Article
Chemistry, Multidisciplinary
Lin Hong, Liang-Yu Wang, Yuling Wang, Xiuming Wu, Wei Huang, Yongfeng Zhou, Kai-Xue Wang, Jie-Sheng Chen
Summary: This study successfully addresses the issues of dendrite growth and hydrogen evolution reaction on zinc metal anodes in Zn-ion batteries by developing a uniform and robust metallic Sb protective layer. The modified Zn anodes exhibit excellent cycling stability with dendrite-free and hydrogen-free behaviors.
Review
Chemistry, Multidisciplinary
Vo Pham Hoang Huy, Luong Trung Hieu, Jaehyun Hur
Summary: Rechargeable aqueous Zn-ion batteries have attracted significant interest as potential alternatives to lithium-ion batteries due to their low cost and high theoretical capacity, but constraints associated with Zn metal anodes have hindered further advancements in this technology. Various strategies have been proposed to overcome the limitations of Zn metal anodes, but a successful solution has not yet been developed.
Review
Chemistry, Physical
Zhehan Yi, Guoyuan Chen, Feng Hou, Liqun Wang, Ji Liang
Summary: Zinc-ion batteries are considered promising candidates for next-generation energy storage systems due to their high safety, resource availability, and environmental friendliness. However, the instability of the Zn metal anode has hindered their reliable deployment, and efforts have been made to overcome this through electrode structure design, interface modification, and electrolyte/separator optimization. Understanding and categorizing these strategies based on their intrinsic mechanisms are important for the development of novel Zn metal anodes for ZIBs.
ADVANCED ENERGY MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Yuhan Zou, Xianzhong Yang, Lin Shen, Yiwen Su, Ziyan Chen, Xiang Gao, Jiang Zhou, Jingyu Sun
Summary: This review summarizes the emerging design strategies for directing the orientation of zinc deposition and elaborates on the mechanistic insights towards achieving highly reversible zinc anodes. The existing challenges and future outlook in this field are also proposed to envision the commercialization of AZIBs.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Le Gao, Lin Qin, Bo Wang, Mingdong Bao, Yingwen Cao, Xidong Duan, Weiyou Yang, Xiangdong Yang, Qing Shi
Summary: By fabricating submicron-thick zincophilic CrN coatings, long lifespan and high Coulombic efficiency have been achieved in Zn-ion batteries (ZIBs), with effective suppression of dendrite formation and parasitic reactions, as well as uniform zinc deposition.
Article
Chemistry, Multidisciplinary
Jung Been Park, Changhoon Choi, Sang Won Jung, Byeong Chan Min, Jong Hyun Park, Dong-Wan Kim
Summary: This study develops a stable Zn metal anode in aqueous rechargeable Zn metal batteries (ARZMBs) by designing a Sn-based interfacial layer (ZnTCF@Sn) on Zn with textured crystal facets. ZnTCF@Sn provides abundant zincophilic sites and high surface energy, resulting in fast electrochemical kinetics and dendrite-free deposition. Furthermore, the uniform Sn coverage on the ZnTCF@Sn surface inhibits side reactions and enhances reversibility during Zn deposition/dissolution.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Yaotang Zhong, Mingzhu Liu, Yitong Lu, Baoling Qiu, Jinheng Yu, Hebing Zhou, Zhenghui Pan, Weishan Li
Summary: Researchers have developed an advanced zinc anode by constructing a bi-component layer consisting of indium particles surrounded by zinc-indium alloy. This artificial layer allows highly reversible zinc deposition/stripping and inhibits dendrite growth, while also providing a high hydrogen evolution overpotential. The zinc anode with this layer exhibits a low depositing/stripping overpotential and ultra-long cyclic lifespan, making it suitable for practical applications in zinc metal batteries. In addition, a full cell with the zinc anode and Na3V2(PO4)3 cathode displays excellent cyclic stability and high Coulombic efficiency.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Zhenyue Xing, Yanyan Sun, Xuesong Xie, Yan Tang, Guofu Xu, Junwei Han, Bingan Lu, Shuquan Liang, Gen Chen, Jiang Zhou
Summary: In this work, a versatile protective coating with excellent zincophilic and amphoteric features is constructed on the surface of Zn metal to solve the issues of short lifespan and low Coulombic efficiency in Zn metal batteries. This protective coating mitigates the hydrogen evolution reaction and promotes uniform zinc deposition, resulting in improved reversibility and cycling stability of the battery.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Fengxue Duan, Xiuxiu Yin, Junjie Ba, Junpeng Li, Yue Yu, Chunyu Wang, Yingjin Wei, Yizhan Wang
Summary: A hydrophobic and zincophilic interfacial nanofilm is developed as a protective layer for Zn anodes, addressing the challenges of H2 evolution and Zn dendrite formation. The nanofilm acts as a barrier to isolate water from the electrode and actively participates in the uniform deposition of Zn2+ ions, resulting in stable and reversible Zn plating and stripping behavior.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Physical
Wei Nie, Hongwei Cheng, Qiangchao Sun, Shuquan Liang, Xionggang Lu, Bingan Lu, Jiang Zhou
Summary: Rechargeable aqueous Zn-ion batteries (AZIBs) are considered a promising alternative to traditional energy-storage devices due to their low cost, abundant resources, environmental friendliness, and safety. However, the use of Zn metal anodes in AZIBs faces several challenges including dendrite formation, hydrogen evolution, corrosion, and passivation. This review provides a comprehensive summary of these issues and proposes strategies to develop high-performance Zn anodes, including structurally designed Zn anodes, Zn alloy anodes, surface modification, electrolyte optimization, and separator design. It offers valuable insights and perspectives for the development and application of stable Zn metal anodes in power grid systems.
Review
Chemistry, Multidisciplinary
Funian Mo, Ning He, Lina Chen, Mengrui Li, Suzhu Yu, Jiaolong Zhang, Wenhui Wang, Jun Wei
Summary: This review summarizes and categorizes various strategies with fundamental design principles to address the persistent challenges of dendrites and hydrogen evolution reaction (HER) on zinc anodes in rechargeable zinc-based batteries (RZBs). It critically dissects these strategies based on their intrinsic mechanisms. Additionally, the challenges and perspectives for the future development of zinc anodes are emphasized.
FRONTIERS IN CHEMISTRY
(2022)
Article
Engineering, Multidisciplinary
Hou ZhenHua, Tao HuaChao, Wang JiaXu, Zhang LuLu, Yang XueLin
Summary: A simple in-situ growth strategy was applied to fabricate a Zn anode with a ZnO protective layer, which successfully lengthened the cycle life and inhibited the dendrite growth and side reactions. The Zn/ZnO anode showed excellent performance in symmetrical cells and composite cells.
SCIENCE CHINA-TECHNOLOGICAL SCIENCES
(2022)
Article
Chemistry, Multidisciplinary
Hui Zhang, Yongjian Wu, Jing Yu, Tongtong Jiang, Mingzai Wu
Summary: A multifunctional sieve (MS) consisting of inorganic nanolayers and organic molecule layers was proposed to solve the multiple issues of Zn-metal anode in Zn ion battery (ZIB), including corrosion reaction, hydrogen evolution, and dendrite growth. The MS, represented by SA@TiO2-MS, could accelerate Zn2+ diffusion, repel H2O, and bind with OH- on the surface of zinc anodes, effectively alleviating the detrimental effects and prolonging the lifespan of the battery.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Mengke Liu, Jinyan Cai, Jun Xu, Kaiwen Qi, Qianyao Wu, Huaisheng Ao, Tiansheng Zou, Shengquan Fu, Shuqing Wang, Yongchun Zhu
Summary: This study provides new insights into traditional metal pretreatment for high stable zinc anodes, offering a potential solution for the development of aqueous zinc-metal batteries with improved stability and performance. The developed pretreatment methodology allows for the formation of protective coatings on zinc foils, promoting flat growth and preventing side reactions.
Article
Chemistry, Physical
Huimin Zhao, Zhenzhen Chi, Qingwei Zhang, Dezhi Kong, Lin Li, Ziyang Guo, Lei Wang
Summary: A mixed protection layer composed of reduced graphene oxide (rGO) and Sn/Cu dual-metal was modified on Zn foil (rGO-SnCu/Zn) to facilitate the uniform Zn electrodeposition and enhance the cyclic stability of AZBs. The rGO-SnCu/Zn electrode exhibited lower voltage hysteresis, higher stability, and better rate capability in Zn-based batteries. The method of suppressing Zn dendrites could provide a new way for AZBs with long life spans.
APPLIED SURFACE SCIENCE
(2023)
Article
Spectroscopy
Xiaoli Li, Zhaoshui Yu, Jinli Xu, Yanshan Pan, Wei Bo, Bin Liu, Pengpeng Zhang, Jinfeng Bai, Qin Zhang
Summary: A new sample preparation technique using high pressure pressed pellet and coated with a polyester film is proposed for major and trace element determination in geochemical samples by wavelength dispersive X-ray fluorescence spectrometer. The accuracy of the method is evaluated using calibration curves created with reference materials and certified reference materials.
X-RAY SPECTROMETRY
(2023)
Article
Statistics & Probability
Jingfei Zhang, Will Wei Sun, Lexin Li
Summary: In this article, a new generalized matrix response regression model is proposed for the analysis of multiple-subject network data. The model characterizes the connectivity pattern of the network data and the effect of subject covariates through a low-rank intercept matrix and a sparse slope tensor, respectively. An efficient parameter estimation algorithm is developed, and an error bound for the estimator's accuracy is established. The efficacy of the method is demonstrated through simulations and brain connectivity studies.
JOURNAL OF COMPUTATIONAL AND GRAPHICAL STATISTICS
(2023)
Article
Chemistry, Medicinal
Jingjing Zhang, Hualing Zhu, Lixia Xiong, Jun Shi, Zhiqiang Huang
Summary: By designing and synthesizing benzoylureas analogues with carbamate groups, it was found that these compounds exhibited good larvicidal activities against a broad spectrum of insects such as oriental armyworm, diamondback moth, and mosquito. One compound (3g) showed the highest insecticidal activity against oriental armyworm.
LETTERS IN DRUG DESIGN & DISCOVERY
(2023)
Article
Oncology
Chao Xu, Xiaoli Xie, Ning Kang, Huiqing Jiang
Summary: The study investigated the efficacy and safety of neoadjuvant S-1 plus oxaliplatin combined with PD-1 inhibitor and apatinib (SOXPA) in locally advanced gastric cancer (LAGC) patients. The results showed that this treatment achieved satisfactory clinical response, pathological response, survival profile, and manageable safety in LAGC patients.
JOURNAL OF CANCER RESEARCH AND CLINICAL ONCOLOGY
(2023)
Article
Medicine, General & Internal
Meghan K. Thomas, Marc E. Heincelman, Jingwen Zhang, Justin Marsden, Jennifer Dulin, Patrick Robbins, Kelly Hunt, Patrick Mauldin, William P. Moran, Benjamin Kalivas
Summary: Patients admitted via interhospital transfer are more likely to experience in-hospital delirium, leading to increased mortality, length of stay, and discharge to facility. Routine screening and intervention prior to patient transfer are emphasized.
JOURNAL OF INVESTIGATIVE MEDICINE
(2023)
Article
Chemistry, Multidisciplinary
Junpeng Xie, Yu Ji, Liang Ma, Zhaorui Wen, Jun Pu, Litong Wang, Sen Ding, Zhaoxi Shen, Yu Liu, Jinliang Li, Wenjie Mai, Guo Hong
Summary: Potassium (K) metal batteries have potential for commercial development, but the arbitrary dendrite growth and side reactions of K metal hinder their progress. Interface engineering between the current collector and K metal can improve the performance by guiding K metal deposition and suppressing side reactions. A bifunctional layer with an O/F-rich Sn-K alloy and a preformed solid-electrolyte interphase (SEI) layer has been designed to achieve this. The bifunctional layers enable low nucleation overpotential, high Coulombic efficiency, and stable operation of K metal batteries.
Article
Chemistry, Multidisciplinary
Yu Ji, Junpeng Xie, Zhaoxi Shen, Yu Liu, Zhaorui Wen, Lei Luo, Guo Hong
Summary: A high-performance zinc-iodine energy storage system based on hydrothermal reduced graphene oxide and a high concentration zinc chloride water-in-salt electrolyte is proposed. The system shows improved Coulombic efficiency and rate performance, with stable long-term cycling capability and high capacity.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Fisheries
Pingping Li, Haihong Chen, Jingyu Zhang, Xiaoqing Feng, Baoheng Xiao, Yiyi Hu, Zhenghong Sui
Summary: In recent years, changes in the concentrations and compositions of nutrients in the ocean have negatively affected the biomass and quality of macroalgae. A strain of Gracilariopsis lemaneiformis with a curly branch phenotype has been discovered in China, causing negative impacts on the cultivation industry. The abnormality of this strain is correlated with the concentration of nitrogen and phosphorus, and certain biological processes are down-regulated compared to the normal strain.
Article
Cell Biology
Shuang Hao, Jingchao Zhang, Yu Pei, Longhui Guo, Zhenxing Liang
Summary: This study found that epicardial adipose tissue (EAT) mediates cardiomyocyte apoptosis after acute myocardial infarction (MI) through secretion of complement factor D (CFD) and activation of PARP-1 activity. This discovery offers key targets for intervention in acute MI.
CELLULAR SIGNALLING
(2023)
Article
Chemistry, Physical
Shuxiang Wen, Xin Li, Jingjing Zhang, Jie Wang, Hao Ding, Ningshuang Zhang, Dongni Zhao, Liping Mao, Shiyou Li
Summary: This study investigates the compatibility of Na2Ti3O7@C anode material with sodium perchlorate (NaClO4)-based and sodium trifluoromethyl sulfonate (NaCF3SO3)-based electrolytes in sodium ion batteries (SIBs). The results reveal that the NaCF3SO3-based electrolyte forms a thin, compact, and uniform solid electrolyte interphase (SEI) film, which reduces the transmission energy barrier of Na+ and improves the cycling and rate performance of batteries. In contrast, the NaClO4-based electrolyte leads to the formation of a thicker SEI film containing Na(2)CO(3) and NaF, resulting in higher interface impedance and decreased battery cycle performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Green & Sustainable Science & Technology
Feng Liu, Qingwen Long, Guiquan Che, Zhihao Zhang, Mick Cooper, Jing Zhang, Gang Pan, Wentao Jiao
Summary: In this study, a novel method of coating polyelectrolytes on holey graphene oxide was used to modify the surface charge of the membrane, resulting in improved water flux and desalination performance.
JOURNAL OF CLEANER PRODUCTION
(2023)
Editorial Material
Surgery
Shanel Normandin, Tyler Safran, Ryan Mitchell, Peter Davison, Sebastian Winocour, Edward Reece, Mirko S. S. Gilardino, Liqin Xu, Joshua Vorstenbosch
PLASTIC AND RECONSTRUCTIVE SURGERY
(2023)
Article
Green & Sustainable Science & Technology
Yingbo Zhang, Kui Shan, Xiuming Li, Hangxin Li, Shengwei Wang
Summary: Data centers have attracted worldwide attention due to their high energy consumption, and high-temperature data centers could save significant cooling energy. However, addressing technical bottlenecks and ensuring equipment reliability are essential before implementing high-temperature data centers. This paper provides a comprehensive review of these critical aspects, categorizing and analyzing the benefits, bottlenecks, and potential solutions.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2023)
Article
Genetics & Heredity
Hsien-Yu Fan, Wan-Yu Lin, Tzu-Pin Lu, Yun-Yu Chen, Justin BoKai Hsu, Sung-Liang Yu, Ta-Chen Su, Hung-Ju Lin, Yang-Ching Chen, Kuo-Liong Chien
Summary: This study used targeted next-generation sequencing to investigate the association between genetic variants and left ventricular mass, and identified candidate genes including CASQ2, COL5A1, and FXN. These findings provide important insights into the functional mechanisms of these genes and variants.
FRONTIERS IN GENETICS
(2023)
Review
Oncology
Yuchen Zhang, Chongjie Yao, Ziyong Ju, Danli Jiao, Dan Hu, Li Qi, Shimin Liu, Xueqing Wu, Chen Zhao
Summary: Kruppel-like factors (KLFs) are DNA-binding transcriptional regulators that play essential roles in various cellular processes, including tumor development. They regulate multiple signaling pathways and mediate crosstalk among them, and their abnormal expression is closely associated with tumor cell characteristics and alterations in the tumor microenvironment. The role of each KLF in tumors varies depending on tumor type and stage of development. This review focuses on the molecular biology of KLFs, the regulation of classical signaling pathways by these factors, and their potential as molecular targets in tumor therapy.
FRONTIERS IN ONCOLOGY
(2023)
Article
Chemistry, Physical
Orkun Furat, Donal P. Finegan, Zhenzhen Yang, Matthias Neumann, Sangwook Kim, Tanvir R. Tanim, Peter Weddle, Kandler Smith, Volker Schmidt
Summary: The operating temperature has a significant impact on the degradation behavior of batteries. This study investigates the structural degradation of lithium-ion positive electrodes under different operating temperatures, and finds that particle porosity increases with higher cycling temperature, while particle surface area remains similar across different cycling-temperature aging conditions.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Junyan Li, Ming Lu, Weijia Zheng, Wei Zhang
Summary: MXenes are two-dimensional materials with unique structures and properties, which have attracted significant scientific interest. Ion intercalation, as an important mechanism, plays a crucial role in regulating the electronic and chemical properties of MXene materials. This review provides an overview of the interaction events between ions and MXenes, including advanced characterization techniques, influencing factors, mechanisms, and functionalization roles of ion intercalation.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Zhengtai Zha, Tianjiang Sun, Diantao Li, Tao Ma, Weijia Zhang, Zhanliang Tao
Summary: A novel zwitterion additive is developed to improve the electrochemical performance and cycling stability of aqueous zinc batteries. The zwitterion forms a stable solid electrolyte interphase on the electrode surface, isolating the zinc anode from the electrolytes and enabling fast zinc ion migration. The proposed electrolyte shows promising results in symmetric cells and full cells, with long cycling stability and high capacity retention.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Nyung Joo Kong, Myeong Seon Kim, Jae Hyun Park, Jongbok Kim, Jungho Jin, Hyun-Wook Lee, Seok Ju Kang
Summary: Polymeric conducting binders have significant research value as they can serve as both binders and conducting agents, increasing the proportion of active materials in batteries and the volumetric energy density. This study explores the potential of a composite of PEDOT:PSS and polyethylene glycol (PEG) as a high-performing binder for silicon anodes. The addition of PEG polymer enhances the conductivity of PEDOT:PSS and improves the mechanical properties of the silicon anode, resulting in extended cycle endurance. The use of operando optical microscopy allows for direct observation of the binder's operation. Consequently, the bifunctional PEDOT:PSS/PEG binder shows promise for high-performance lithium-ion battery binders.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Yangze Huang, Lixuan Zhang, Jiawen Ji, Chenyang Cai, Yu Fu
Summary: This study proposed a novel temperature-dependent viscoelastic liquid electrolyte and a hollow transition bi-metal selenide as the sulfur host material to address the issues in Li-S batteries. The experiments showed promising results in stabilizing the anode and improving cycling performance.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Ao Yu, Wei Zhang, Nimanyu Joshi, Yang Yang
Summary: This review provides a comprehensive overview of research progress in ZIB anodes, including protective coating layers on zinc surfaces and intercalated anode materials. By designing protective coating layers and selecting appropriate intercalated anode materials, the inherent limitations of zinc metal anode can be overcome, leading to improved reliability and performance of ZIBs.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Xin Wang, Yumiao Tian, Konghua Yang, Chenhui Ma, Wenqiang Lu, Xiaofei Bian, Nan Chen, Heng Jiang, Yan Li, Xing Meng, Pengyue Gao, Dong Zhang, Fei Du
Summary: Researchers developed a new sandwich deposition approach using boron nitride layer as a current collector, which enhances the performance of aqueous zinc-ion batteries.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Sang Jun Lee, Dongwoo Kang, Dong Yeol Hyeon, Dong Seok Kim, Suyoon Eom, Su Hwan Jeong, Dong Park Lee, Dawon Baek, Jou-Hyeon Ahn, Gyeong Hee Ryu, Kwi-Il Park, San Moon, Joo-Hyung Kim
Summary: This study utilizes the ice-templating method to create a self-supporting three-dimensional hierarchical porous structure, which effectively inhibits sodium dendrite growth and improves the performance and longevity of sodium-metal batteries.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Yifan Yu, Meng Lei, Yangyang Liu, Keyi Chen, Chuanzhong Lai, Jiulin Hu, Chilin Li
Summary: Metal fluorides as conversion-reaction cathodes have advantages such as low cost, environmentally friendly, and high energy density. In this study, a hydroxyl-rich copper fluoride (Cu2(OH)3F) was proposed as a conversion cathode, coupled with an electrolyte additive engineering, to address the poor reversibility issue. The presence of OH in Cu2(OH)3F enables effective suppression of Cu+ dissolution, resulting in better reaction reversibility and kinetics.
ENERGY STORAGE MATERIALS
(2024)
