Article
Chemistry, Physical
Kayaramkodath C. Ranjeesh, Sukhjot Kaur, Abdul K. Mohammed, Safa Gaber, Divyani Gupta, Khaled Badawy, Mohamed Aslam, Nirpendra Singh, Tina Skorjanc, Matjaz Finsgar, Jesus Raya, Tharamani C. Nagaiah, Dinesh Shetty
Summary: This study reports a covalent organic framework catalyst with in-situ proton filter ability, which can effectively control proton supply and enhance N2 flux for efficient nitrogen reduction reaction. The feasibility of the catalyst is further validated through molecular dynamics simulations and control experiments. These findings signify a paradigm shift in engineering high-performance NRR electrocatalysts and contribute to more feasible green NH3 production.
ADVANCED ENERGY MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Haneul Jin, Suyeon S. S. Kim, Sandhya Venkateshalu, Jeseok Lee, Kwangyeol Lee, Kyoungsuk Jin
Summary: Ammonia, a key feedstock used in various industries, is considered a sustainable fuel and energy storage option. However, the conventional Haber-Bosch process for NH3 production is costly, energy-intensive, and contributes significantly to carbon emissions. Electrochemical nitrogen fixation offers a green alternative for NH3 production without harmful pollutants. This review discusses recent progress and challenges in two electrochemical pathways: direct and indirect nitrogen reduction reactions, as well as efforts to improve catalytic performances.
Article
Chemistry, Multidisciplinary
Tae-Yong An, Subramani Surendran, Sebastian Cyril Jesudass, Hyunjung Lee, Dae Jun Moon, Jung Kyu Kim, Uk Sim
Summary: Hydrogen has become essential for sustainable energy resources due to the depletion of fossil fuels and increased pollution. Green ammonia is considered an efficient carrier for hydrogen storage and transport. This study focuses on controlling the nitrogen reduction performance of Mo2C-Mo2N heterostructure electrocatalyst and reveals the improved activity achieved by the combination of Mo2C and Mo2N0.92 phases. The study suggests the importance of precisely tuning the electrocatalyst using heterostructure strategy to achieve higher nitrogen reduction activity.
FRONTIERS IN CHEMISTRY
(2023)
Review
Chemistry, Physical
Usman Bin Shahid, Kumar Siddharth, Minhua Shao
Summary: The Haber-Bosch (HB) process revolutionized the chemical industry by making various nitrogenous derivatives accessible, but depleting natural resources and environmental concerns are driving a shift towards energy-efficient and environmentally friendly alternatives. The electro-chemical reduction pathway is seen as one of the most promising prospects as a carbon-free, environment-friendly, energy-efficient alternative to the HB process.
CURRENT OPINION IN ELECTROCHEMISTRY
(2021)
Review
Chemistry, Multidisciplinary
Xue Zhao, Guangzhi Hu, Gao-Feng Chen, Haibo Zhang, Shusheng Zhang, Haihui Wang
Summary: The electrochemical nitrogen reduction reaction, which produces ammonia, is environmentally friendly and suitable for rural economy, but faces challenges in catalysts and quantitative determination.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
K. M. Parida, Lekha Paramanik, Sabiha Sultana
Summary: This study demonstrated the efficient nitrogen reduction to ammonia using a combination of cobalt titanate and nitrogen-doped reduced graphene oxide under visible light irradiation. By optimizing the concentration of nitrogen-doped reduced graphene oxide, the production of ammonia was significantly improved, paving the way for the development of highly active catalyst materials for sustainable energy conversion in the future.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Hui-Qi Xie, Xuan Zheng, Qing-Yun Feng, Xiao-Ping Chen, Ze-Hua Zou, Qing-Xiang Wang, Jing Tang, Yi Li, Yun Ling
Summary: This study successfully synthesized Fe-based oxide composite nanoparticles with stable chemical states. The catalyst exhibited remarkable activity and selectivity in the nitrogen reduction reaction, with high faradaic efficiency and ammonia yield. Experimental characterization and theoretical calculations revealed the excellent charge transfer capability and the suppression of the competitive HER process by the catalyst.
Review
Chemistry, Multidisciplinary
Munkhjargal Bat-Erdene, Abdulaziz S. R. Bati, Jiadong Qin, Huijun Zhao, Yu Lin Zhong, Joseph G. Shapter, Munkhbayar Batmunkh
Summary: Graphene and related elemental 2D materials are key materials in nanotechnology and hold promise for electrocatalysis reactions. Research beyond graphene is in early stages, but recent studies show the efficacy of elemental 2D materials as electrocatalysts.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Qin Liu, Qian Liu, Lisi Xie, Yuyao Ji, Tingshuai Li, Bing Zhang, Na Li, Bo Tang, Yang Liu, Shuyan Gao, Yonglan Luo, Lingmin Yu, Qingquan Kong, Xuping Sun
Summary: This study introduces a high-performance electrocatalyst FeOOH/CP, which efficiently converts nitrate to ammonia at room temperature, with high ammonia yield and remarkably high Faradic efficiency.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Engineering, Environmental
Ziqiang Wang, Zechuan Dai, Shengqi Wang, Hugang Zhang, Wenjing Tian, You Xu, Xiaonian Li, Liang Wang, Hongjing Wang
Summary: PdH0.43 NRs prepared by hydrogenating Pd NRs show excellent performance in electrochemical ammonia synthesis, exhibiting high NH3 yield, Faradaic efficiency, and long-term electrochemical stability. This hydrogenation strategy provides a new approach for designing efficient and stable metal hydrides for active NRR.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Applied
Jit Mukherjee, Ashadul Adalder, Nilmadhab Mukherjee, Uttam Kumar Ghorai
Summary: This study demonstrates that α-CuPc can serve as an electrocatalyst for the synthesis of ammonia (NH3) via the Nitrogen Reduction Reaction (NRR) under ambient conditions. The α-CuPc catalyst exhibits high performance, excellent stability (up to 10 hours), and recyclability for multiple cycles. The validity of nitrogen sources in NH3 generation is confirmed through isotopic labelling studies and different control experiments.
Article
Chemistry, Physical
Boaz Izelaar, Davide Ripepi, Simone Asperti, A. Iulian Dugulan, Ruud W. A. Hendrikx, Amarante J. Boettger, Fokko M. Mulder, Ruud Kortlever
Summary: The electrochemical dinitrogen reduction reaction (NRR) has attracted much attention as a potential alternative to the Haber-Bosch process for ammonia production. Previous studies suggested that Fe- and Mo-carbides are promising electrocatalysts for NRR. However, recent research has challenged these findings due to contamination issues. In this study, the performance of several Fe- and Mo-carbides as NRR catalysts was critically assessed using a strict experimental protocol. The results showed that the observed ammonia was not from NRR, but from extraneous ammonia and NOx impurities.
Article
Chemistry, Multidisciplinary
Sisi Liu, Mengfan Wang, Yanzheng He, Qiyang Cheng, Haoqing Ji, Yunfei Huan, Xiaowei Shen, Xi Zhou, Tao Qian, Chenglin Yan
Summary: The use of molecular imprinting technology to construct an adlayer with abundant nitrogen imprints on the electrocatalyst allows for selective recognition and aggregation of high-concentrated nitrogen at the interface while hindering access to overwhelming water. This leads to significant improvements in both ammonia production rate and Faradaic efficiency compared to a bare catalyst.
ADVANCED MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Ting Pan, Liu Wang, Yu Shen, Xinglong Zhang, Chengyang Luo, Hongfeng Li, Peng Wu, Hao Zhang, Weina Zhang, Serguei V. Savilov, Fengwei Huo
Summary: In this study, a hierarchically porous amorphous metal oxide catalyst was constructed, exhibiting superior electrocatalytic performance for NRR under ambient conditions. It has the potential to serve as an alternative electrocatalyst for NH3 synthesis.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Tingting Wu, Wenjun Fan, Yang Zhang, Fuxiang Zhang
Summary: The electrochemical synthesis of ammonia, with advantages such as mild operating conditions and zero emission of carbon dioxide, is considered a promising alternative to the traditional Haber-Bosch process. Research in this field focuses on catalyst development, innovations in electrolytic cell configurations, and verification of ammonia synthesis results.
MATERIALS TODAY PHYSICS
(2021)
Article
Nanoscience & Nanotechnology
Song Jin, Seung Yong Yang, Jong Min Lee, Mun Seon Kang, Sung Mook Choi, Wook Ahn, Xolile Fuku, Remegia Mmalewane Modibedi, Byungchan Han, Min Ho Seo
Summary: Fluorine-doped graphene nanoribbons were found to have a stable structure and exhibit good performance in carbon corrosion, making them suitable as support materials for electrocatalysts and cathode additives in polymer electrolyte membrane fuel cells.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Nguyet N. T. Pham, Kwang Ho Kim, Byungchan Han, Seung Geol Lee
Summary: Density functional theory was used to investigate the electrocatalytic activity of pyridinic-N doped graphene in single-layer and bilayer structures. The N-doped bilayer graphene showed better activity for the oxygen reduction reaction compared to single-layer graphene. The stacking structure of bilayer graphene improved the stability and activity of the N-doped graphene.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Multidisciplinary Sciences
Jaeyoung Hong, Jee-Hwan Bae, Hyesung Jo, Hee-Young Park, Sehyun Lee, Sung Jun Hong, Hoje Chun, Min Kyung Cho, Juyoung Kim, Joodeok Kim, Yongju Son, Haneul Jin, Jin-Yoo Suh, Sung-Chul Kim, Ha-Kyung Roh, Kyu Hyoung Lee, Hyung-Seok Kim, Kyung Yoon Chung, Chang Won Yoon, Kiryeong Lee, Seo Hee Kim, Jae-Pyoung Ahn, Hionsuck Baik, Gyeung Ho Kim, Byungchan Han, Sungho Jin, Taeghwan Hyeon, Jungwon Park, Chang Yun Son, Yongsoo Yang, Young-Su Lee, Sung Jong Yoo, Dong Won Chun
Summary: Metastable phases, which are structures favored by kinetics, are widely found in nature. Crystals grown from high-energy precursors often initially take on metastable structures depending on conditions such as temperature, pressure, or crystal size. These metastable phases can have superior properties, making the discovery and synthesis of new metastable phases an exciting area for advancements in materials science.
Article
Chemistry, Multidisciplinary
Junyoung Heo, Dohun Kang, Sungin Kim, Hoje Chun, Byungchan Han, Byung Hyo Kim, Jungwon Park
Summary: In this study, a method of symmetry analysis using 3D atomic coordinates is introduced, which provides a direct and quantitative analysis of the symmetrical properties and local structural characteristics of nanoparticles. The experimental results reveal the crystal structure features of platinum nanoparticles and demonstrate localized structural deformations different from their bulk counterpart.
Article
Chemistry, Multidisciplinary
Mengjie Liu, Hoje Chun, Tsung-Cheng Yang, Sung Jun Hong, Chia-Min Yang, Byungchan Han, Lawrence Yoon Suk Lee
Summary: By modulating the d-orbital energy level, we successfully synthesized N-doped carbon materials with paired metal sites. Compared with other counterparts, the Ru-Co diatomic catalyst exhibited higher oxygen electroreduction activity and better catalytic performance. Moreover, in a gas diffusion Zn-air battery, the Ru-Co diatomic catalyst showed bifunctional activity that outperformed commercial catalysts.
Article
Engineering, Environmental
Hwakyeung Jeong, Dong Woo Lee, Sung Jun Hong, Jihye Kim, Minsik Kim, Junhyuck Kim, Hyeon Seok Lee, Tae-Hong Park, Hee-Kyung Kim, Jai Il Park, Jong-Yun Kim, Sang Ho Lim, Taeghwan Hyeon, Byungchan Han, Sang-Eun Bae
Summary: This study developed platinum-coated iron nanoparticles (Fe@Pt) as a highly selective and reusable adsorbent for the removal of radioactive iodine species. Fe@Pt demonstrated excellent removal efficiency and stability, making it a promising option for environmental restoration after nuclear accidents.
Article
Materials Science, Multidisciplinary
Jeongyeon Lee, Yoonbin Kim, Soyong Park, Kang Ho Shin, Gun Jang, Min Jun Hwang, Daekyu Kim, Kyung-Ah Min, Ho Seok Park, Byungchan Han, Dennis K. P. Ng, Lawrence Yoon Suk Lee
Summary: In this study, researchers utilized polymeric disodium phthalocyanines (pNaPc) as anode materials for sodium-ion batteries, providing stable coordination sites for Na ions and enhancing stability at high current density. By varying the linker type, two pNaPc anodes with O- (O-pNaPc) and S-linkers (S-pNaPc) were prepared, and their structural and electrochemical properties were investigated. O-pNaPc showed improved redox kinetics and cycle stability, allowing the fabrication of a full cell with high energy density (288 Wh kg(-1)) and high power density (149 W kg(-1)) when coupled with Na3V2(PO4)(2)F-3/C cathode.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Sukhwa Hong, Kahyun Ham, Jeemin Hwang, Sinwoo Kang, Min Ho Seo, Young-Woo Choi, Byungchan Han, Jaeyoung Lee, Kangwoo Cho
Summary: In this study, a highly efficient and stable oxygen evolution reaction (OER) electrocatalyst is developed by using scalable solution casting method to deposit doped nanoparticles on Ni foam. Advanced X-ray absorption spectroscopy and density functional theory calculations reveal the changes in catalytic active sites, providing new insights for precious-metal doped Ni-Fe oxide electrocatalysts.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Suseong Hyun, Hoje Chun, Minjoon Hong, Joonhee Kang, Byungchan Han
Summary: In this study, we designed ultrafast diffusion channels for Li ions through optimal aliovalent doping (Fe2+) of the halide electrolyte with a chloride framework, solving the issue of slow Li+ diffusion even in advanced halide-type electrolytes. The proposed material exhibits high chemical stability and high Li-ion conductivity, providing a new direction for research in electrolyte field.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Wonjae Lee, Hyebin Yun, Yongmin Kim, Sun Seo Jeon, Hoon Taek Chung, Byungchan Han, Hyunjoo Lee
Summary: Water electrolysis using anion exchange membranes holds promise for hydrogen production, and Ni-Mo catalysts have shown high activity for alkaline hydrogen evolution reaction. This study investigates their performance in a single-cell setup and reveals the significant impact of activation procedures on cell performance. The study also provides insights into the distribution of Mo, the surface structure, and the reaction mechanism, contributing to the development of efficient catalysts for large-scale hydrogen production.
Article
Materials Science, Multidisciplinary
Sivalingam Muthu Mariappan, Sung Jun Hong, Byungchan Han, Mohd Shkir, Elangovan Vinoth, Stella Mary, K. Janani Archana, Balasubramanian Karthikeyan, Hamed Algarni, Salem AlFaify
Summary: Minimizing carrier-phonon interactions is crucial for designing hot carrier optoelectronic devices. Strontium doped lead sulphide nanoparticles demonstrate excellent sensitizing properties by reducing energy dissipation through carrier-phonon interactions. The bottleneck effect and decreased coupling strength in Sr:PbS nanoparticles suppress energy loss and enhance device performance.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Nanoscience & Nanotechnology
See Wee Koh, Jie Hu, Hoje Chun, Peng Yu, Junyu Ge, Zixu Sun, Wei Hong, Qiunan Liu, Kyungju Nam, Byungchan Han, Zheng Liu, Hong Li
Summary: In this study, two-dimensional ternary palladium phosphoronitride (Pd3P2Nx) was synthesized for the first time for oxygen reduction reaction (ORR) catalysis, with a rational design guided by first-principles density functional theory calculations. The doping process significantly increased the mass activity of the palladium phosphorus sulfide compound and improved its kinetics and stability for ORR. The ORR diffusion-limited current density of Pd3P2Nx exceeded that of commercial Pt/C, showcasing fast kinetics and robust long-term stability.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Eunji Choi, Sung Jun Hong, Junhe Chen, Yeong Jae Kim, Yunkyu Choi, Ohchan Kwon, Kiwon Eum, Ji Il Choi, Seung Soon Jang, Byungchan Han, Dae Woo Kim
Summary: The CO2-selective ZIF-type membrane showed a high CO2 permeance and selectivity by tuning the pore size of the ZIF-8 framework, with CH4 diffusivity being the key factor affecting the CO2 separation performance. Both experimental and computational results confirm the effectiveness of the pore-tuned ZIF-8 framework for CO2 separation.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)