期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 56, 期 11-12, 页码 977-989出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201600077
关键词
achiral column chromatography; amides; amino acids; homochiral and heterochiral molecular associations; self-disproportionation of enantiomers (SDE)
资金
- IKERBASQUE
- Basque Foundation for Science
- Ministry of Science and Higher Education [612561]
- National Science Center (Krakow, Poland) [UMO 2014/15/B/ST5/05329]
This article is based on a review of literature devoted to the phenomenon of SDE via achiral chromatography since the appearance of the seminal work of Professor Emanuel Gil-Av. The discussed examples of chromatographic studies are related to amides derived from chiral amines and alpha- and beta-amino acids. We discuss the observed SDE magnitude as a function of a compound's structure, and composition of eluent and stationary phases, providing some mechanistic considerations. Particular emphasis is given to the aspect of SDE via achiral chromatography as an emerging unconventional enantiomeric purification technique.
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