期刊
ADVANCED MATERIALS
卷 34, 期 28, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202201600
关键词
absorption coefficient; near-infrared organic photodetectors; pyrrolo[3; 2-b]thieno[2; 3-d]pyrrole; stretched geometry; transition dipole moments
类别
资金
- National Natural Science Foundation of China [52173189, 22105208]
In this study, an ultrastrong near-infrared absorbing organic semiconductor was designed with high absorption coefficient beyond 900 nm. The resulting organic photodetectors based on this material showed high detectivity and excellent peak values in a wide wavelength range of 310-1010 nm, comparable with or even better than commercial inorganic photodetectors.
Designing ultrastrong near-infrared (NIR) absorbing organic semiconductors is a critical prerequisite for sensitive NIR thin film organic photodetectors (OPDs), especially in the region of beyond 900 nm, where the absorption coefficient of commercial single crystalline silicon (c-Si) is below 10(3) cm(-1). Herein, a pyrrolo[3,2-b]thieno[2,3-d]pyrrole heterocyclic core (named as BPPT) with strong electron-donating property and stretched geometry is developed. Relative to their analogue Y6, BPPT-contained molecules, BPPT-4F and BPPT-4Cl, show substantially upshifted and more delocalized highest occupied molecular orbitals, and larger transition dipole moments, leading to bathochromic and hyperchromic absorption spectra extending beyond 1000 nm with very large absorption coefficients (up to 3.7-4.3 x 10(5) cm(-1)) as thin films. These values are much higher than those (10(4) to 1 x 10(5) cm(-1)) of typical organic semiconductors, and 1-2 orders higher than those of commercial inorganic materials, such as c-Si, Ge, and InGaAs. The OPDs based on BPPT-4F or BPPT-4Cl blending polymer PBDB-T show high detectivity of above 10(12) Jones in a wide wavelength range of 310-1010 nm with excellent peak values of 1.3-2.2 x 10(13) Jones, respectively, which are comparable with and even better than those commercial inorganic photodetectors.
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