4.7 Article

ZrB2-ZrSi2-SiC composites prepared by reactive spark plasma sintering

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ijrmhm.2016.07.011

关键词

Zirconium diboride; Reactive spark plasma sintering; Mechanical properties

资金

  1. National Natural Science Foundation of China [51402264]
  2. China Postdoctoral Science Foundation [2014M561996]
  3. Excellent Young Faculty Research Foundation of Zhengzhou University [1421320049]

向作者/读者索取更多资源

ZrSi2 and SiC are good candidates to improve both sinterability and mechanical properties of ZrB2 ceramics, which were synthesized simultaneously by an in-situ reaction of ZrC and Si additives during the sintering processing in this work. The ZrB2 ceramic composites with different amount of ZrSi2 and SiC were fabricated by reactive spark plasma sintering (RSPS) method. X-ray diffraction, scanning microscopy and Archimedes's method are used to characterize the phase, microstructure and density of the composites. Meanwhile, fracture toughness and flexural strength of the obtained composites were investigated too. It's found that a fully dense composite can be achieved at 1500 degrees C by SPS. Both fracture toughness and flexural strength of ZrB2 ceramics increased with increasing the concentration of ZrSi2 and SiC additives and reached a maximum of 733 +/- 024 MPa.m(1/2) and 471 +/- 15 MPa, respectively, with the ZrSi2 + SiC content of 30 wt%. (C) 2016 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

TiO2-carbon porous nanostructures for immobilization and conversion of polysulfides

Keke Gao, Rui Xu, Yunxiang Chen, Zongtao Zhang, Jiashuo Shao, Haipeng Ji, Liying Zhang, Shasha Yi, Deliang Chen, Junhua Hu, Yanfeng Gao

Summary: The paper presents a strategy to enhance the electrochemical properties of lithium-sulfur batteries by using TiO2-carbon nanocomposites embedded hierarchical porous carbon interlayers. The interlayers effectively immobilize polysulfides and improve the redox reaction kinetics, resulting in improved battery performance.

CHINESE CHEMICAL LETTERS (2023)

Article Biochemistry & Molecular Biology

Structural Evolution and Electronic Properties of Selenium-Doped Boron Clusters SeBn0/- (n=3-16)

Yue-Ju Yang, Shi-Xiong Li, De-Liang Chen, Zheng-Wen Long

Summary: This theoretical research investigates the structural evolution, electronic properties, and photoelectron spectra of selenium-doped boron clusters SeBn0/- (n = 3-16) using particle swarm optimization (CALYPSO) software and density functional theory calculations. The results show that the lowest energy structures of SeBn0/- (n = 3-16) clusters tend to be quasi-planar or planar. The addition of a Se atom modifies and improves some of the pure boron cluster structures. The research enriches the geometrical structures of small doped boron clusters and provides insights for boron-based nanomaterials.

MOLECULES (2023)

Article Environmental Sciences

Enhanced Variability and Declining Trend of Soil Moisture Since the 1880s on the Southeastern Tibetan Plateau

Lu Wang, Hongyan Liu, Jussi Griessinger, Deliang Chen, Changfeng Sun, Congxi Fang

Summary: This study reconstructed the summer soil moisture changes in the southeastern Tibetan Plateau from 1691 to 2007 using tree-ring delta O-18 as a paleoclimate proxy. The results showed an abrupt wet-to-dry change in 1884, followed by a decreasing trend and increased variability in soil moisture. The variability reached an unprecedented level after the 1950s. The study indicates that precipitation, rather than temperature, is the main controlling factor for soil moisture variation.

WATER RESOURCES RESEARCH (2023)

Article Forestry

Estimating Summer Arctic Warming Amplitude Relative to Pre-Industrial Levels Using Tree Rings

Cong Gao, Chunming Shi, Yuxin Lou, Ran An, Cheng Sun, Guocan Wu, Yuandong Zhang, Miaogen Shen, Deliang Chen

Summary: To reconstruct the past Arctic temperature variations, the authors screened 1116 tree-ring width and density records and applied four detrending functions. They selected 338-396 records that showed significant correlations with instrumental temperature data and combined them into a proxy record. The reconstruction explained 45-57% of the instrumental temperature variance since 1950, and the estimated Arctic warming amplitudes were consistent with temperature anomaly datasets.

FORESTS (2023)

Article Environmental Sciences

Runoff Response to Climate in Two River Basins Supplied by Small Glacier Meltwater in Southern and Northern Tibetan Plateau

Ruzhen Yao, Shenghai Li, Deliang Chen

Summary: The Tibetan Plateau has undergone significant warming in recent decades, leading to glacier melt and impacts on river runoff. This study used glacier mass balance measurements and hydrological modeling to analyze the contributions of two glacierized basins to river runoff and investigate their responses to climate changes. The results highlight the dominant role of precipitation changes in these basins, which have small glacier meltwater contributions.

ATMOSPHERE (2023)

Article Water Resources

Characterizing precipitation uncertainties in a high-altitudinal permafrost watershed of the Tibetan plateau based on regional water balance and hydrological model simulations

Huiru Jiang, Yonghong Yi, Jijun Xu, Deliang Chen, Fan Lu, Rongxing Li, Xuejia Wang, Binrong Zhou

Summary: This study evaluates the performance of nine precipitation products in the source region of the Yangtze River. The majority of products are able to replicate the observed decreasing trend of precipitation below 4500 meters, but trends vary at higher elevations. The results indicate that gauge-based precipitation products with bias correction perform best, while most satellite-based products underestimate precipitation.

JOURNAL OF HYDROLOGY-REGIONAL STUDIES (2023)

Article Geosciences, Multidisciplinary

Projections of rainfall erosivity in climate change scenarios for mainland China

Wenting Wang, Shuiqing Yin, Zeng He, Deliang Chen, Hao Wang, Andreas Klik

Summary: This study improves the accuracy of future rainfall erosivity projections in China by selecting five CMIP6-based and bias-adjusted Global Climate Models (GCMs). The results show that GFDL-ESM4, IPSL-CM6A-LR, and UKESM1-0LL models outperform others in estimating rainfall erosivity, especially in regions prone to water erosion. The study projects an increase in rainfall erosivity for most regions in China, indicating the need for enhanced soil and water conservation measures to mitigate the challenges posed by global warming.

CATENA (2023)

Article Environmental Sciences

Heterogeneity in Spatiotemporal Variability of High Mountain Asia's Runoff and Its Underlying Mechanisms

Yanxin Zhu, Yan-Fang Sang, Bin Wang, Arthur Lutz, Shi Hu, Deliang Chen, Vijay P. Singh

Summary: This study investigates the spatial heterogeneity of runoff variability in High Mountain Asia (HMA) and the roles of climate conditions and catchment properties. Results show significant variability of runoff at different timescales, with climate variations and catchment properties playing important roles. These findings have critical implications for sustainable freshwater management and risk mitigation in HMA.

WATER RESOURCES RESEARCH (2023)

Article Meteorology & Atmospheric Sciences

Fire carbon emissions over Equatorial Asia reduced by shortened dry seasons

Sifan Wang, Bin He, Hans W. Chen, Deliang Chen, Yaning Chen, Wenping Yuan, Feng Shi, Jianping Duan, Wei Wu, Tiexi Chen, Lanlan Guo, Ziqian Zhong, Weili Duan, Zhi Li, Weiguo Jiang, Ling Huang, Xingming Hao, Rui Tang, Huiming Liu, Yafeng Zhang, Xiaoming Xie

Summary: The length of the dry season over Equatorial Asia has significantly decreased due to increased precipitation in the early dry season. This has led to a significant reduction in fire carbon emissions during the early and peak fire season. Climate models project a further decline in dry season length, indicating further reductions in fire carbon emissions.

NPJ CLIMATE AND ATMOSPHERIC SCIENCE (2023)

Article Environmental Sciences

Increased southerly and easterly water vapor transport contributed to the dry-to-wet transition of summer precipitation over the Three-River Headwaters in the Tibetan Plateau

Xuan Liu, Ming-Xiang Yang, Ning-Peng Dong, Wei-Ning Xie, Zhen Guan, Fan Wen, Hao Wang, Deliang Chen

Summary: This study investigates the changes in summer precipitation in the Three-River Headwaters region using observational and ERA5 reanalysis data. The results show an increasing trend in summer precipitation with a significant dry-to-wet transition in 2002. The study also attributes the transition and increased precipitation to changes in atmospheric circulations and water vapor transport.

ADVANCES IN CLIMATE CHANGE RESEARCH (2023)

Article Environmental Sciences

Changes in the supply and demand potentials of China's glacier water resources in the 21st century: Spatiotemporal mismatches and combined effects

Bo Su, Hong-Yu Zhao, Heng Ma, Can Zhang, Deliang Chen, Bin Chen, Yi Huang, Shi-Wei Liu, Tong Zhang, Cun-De Xiao

Summary: This study evaluates the supply and demand potentials of China's glacier water resources and their effects, taking into account the downstream countries' demand. The study reveals the spatial and temporal matches between the supply and demand potentials. It finds that some basins rely heavily on glacier meltwater for water supply, but there are also risks and pressures due to decreasing glacier runoff and increasing population.

ADVANCES IN CLIMATE CHANGE RESEARCH (2023)

Article Engineering, Civil

Quantifying precipitation moisture contributed by different atmospheric circulations across the Tibetan Plateau

Chi Zhang, Xu Zhang, Qiuhong Tang, Deliang Chen, Jinchuan Huang, Shaohong Wu, Yubo Liu

Summary: Precipitation over the Tibetan Plateau is influenced by systems such as the Asian monsoons, the westerlies, and local circulations. The Indian monsoon, the westerlies, and local circulations are the main systems affecting precipitation over the entire Tibetan Plateau. The East Asian summer monsoon primarily affects the eastern Tibetan Plateau. The Indian monsoon has the greatest influence on precipitation in the southern and central grid cells, while the westerlies have the greatest influence on precipitation in the northern and western grid cells. Local circulations have the strongest influence on the central and eastern grid cells.

JOURNAL OF HYDROLOGY (2024)

Article Multidisciplinary Sciences

Reversed asymmetric warming of sub-diurnal temperature over land during recent decades

Ziqian Zhong, Bin He, Hans W. Chen, Deliang Chen, Tianjun Zhou, Wenjie Dong, Cunde Xiao, Shang-ping Xie, Xiangzhou Song, Lanlan Guo, Ruiqiang Ding, Lixia Zhang, Ling Huang, Wenping Yuan, Xingming Hao, Duoying Ji, Xiang Zhao

Summary: In recent decades, there has been an increase in the diurnal temperature range, with daily maximum temperatures warming at a faster rate while daily minimum temperatures remain stable. This may be due to reduced cloud cover leading to increased solar radiation.

NATURE COMMUNICATIONS (2023)

Article Environmental Sciences

Fate and Changes in Moisture Evaporated From the Tibetan Plateau (2000-2020)

Chi Zhang, Deliang Chen, Qiuhong Tang, Jinchuan Huang

Summary: This study tracked and quantified the moisture originating from the Tibetan Plateau (TP) and its influence on downwind regions. The findings show that the TP moisture has the strongest impact on precipitation in the eastern boundary of the TP, gradually diminishing eastward. The TP moisture ratio in precipitation reaches its highest over the central-eastern TP, accounting for over 30%. A significant portion of TP annual evaporation is recycled within the TP, while the majority is reprecipitated over terrestrial China. The recycling of TP moisture exhibits seasonal variation determined by precipitation, evaporation, and wind patterns.

WATER RESOURCES RESEARCH (2023)

Article Geosciences, Multidisciplinary

Separating Direct Heat Flux Forcing and Freshwater Feedback on AMOC Change Under Global Warming

Qin Wen, Chenyu Zhu, Deliang Chen, Mengyu Liu, Liang Ning, Mi Yan, Jian Liu, Zhengyu Liu

Summary: This study separates the heat flux and freshwater feedback in the AMOC change and finds that they dominate at different timescales. It provides important insights into understanding the mechanism of AMOC under global warming.

GEOPHYSICAL RESEARCH LETTERS (2023)

Article Materials Science, Multidisciplinary

The effect of Ta on oxidation resistance of in-situ TiC/Ni composites

Ziyan Zhao, Kaiyue Zheng, Xianghui Yu, Qian Qi, Lujie Wang, Yan Liu

Summary: In-situ TiC/Ni composites with Ta element were fabricated by reactive sintering. It was found that Ta element could reduce the oxidation rate and decrease the content of TiO2 and NiTiO3 in the oxide scale, thereby optimizing the oxidation resistance and electrical conductivity of the composites.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Role of V(C, N) on gradient structure formation and mechanical properties of nanocrystalline cemented carbides

Kai Wang, Mingyuan Ma, Yingchun Diao, Qijun Huang, Xiangkui Zhou, Guojian Li, Qiang Wang

Summary: The relationship between the V(C, N) content and the thickness of the gradient layer in nanocrystalline cemented carbides was investigated. The introduction of V(C, N) was found to enhance the mechanical properties of these materials.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Influence of sintering parameters on the microstructure and mechanical properties of WC-Co hardmetals

Claudio Bertalan, Steven Moseley, Leonel Pereira, Ralph Useldinger

Summary: The influence of sintering temperature, dwelling time at maximum temperature and carbon content on the microstructure and mechanical and magnetic properties of WC-6%Co hardmetal was investigated. Results showed that to maximize hardness and transverse rupture strength (TRS), sintering should be performed at a low temperature (< 1400°C) and with a dwelling time of at least 75 minutes. This is particularly important for low carbon parts to ensure the necessary microstructure homogeneity required for high TRS.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Effects of bias voltage on the structure, mechanical properties and tribological properties of TaBx films at elevated temperatures

Longlong Sun, Hang Li, Ningxin Wei, Jianliang Li, Jiewen Huang, Jian Kong, Qiujie Wu, Yan Shi, Dangsheng Xiong

Summary: By regulating the microstructure of TaBx films deposited by magnetron sputtering, the hardness and wear resistance of the films can be improved. With the increase of the bias voltage, the B content decreases and the crystallinity is enhanced. The microstructure of the films transforms from fibrous to dense columnar and then to granular structure. At a bias voltage of -180 V, the films exhibit super high hardness and relatively moderate fracture toughness.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Ion-irradiation induced hardening behavior of zirconium alloys: A combination of experimental and theoretical study

Liang Xia, Kai Liu, Yucheng Cao, Chao Jiang

Summary: This study investigates the microstructure information and mechanical behavior of ion-irradiated zirconium alloys through experimental measurements and theoretical analysis. Experimental procedures involve Au3+ irradiation of specific alloys, and transmission electron microscopy analysis reveals the formation of precipitates and their transformation after ion-irradiation. Macroscopic mechanical properties are characterized by nano-indentation tests, revealing significant indentation size effect and irradiation hardening behavior. A mechanistic model is developed to explain the depth-dependent hardness observed in ion-irradiated zirconium alloys.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Dynamic simulation of powder spreading processes toward the fabrication of metal-matrix diamond composites in selective laser melting

Jiangtao Zhang, Guoqin Huang, Yangli Xu, Jianyu Wang, Guangyao Han, Yuanqiang Tan

Summary: Selective laser melting (SLM) provides a novel method for the integrated production of structural and functional metal-matrix diamond composites in the field of diamond tools. In this study, a discrete element method model is developed to simulate the spreading process of diamond/CuSn composite powders. The findings reveal that adjusting the physical properties of diamond particles and process parameters can improve the powder bed quality and particle dynamics, leading to better performance of diamond tools.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Tribological and corrosion properties of β-TiNb alloy modified by plasma electrolytic oxidation: Evaluation of the synergistic effect of composition and processing time through statistical evaluation

Roman Gabor, Ladislav Cvrcek, Karel Masek, Josef Hlinka, Oldrich Motyka, Jan Walter, Grazyna Simha Martynkova, Gabriela Mikeskova, Jana Seidlerova

Summary: This study investigated the surface modification of β-Ti39Nb alloy using micro-arc oxidation technique, and examined the relationships between surface chemical composition, morphology, and tribological and corrosion properties. The results showed that the technique improved the wear resistance of the alloy, and the particle analysis confirmed the correlation between particle composition and tribological parameters.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Scanning photoelectron microscopy discloses the role of Cr and Mo in the selective corrosion of hardmetal grades with Co-Ni binders

Benedetto Bozzini, Matteo Amati, Luca Gregoratti, Majid Kazemian, Francesco Tavola, Sandra Tedeschi, Gian Pietro De Gaudenzi

Summary: In this study, the composition and chemical state of the surface of hardmetal subjected to controlled electrochemical corrosion were analyzed using synchrotron-based scanning photoelectron microscopy and photoelectron microspectroscopy. The results showed that corrosion under different conditions led to surface enrichment and leaching of different chemical elements and species.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Recent metrological approaches relevant to the characterisation of hardmetals

B. Roebuck, M. G. Gee, K. P. Mingard, H. G. Jones, H. Zhang, V. Tong

Summary: Metrology provides scientific support for the practical use of testing standards and helps establish a common language for different users regarding material capabilities. The hardmetal industry already has numerous international standards, but there is still room for improvement in certain testing strategies. The Materials Group at the National Physical Laboratory in the UK focuses on metrology and has highlighted specific metrological issues that need further attention. These include high hardness measurements, dislocation analysis, micro-tribology, nanoindentation, and structural characterization.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Effect of nanopowder preparation method on the sintering behavior and microstructure of Mo-W alloy

Suyeon Kim, Taehyun Kwon, Seulgi Kim, Sung Ho Song, Dongju Lee

Summary: This study examines the effect of two different methods, oxide reduction and mechanical alloying, on the sintering behavior and microstructure of molybdenum-tungsten sintered compacts. The sintered compacts produced with oxide-reduced nanopowders exhibit higher density, purity, and a finer microstructure, making them more suitable for sputtering targets.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Prediction of hardmetal corrosion based on the binder response

A. M. Ferro Rocha, A. M. Santos, R. Mineiro, P. Pereira, J. Sacramento, A. M. R. Senos, A. C. Bastos

Summary: This study compares the corrosion resistance of different hardmetal composites and their binders in a corrosive environment. Through electrochemical testing methods, the corrosion behavior of these materials was studied, and the influence of the binder's electrochemical behavior on the corrosion resistance of hardmetal was explored.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Strengthening mechanism of Cr doping in Mo2FeB2-based cermets and effects on biphase interface

Bo Li, Yong Zheng, Wangwang Wang, Hao Wu, Yufan Li, Jin Lv

Summary: The effects of various Cr doping amounts on the microstructure and properties of Mo2FeB2-based cermets were investigated using EDS, SEM, and TEM. The results showed that moderate Cr doping enhanced the system's wettability, fracture toughness, and transverse rupture strength, while excessive Cr addition decreased mechanical properties. The solid-solution of Cr in the hard phase had the most pronounced effect on the mechanical properties of the cermets.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Enhancing the fracture toughness of polycrystalline diamond by adjusting the transgranular fracture and intergranular fracture modes

Min Lian, Fei Wang, Kaixuan Rong, Xiaoci Ma, Hetian Liu, Xinmiao Gai, Yufei Ge, Shushan Dong, Qiang Tao, Pinwen Zhu

Summary: This study successfully optimized the toughness of polycrystalline diamond (PCD) by adjusting the intergranular fracture (IF) and transgranular fracture (TF) modes. The results showed that a mixture of the IF and TF modes resulted in higher hardness and toughness in PCD compared to a single fracture mode. The toughness of the PCD was approximately three times that of single-crystal diamonds and comparable to that of pure nanotwinned diamonds. The mixed modes introduced toughening mechanisms such as high frequency large crack deflection, crack bridging, pull-out, and crack branching, which increased the toughness of the PCD.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Regulation of particle size and morphology of tungsten powders in bottom-blowing hydrogen reduction process

Ruifang Wang, Xiang Zhan, Yongqiang Chen, Chao Zhang, Yusi Che, Jilin He

Summary: The particle size and morphology of tungsten powders play a crucial role in determining the processing properties of tungsten products. This study investigated the effects of water vapor partial pressure on the hydrogen reduction of tungsten oxides, and proposed a method of changing the particle size of tungsten powders using bottom blowing hydrogen. The experimental results showed that bottom-blowing hydrogen could improve the uniformity of tungsten powders in a crucible by eliminating discrepancies in water vapor partial pressure. The partial pressure of water vapor increased with the temperature of the water bath, leading to an increase in the average particle size of tungsten powders.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)

Article Materials Science, Multidisciplinary

Property correlations of WC-Co with modified binders

Oladapo Eso, Xu Wang, Samuel Wolf, Travis Puzz

Summary: In recent decades, there has been an increasing trend in incorporating alloying additives into WC-Co hardmetals for property enhancement. This paper establishes correlations between properties and microstructure of binder modified WC-Co compositions, and explains the observed property correlations.

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS (2024)