Article
Energy & Fuels
Yakun Wang, Kai Pei, Bote Zhao, Yun Zhao, Haobing Wang, Quan Niu, Yu Chen
Summary: The study found that the composite electrode with an 8:2 mass ratio of BSCFN-BZCYYb exhibits the best performance in fuel cells, with a peak power density of 1.14 W/cm2, an electrode polarization resistance of 0.062 ohm·cm2, and a reasonable durability test lasting 24 hours at -0.5A/cm2 at 750 degrees Celsius. Additionally, a stable operation of the cell in dual modes of electrolysis and fuel cell for approximately 50 hours at +/- 0.5 A/cm2 was achieved, demonstrating good reversibility.
Article
Materials Science, Ceramics
Hiroyuki Shimada, Yuki Yamaguchi, Hirofumi Sumi, Yasunobu Mizutani
Summary: By modifying the cathode/electrolyte interface with a porous BZCYYb interlayer (PBI) in PCFCs, the cathode performance has been significantly improved, achieving high power density at lower temperatures. The use of this interlayer enhances the cathode/electrolyte interfacial structure and increases the triple-phase boundary, resulting in improved overall performance of the fuel cell.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Xiaoyang Wang, Xiaoqing Si, Chun Li, Xiajun Guo, Jian Cao
Summary: The lack of sealing technology for PCFC stacks presents a challenge for the commercialization of protonic ceramic fuel cells, but this study successfully used Ag-CuO braze to join the BZCYYb electrolyte to AISI 441 interconnect. By changing the CuO content, the wettability of the braze on the BZCYYb surface can be tailored, leading to a suitable joint microstructure. Additionally, the Ag-CuO braze system shows long-term stability after aging tests, indicating its applicability for fabricating PCFC stacks.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Multidisciplinary Sciences
Wenjuan Bian, Wei Wu, Baoming Wang, Wei Tang, Meng Zhou, Congrui Jin, Hanping Ding, Weiwei Fan, Yanhao Dong, Ju Li, Dong Ding
Summary: Researchers improved the electrochemical performance and stability of protonic ceramic fuel cells by acid treatment, enabling exceptional performance at lower temperatures.
Article
Chemistry, Multidisciplinary
Hua Zhang, Yucun Zhou, Kai Pei, Yuxin Pan, Kang Xu, Yong Ding, Bote Zhao, Kotaro Sasaki, YongMan Choi, Yu Chen, Meilin Liu
Summary: Ammonia protonic ceramic fuel cells (PCFCs) have the potential to be a highly efficient power source with high energy density, but the catalytic activity of existing anodes for ammonia utilization is inadequate. This study presents an Fe-modified Ni/BZCYYb anode with enhanced activity and durability, providing valuable guidance for the development of efficient electro-catalysts for ammonia PCFCs.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Physical
Sung Hyun Hwang, Soon Ki Kim, Jun-Tae Nam, Jong-Sung Park
Summary: The study optimized the performance of a cathode for protonic ceramic fuel cells by employing a triple-component composite cathode design, which significantly improved the performance of CH4 fuel and suggests a possible contribution of the oxygen reduction reaction at the cathode to the reformation of CH4 at the anode.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Allan J. M. Araujo, Vanessa C. D. Graca, Rafael A. Raimundo, Antonio C. L. Filho, Daniel A. Macedo, Francisco J. A. Loureiro
Summary: Protonic ceramic cells (PCCs) have the potential to be energy conversion devices operating at lower temperatures. This study introduces Ba2Co9O14 (BCO) as an electrocatalyst for oxygen reactions in PCCs, demonstrating high electrochemical performance and chemical compatibility. The results highlight the importance of surface diffusion in explaining the high-performing behavior of BCO electrodes.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Review
Chemistry, Multidisciplinary
Jun Zhang, Sandrine Ricote, Peter Vang Hendriksen, Yunzhong Chen
Summary: Solid oxide fuel cells (SOFCs) are efficient electrochemical energy conversion devices that have the potential to become low cost. However, their high operating temperatures have hindered their widespread commercialization. This review summarizes the recent progress in developing materials to lower the operating temperature of SOFCs and discusses the new opportunities and challenges. The focus is on thin film SOFCs, sub-micrometer SOFCs based on microelectromechanical systems, and devices based on proton-conducting oxide electrolyte.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
Energy & Fuels
Idris Temitope Bello, Shuo Zhai, Qijiao He, Chun Cheng, Yawen Dai, Bin Chen, Yuan Zhang, Meng Ni
Summary: Protonic ceramic fuel cells (PCFCs) are considered a potential and more efficient upgrade to conventional solid oxide fuel cells (SOFCs) due to their efficient operation at low and intermediate temperatures and nonfuel dilution at the anode during operation. This review provides a detailed exposition of material development strategies for major components of PCFCs and discusses credible science-backed recommendations for synthesis and fabrication of PCFCs materials. Additionally, the opportunities, challenges, and future directions for P-SOFCs are highlighted as well.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Materials Science, Ceramics
Zidai Fan, Dan Cao, Mingyang Zhou, Ziyi Zhu, Meilong Chen, Jiang Liu
Summary: Proton-conducting perovskite oxide BaCe0.7Zr0.1Y0.2O3-delta (BZCY) is prepared using carbonate coprecipitation method with Tween-80 as the surfactant, resulting in well dispersed particles with an average size of 200 nm. The BZCY powder is used as the electrolyte material in a Ni-based anode-supported protonic ceramic fuel cell (PCFC). The electrolyte can be densified without any sintering aids at 1400 degrees C in open air, and the PCFC exhibits a peak power density of 1050 mW cm-2 at 700 degrees C, with a conducting activation energy of 0.36 eV. The superiority of the BZCY powder prepared using the coprecipitation method is demonstrated by comparing it with a BZCY powder made by conventional solid-state reaction method.
CERAMICS INTERNATIONAL
(2023)
Article
Energy & Fuels
Sung Jea Yang, Wanhyuk Chang, Heon Jun Jeong, Dong Hwan Kim, Joon Hyung Shim
Summary: This study demonstrated the enhanced performance of protonic ceramic fuel cells by adopting electrode-electrolyte cathode functional layers (CFLs), resulting in improved power output and reduced electrode polarization resistance. The extended interface between the cathode and electrolyte in the CFLs was found to contribute to the enhancement of electrode performance.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Chemistry, Physical
Arim Seong, Donghwi Jeong, Minseo Kim, Sihyuk Choi, Guntae Kim
Summary: This study investigates the effect of composite cathodes on the electrochemical performance of protonic ceramic fuel cells (PCFCs). It is found that combining proton-conducting oxide with a mixed ionic and electronic conductor or a triple ionic and electronic conductor can significantly enhance the peak power density, with the reduction in non-charge transfer resistance playing a key role.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Donguk Kim, Tae Kyeong Lee, Seungwoo Han, Yuhan Jung, Dong Gyu Lee, Mingi Choi, Wonyoung Lee
Summary: Unlike SOCs, PCCs utilize protons as primary charge carriers and show higher ionic conductivity with lower activation energy. They have advantages such as easy gas separation and no fuel dilution, making them an attractive option for commercialization. However, their performance and stability still need improvement compared to SOCs.
MATERIALS TODAY ENERGY
(2023)
Article
Chemistry, Multidisciplinary
Heon Jun Jeong, Wanhyuk Chang, Beum Geun Seo, Yun Sung Choi, Keun Hee Kim, Dong Hwan Kim, Joon Hyung Shim
Summary: This study presents the performance and durability of protonic ceramic fuel cells (PCFCs) in an ammonia fuel injection environment. The use of a palladium (Pd) catalyst improves the low ammonia decomposition rate in PCFCs with lower operating temperatures. By treating the anode with Pd catalyst, the performance of PCFCs is significantly enhanced, with a peak power density of 340 mW cm (-2) at 500 degrees C. The Pd catalysts are deposited through an atomic layer deposition post-treatment process, improving current collection and reducing polarization resistance in the low-temperature region.
Article
Chemistry, Physical
Xiaoyang Wang, Chun Li, Qihan Zhou, Mingshen Li, Mushi Zheng, Junlei Qi, Xiaoqing Si, Jian Cao
Summary: Sealing electrolytes and interconnects is a critical challenge for protonic ceramic fuel cell stacks. This study presents a solution to the oxidation and brittleness issues caused by traditional sealants by using a silver particle interlayer with high dislocation density to join the electrolyte and interconnect. The joints exhibit superior oxidation resistance and aging performance after aging tests.
JOURNAL OF MATERIOMICS
(2022)
Article
Chemistry, Physical
Elia Gianotti, Melanie Taillades-Jacquin, Alvaro Reyes-Carmona, Gilles Taillades, Jacques Roziere, Deborah J. Jones
APPLIED CATALYSIS B-ENVIRONMENTAL
(2016)
Article
Chemistry, Physical
Melanie Taillades-Jacquin, Carlo Resini, Kan-Ern Liew, Gilles Taillades, Ilenia Gabellini, David Wails, Jacques Roziere, Deborah Jones
APPLIED CATALYSIS B-ENVIRONMENTAL
(2013)
Article
Chemistry, Physical
Elia Gianotti, Alvaro Reyes-Carrnona, Melanie Taillades-Jacquin, Gilles Taillades, Jacques Roziere, Deborah J. Jones
APPLIED CATALYSIS B-ENVIRONMENTAL
(2014)
Article
Chemistry, Applied
Carlo Lucarelli, Stefania Albonetti, Angelo Vaccari, Carlo Resini, Gilles Taillades, Jacques Roziere, Kan-Ern Liew, Alexander Ohnesorge, Christian Wolff, Ilenia Gabellini, David Wails
Article
Chemistry, Applied
Alvaro Reyes-Carmona, Elia Gianotti, Melanie Taillades-Jacquin, Gilles Taillades, Jacques Roziere, Enrique Rodriguez-Castellon, Deborah J. Jones
Article
Chemistry, Multidisciplinary
Julien Bernard d'Arbigny, Gilles Taillades, Mathieu Marrony, Deborah J. Jones, Jacques Roziere
CHEMICAL COMMUNICATIONS
(2011)
Article
Chemistry, Physical
Zohreh Khani, Melanie Tallades-Jacquin, Gilles Taillades, Deborah J. Jones, Mathieu Marrony, Jacques Roziere
CHEMISTRY OF MATERIALS
(2010)
Article
Electrochemistry
G. Taillades, J. Dailly, M. Taillades-Jacquin, F. Mauvy, A. Essouhmi, M. Marrony, C. Lalanne, S. Fourcade, D. J. Jones, J. -C. Grenier, J. Roziere
Article
Chemistry, Physical
J. Dailly, M. Marrony, G. Taillades, M. Taillades-Jacquin, A. Grimaud, F. Mauvy, E. Louradour, J. Salmi
JOURNAL OF POWER SOURCES
(2014)
Article
Chemistry, Applied
Gilles Taillades, Pierre Batocchi, Abdel Essoumhi, Melanie Taillades, Deborah J. Jones, Jacques Roziere
MICROPOROUS AND MESOPOROUS MATERIALS
(2011)
Proceedings Paper
Electrochemistry
G. Taillades, P. Pers, P. Batocchi, M. Taillades
SOLID OXIDE FUEL CELLS 13 (SOFC-XIII)
(2013)
Proceedings Paper
Electrochemistry
J. Bernard d'Arbigny, G. Taillades, J. Roziere, D. J. Jones, M. Marrony
POLYMER ELECTROLYTE FUEL CELLS 11
(2011)
Proceedings Paper
Electrochemistry
G. Taillades, P. Batocchi, M. Taillades, D. Jones, J. Roziere
SOLID OXIDE FUEL CELLS 12 (SOFC XII)
(2011)
Proceedings Paper
Electrochemistry
Christos Argirusis, Jana Grosse-Brauckmann, Georgia Sourkouni, Gilles Taillades, Jaques Roziere
ELECTROPHORETIC DEPOSITION: FUNDAMENTALS AND APPLICATIONS III
(2009)