期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 41, 期 41, 页码 18478-18483出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.08.082
关键词
Acrylonitrile; Hydrogenation; Propionitrile; Raney Ni; Kinetics
资金
- Natural Science Foundation of China [21376213, 21476194]
- Zhejiang Provincial Public Technology Research of China [2014C31123, 2015C31038]
- China Postdoctoral Science Foundation [2016M590536]
- Fundamental Research Funds for the Central Universities [JUSRP115A05]
Hydrogenation of acrylonitrile to propionitrile catalyzed by Raney Ni was accessible with good yield and high selectivity under optimized reaction conditions. Kinetic modeling was performed by means of computer aided autoclave reaction; the apparent activation energy of this reaction was determined to be 31.3 kJ/mol. This reaction is controlled by Raney Ni surface. The reaction is apparently zero-order reaction with respect to acrylonitrile and first-order reaction regarding the concentration of dissolved hydrogen in the liquid phase, respectively. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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