced composites

Wenhan Tian, Kang Yang, Sujun Wu, Jiping Yang, Hongyun Luo, Juan Guan, Robert O. Ritchie

Summary: The study found that high hydration conditions can lead to more susceptible interfacial failure in silk fiber-reinforced polymers (SFRPs), while mild hydration treatment appears not to affect SFRPs. Acoustic emission analysis revealed that interface failure plays a key role in the damage modes of SFRPs.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2021)

Article Biochemistry & Molecular Biology

The relationship between crosslinking structure and silk fibroin scaffold performance for soft tissue engineering

Zhinan Mao, Xuewei Bi, Fan Ye, Puyu Du, Xiong Shu, Lei Sun, Juan Guan, Xiaoming Li, Sujun Wu

Summary: The appropriate dosage of crosslinking agent EGDE is critical for achieving balanced mechanical properties, in vivo degradability, and immunological properties of silk fibroin scaffold platform for soft tissue engineering.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2021)

Article Materials Science, Composites

Structure and moisture effect on the mechanical behavior of a natural biocomposite, buffalo horn sheath

Siyu Cai, Kang Yang, Yanjin Xu, Juan Guan, Baoshuai Han, Bin Sun, Yuansong Zeng, Sujun Wu

Summary: Buffalo horn sheath is a natural composite with balanced strength and toughness, showing a hierarchical structure with different components contributing to its mechanical properties. The study clarifies the effects of protein secondary structure, anisotropic microstructure, and moisture on the flexural properties of the sheath, providing insights into the structure-property relationship of natural composites and design strategies for bioinspired composites.

COMPOSITES COMMUNICATIONS (2021)

Article Engineering, Biomedical

Extrusion Printed Silk Fibroin Scaffolds with Post-mineralized Calcium Phosphate as a Bone Structural Material

Ruya Shi, Xingxing Cai, Guanping He, Juan Guan, Yuzeng Liu, Hongyi Lu, Zhinan Mao, Yan Li, Hongbo Guo, Yong Hai

Summary: This study demonstrates the fabrication of silk fibroin scaffolds using 3D printing and their subsequent mineralization to enhance mechanical properties. The mineralized scaffolds not only exhibit significant reinforcement but also promote osteogenesis.

INTERNATIONAL JOURNAL OF BIOPRINTING (2022)

Article Nanoscience & Nanotechnology

Understanding the Interfacial Adhesion between Natural Silk and Polycaprolactone for Fabrication of Continuous Silk Biocomposites

Ruya Shi, Dongdong Ye, Ke Ma, Wenhan Tian, Yan Zhao, Hongbo Guo, Zhengzhong Shao, Juan Guan, Robert O. Ritchie

Summary: This study investigated the interfacial properties between silk fibers and polycaprolactone (PCL) at different scales and fabricated continuous silk-PCL composite filaments. The results showed that Antheraea pernyi (Ap) silk had the best interfacial shear strength with PCL. Raman imaging technique revealed the physical fusion of the interface phase in these silk-reinforced PCL composites.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Chemistry, Multidisciplinary

Rapid Regeneration of a Neoartery with Elastic Lamellae

Ziyu Wang, Suzanne M. Mithieux, Howard Vindin, Yiwei Wang, Miao Zhang, Linyang Liu, Jacob Zbinden, Kevin M. Blum, Tai Yi, Yuichi Matsuzaki, Farshad Oveissi, Reyda Akdemir, Karen M. Lockley, Lingyue Zhang, Ke Ma, Juan Guan, Anna Waterhouse, Nguyen T. H. Pham, Brian S. Hawkett, Toshiharu Shinoka, Christopher K. Breuer, Anthony S. Weiss

Summary: This study introduces a novel electrospun small-diameter vascular graft that can promote the regeneration of the intima-media region with structurally appropriate elastin. After implantation, the graft develops a cell and extracellular matrix profile similar to that of native arteries, including circumferentially aligned smooth muscle cell layers and elastin layers. The adventitia region of the graft also contains mature collagen fibrils, and the neoartery exhibits a distinct internal elastic lamina comparable to that in mouse abdominal aorta.

ADVANCED MATERIALS (2022)

Article Engineering, Biomedical

A Cell-Free Silk Fibroin Biomaterial Strategy Promotes In Situ Cartilage Regeneration Via Programmed Releases of Bioactive Molecules

Zhinan Mao, Xuewei Bi, Chengai Wu, Yufeng Zheng, Xiong Shu, Sujun Wu, Juan Guan, Robert O. Ritchie

Summary: In this study, a cartilage-biomimetic silk fibroin-based scaffold with controlled sequential release of bioactive molecules was developed for cartilage repair. The scaffold exhibited excellent structural stability and mechanical properties, providing a desirable 3D microenvironment for cartilage reconstruction. In vitro and in vivo studies showed that the scaffold promoted the recruitment and differentiation of stem cells, leading to in situ cartilage regeneration. This biomimetic scaffold shows promising potential for improved cartilage tissue engineering.

ADVANCED HEALTHCARE MATERIALS (2023)

Article Materials Science, Multidisciplinary

Correlating multi-scale structure characteristics to mechanical behavior of Caprinae horn sheaths

Kang Yang, Nannan Qin, Changgeng Zhou, Hailiang Deng, Wenhan Tian, Siyu Cai, Zihong Wu, Juan Guan

Summary: This study investigated the effect of multi-scale structure characteristics on the mechanical behavior of horn sheath in different goats. The conformation of keratin and strength of fibers were found to significantly influence the tensile/flexural performance of the horn sheath under both dried and hydrated conditions. The corrugated lamellae structure was identified to promote crack deflection and enhance the performance of dried samples, making them more advantageous for flexural loading applications. The synergism of multi-scale mechanisms was found to be crucial to the mechanical properties of the Caprinae horn sheath.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2022)

Article Biochemistry & Molecular Biology

Restructuring the Interface of Silk-Polycaprolactone Biocomposites Using Rigid-Flexible Agents

Yan Zhao, Zihong Wu, Lei Chen, Xiong Shu, Juan Guan, Kang Yang, Ruya Shi, Yibin Li, Keiji Numata, Zhengzhong Shao

Summary: Natural fiber-reinforced biocomposites with excellent mechanical and biological properties have attractive prospects for internal medical devices. However, poor interfacial adhesion between natural silk fiber and the polymer matrix has been a disturbing issue for such applications. In this study, rigid-flexible agents, such as polydopamine (PDA) and epoxy soybean oil (ESO), were introduced to enhance the interfacial adhesion between Antheraea pernyi (Ap) silk and polycaprolactone (PCL). The Ap-PDA-ESO strategy exhibited a greater enhancement in interfacial adhesion, and proposed interfacial toughening mechanisms.

BIOMACROMOLECULES (2023)

Article Polymer Science

Peculiar Tensile and Fracture Behaviors of Natural Silk Fiber in the Presence of an Artificial Notch

Yu Wang, Zihong Wu, Liang Zhou, Xin Chen, Juan Guan, Zhengzhong Shao

Summary: In this study, we investigate the tensile and fracture behaviors of natural silk fibers with hierarchical structures and defects, and reveal their self-tolerance and fracture mechanism. By introducing transverse notches, we demonstrate that the silk fibers can effectively blunt the notches through longitudinal cracks, leading to ductile failure. The tensile behavior of the notched silk fibers is mainly determined by the magnitude of longitudinal crack and the interface interaction between nanofibrils.

MACROMOLECULES (2022)

Review Chemistry, Multidisciplinary

Enhancing the Mechanical Performance of Fiber-Reinforced Polymer Composites Using Carbon Nanotubes as an Effective Nano-Phase Reinforcement

Zihong Wu, Yan Zhao, Kang Yang, Juan Guan, Shaokai Wang, Yizhuo Gu, Min Li, Yiyu Feng, Wei Feng, Robert O. Ritchie

Summary: Carbon nanotubes (CNTs) are an economical and multi-functional nanofiller that can enhance the mechanical and functional properties of fiber-reinforced polymer composites. This review discusses the fabrication routes of CNT incorporation into composites, the effects of CNTs on mechanical properties, modeling studies on CNT composites, and reinforcement and toughening mechanisms. The aim is to provide a comprehensive summary and guide future research.

ADVANCED MATERIALS INTERFACES (2023)

Article Engineering, Manufacturing

Characterization of tool-ply friction behavior for treated jute/PLA biocomposite prepregs in thermoforming

Wenwu Zhang, Helezi Zhou, Bin Huang, Huamin Zhou, Xiongqi Peng

Summary: This paper investigates the tool-ply friction behavior of jute/PLA biocomposites in thermoforming. A pull-through friction testing device was developed to characterize the tool-ply friction behavior of jute/PLA prepreg at elevated temperature. The effects of alkali treatment, fiber orientation, normal force, and slipping velocity were studied, and a quantitative definition of tool-ply friction behavior was achieved. The results indicate a strong relationship between tool-ply friction behavior and woven and fiber structures, indicating hydrodynamic lubrication.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Experimental characterization of compression failure mechanism initiation and growth in notched carbon fiber reinforced composite specimens

Stephen Clay, Wesley Ault, Alex Faupel, Caglar Oskay, Philip Knoth, Noam N. Y. Shemesh, Rami Haj-Ali, Uri Breiman, Ido Meshi, Ofir Shor

Summary: This paper presents an experimental investigation on the compression failure mechanisms of laminated carbon fiber reinforced composites under non-standard quasi-static loading. The results demonstrate the presence of interior kink bands, surface ply splitting, and delaminations, with each failure mechanism associated with different stress levels.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Improved pyroelectric performances of functionally graded graphene nanoplatelet reinforced polyvinylidene fluoride composites: Experiment and modelling

Bowen Zeng, Jinlong Yang, Zhi Ni, Yucheng Fan, Ziyan Hang, Chuang Feng

Summary: This study successfully improved the pyroelectric properties of PVDF films by preparing functionally graded graphene nanoplatelet (FG-GNP) reinforced PVDF composite films. The increase in the number of layers and the concentration of GNP near the surface of the composite film were found to enhance the pyroelectric properties and temperature stability.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Investigation of nanocomposite system with long-chain phosphorus-containing intercalator-modified montmorillonite nanosheets

Shenghe Zhang, Fukai Chu, Weizhao Hu, Bibo Wang, Richard K. K. Yuen, Yuan Hu

Summary: This study improves the flame retardancy and mechanical properties of PBAT by synthesizing a phosphorus-containing intercalator and mixing it into the PBAT matrix.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Suppression of compression induced delamination in tapered laminated composites using a ply scarfing method

Tharan Gordon, Michael R. Wisnom, Byung Chul Kim

Summary: Thickness tapering is a common strategy for efficient and lightweight composite structures, but it can introduce delamination sites. This study investigated the use of ply scarfing method to improve the compressive failure stress of tapered laminates made from thick unidirectional non-crimp fabrics. The results showed that ply scarfing suppressed delamination and increased the failure stress by 60%.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Pre-compositing polyetherketoneketone with short-cut carbon fibers into advanced powder materials toward composites with fully-adhered interfaces

Xin Wang, Yiting Qu, Junlei Bai, Fujun Xu, Bin Ding, Xiaohua Zhang

Summary: A solution-based strategy is proposed to achieve a strong bond between fibers and matrix in powder materials, resulting in improved mechanical properties, thermal conductivity, and fracture strain of the composites. The method also offers advantages such as enhanced powder flowability and thermal stability.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Shape-memory polyurethane elastomer originated from waste PET plastic and their composites with carbon nanotube for sensitive and stretchable strain sensor

Xing Zhou, Guosheng Wang, Dexiang Li, Qi Wang, Keming Zhu, Yaya Hao, Yueyang Xu, Neng Li

Summary: This study successfully synthesized polyurethane elastomer by using degraded products from waste PET, and fabricated composites with carbon nanotubes for strain sensors. The composites showed good mechanical and durability performance, indicating a potential method for recycling waste PET into valuable and functional materials.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Facilely fabricated Janus polymer film for actuator and self-powered sensor

Fei Peng, Tingting Shan, Rongrui Chen, Jiulong Shi, Di Liu, Guoqiang Zheng, Chaojun Gao, Kun Dai, Chuntai Liu, Changyu Shen

Summary: Janus polymer films with distinct surface performance and potential applications were successfully prepared by vacuum-assisted hot-compressing method and spray coating. These films exhibit decent actuation performance and rapid selfpowered sensing property, and can be used for real-time acetone monitoring system.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Enhanced thermal conductivity of phase change composites with novel binary graphite networks

Biao Cheng, Huafeng Quan, Yuefeng Zhang, Dong Huang, Tongqi Li, Chong Ye, Xingming Zhou, Zhen Fan, Yafang Zhang, Ting Ouyang, Fei Han, Hongbo Liu, Jinshui Liu

Summary: In this study, a binary graphite network was constructed to improve the thermal conductivity and control the formation of micrometer-scale open pores in phase change composites. The developed composites showed a high thermal conductivity and phase change enthalpy, making them promising for thermal control in space optical-mechanical systems and other critical aerospace components.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

An effective micro-arc oxidation (MAO) treatment on aluminum alloy for stronger bonding joint with carbon fiber composites

Shihao Zuo, Fei Cheng, Guangming Yang, Jiangzhou Li, Yongjun Deng, Guangjun Gou, Xuejun Cui, Yunsen Hu, Xiaozhi Hu

Summary: Micro-arc oxidation (MAO) treatment was used to modify aluminum (Al) alloys in order to improve bond strength with carbon fiber reinforced polymer (CFRP). The treatment successfully created a porous surface with better hardness, roughness, and wetting, and introduced resin pre-coating (RPC) and carbon nanotube (CNT) fiber bridging to improve the bonding interface. The combined treatments significantly increased the bond strength by up to 156.1%, indicating the feasibility of MAO as an alternative method for manufacturing high-performance Al-CFRP composites in industrial production.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Effects of accelerated curing in thermoplastic particle interleaf epoxy laminates

James Kratz, Christophe Paris, Karolina Gaska, Vincent Maes, Ivana Partridge, Philippe Olivier

Summary: Faster heating rates and higher process temperatures can reduce the total process time while achieving the same degree-of-cure. Thermal analysis shows that thermoplastic interleaf particles melt at the recommended curing temperature. A short dwell at a lower temperature can prevent the mixing of thermoplastic particles and thermoset pre-polymer.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Resistance-welded thermoset composites: A Bayesian approach to process optimisation for improved fracture toughness

Thomas Maierhofer, Evripides G. Loukaides, Craig Carr, Chiara Bisagni, Richard Butler

Summary: Joining thermoset composites via resistance welding provides an efficient method for aerospace structures with benefits such as high-volume manufacturing and simplified surface preparation. The influence of welding parameters on joint performance is assessed using Mode I fracture toughness testing. A Bayesian approach is employed to select high-performance parameters.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

High-performance chlorinated polyvinyl chloride/polyurea nanocomposite foam with excellent solvent resistance, flame-triggered shape memory effect and its upcycling

Jiangan You, Ling Cai, Ronghua Yu, Haiping Xing, Jian Xue, Ying Li, Zhiwei Jiang, Dongmei Cui, Tao Tang

Summary: In response to the global environmental pollution crisis caused by waste plastics, recyclable design is an effective solution. A CPVC/PUA nanocomposite foam was developed using the plasticizing-foaming-reinforcing strategy, combined with catalytic carbonization. The foam exhibited high expansion ratio, robustness, solvent resistance, flame-triggered shape memory effect, and ablation resistance. The foam could be directly upcycled into functional carbon foam with attractive electromagnetic interference shielding performance.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Flexible multiwalled carbon nanotubes/cellulose nanofibers membrane with rapid temperature increasing induced by interface strengthening

Siyao Chen, Zhiyu Chen, Yangling Ou, Junwei Lyu, Junning Li, Xiangyang Liu, Yang Liu

Summary: In this study, we demonstrated the significant effect of composite interface on temperature increase in electrical heaters. By selectively fluorinating the outer walls of carbon nanotubes and compositing them with cellulose nanofibers, improved interfacial phonon diffusion was achieved, leading to a higher temperature increase rate.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)

Article Engineering, Manufacturing

Effect of atomic oxygen exposure on polybenzoxazine/POSS nanocomposites for space applications

Yanjun He, Agnieszka Suliga, Alex Brinkmeyer, Mark Schenk, Ian Hamerton

Summary: A new thermoset resin system based on a polybenzoxazine blend showed good performance under high ATOX irradiation. It reduced erosion yield by forming a silicon-rich surface layer and improved the mechanical properties of CFRP laminates.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2024)