4.7 Article

Hydrogen storage in heavily deformed ZK60 alloy modified with 2.5 wt.% Mm addition

期刊

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 41, 期 7, 页码 4177-4184

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.01.036

关键词

Magnesium alloy; Mischmetal addition; Severe plastic deformation; Activation

资金

  1. CNPq
  2. FAPESP

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Severe plastic deformation techniques have been extensively used to improve hydrogen storage properties of magnesium based alloys. In this work, the commercial magnesium alloy ZK60 (Mg-6Zn-1Zr in wt.%) was modified with addition of 2.5 wt.% of mischmetal (55Ce-24La-15Nd-4Pr in wt.%) and subsequently processed by equal-channel angular pressing (ECAP) and extensive cold rolling (CR). Due to the mischmetal addition, a network of intermetallic particles was formed at the grain boundaries. Besides Zn and Zr, the particles also contained the rare-earth elements La and Ce. With CR, a breakage of intermetallics occurred, that could also have played a role in enhancing the hydrogen storage properties. Ultimately, after the combined processing of ECAP followed by CR cold rolling, a significant increase in the storage capacity and activation kinetics was observed. Copyright (C) 2016, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

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