Review
Environmental Sciences
Mahdieh Mozaffari Majd, Vahid Kordzadeh-Kermani, Vahab Ghalandari, Anis Askari, Mika Sillanpaa
Summary: This paper gathers the most widely used adsorption isotherms and their definitions, along with examples of recent related work. A total of 37 adsorption isotherms collected from research published between 2010 and 2020 are presented, along with their parameters and applicable definitions. A table featuring the usage of these isotherms in peer-reviewed studies is also provided.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Green & Sustainable Science & Technology
Bo Lv, Zeya Zhao, Xiaowei Deng, Chaojun Fang, Baolin Xing, Bobing Dong
Summary: The liquid-solid fluidized bed using nutshell activated carbon showed strong adsorption capacity for copper ions in wastewater, with an adsorption efficiency of 96% compared to 76% in a packed bed. The fluidization characteristics played a crucial role in determining the adsorption efficiency.
JOURNAL OF CLEANER PRODUCTION
(2021)
Article
Engineering, Environmental
Hai Nguyen Tran, Eder C. Lima, Ruey-Shin Juang, Jean-Claude Bollinger, Huan-Ping Chao
Summary: The study investigated the effects of different adsorption isotherm models on thermodynamic parameters, indicating the importance of selecting the appropriate model, unit, and equilibrium constant for calculating thermodynamic parameters. Using commercial activated carbon to adsorb methylene green dye, the study compared various models and found that certain equilibrium constants were more suitable for calculating thermodynamic parameters.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Multidisciplinary Sciences
Rosario Delgado
Summary: Calibration curves help determine the concentration of analytes in a sample based on instrument readings, but often this method is misapplied. This paper aims to clarify the issue, explain the error, and provide an easy fix to prevent further replication in experimental scientific work.
ROYAL SOCIETY OPEN SCIENCE
(2022)
Article
Multidisciplinary Sciences
Jason Yi Juang Yeo, Deni Shidqi Khaerudini, Felycia Edi Soetaredjo, Gladdy L. Waworuntu, Suryadi Ismadji, Jaka Sunarso, Shaomin Liu
Summary: The dataset in this article presents the adsorption isotherms of amoxicillin, ampicillin, and doripenem on bentonite. Batch adsorption experiments were conducted using various dosages of bentonite and temperature ranges from 30 to 50 degrees C for single antibiotic solutions. The dataset includes adsorbent loading data obtained through UV-Vis spectrophotometer measurements of antibiotic concentration at adsorption equilibrium. The dataset was fitted using different isotherm models and orthogonal regression to analyze the adsorption behavior, with Langmuir model yielding the highest adsorption capacities for amoxicillin, ampicillin, and doripenem.
Article
Multidisciplinary Sciences
Shotaro Hiraide, Yuta Sakanaka, Yuya Iida, Homare Arima, Minoru T. Miyahara, Satoshi Watanabe
Summary: Flexible metal-organic frameworks (MOFs) with adsorption-induced structural transitions have significant advantages in industrial applications. However, there is currently no theoretical equation available to accurately describe the S-shaped adsorption isotherms of flexible MOFs. In this study, a theoretical equation based on statistical mechanics is derived as a standard for structural transition type adsorption isotherms, and its versatility is demonstrated through multiple examples.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2023)
Article
Chemistry, Multidisciplinary
Murat Yilmaz, Mohd Ali Hashim, Khim Hoong Chu
Summary: This article examines the limitations of the widely used Brunauer-Emmett-Teller (BET) equation in fitting nonstandard type II isotherm data in adsorptive water remediation. It introduces the Aranovich-Donohue equation as a modified version of the BET equation and demonstrates its superior performance in accurately correlating anomalous isotherm data. The Aranovich-Donohue-Sips equation is also shown to effectively fit nonstandard type II isotherm data, highlighting its versatility in practical applications.
SEPARATION SCIENCE AND TECHNOLOGY
(2022)
Article
Computer Science, Information Systems
Xiaoxia He, Xiaodan Zhou, Chunli Li
Summary: This paper investigates the expectile regression with error-in-variables to reduce data error and describe the overall data distribution. It thoroughly examines the asymptotic normality of the proposed estimator and proposes an IRWLS algorithm based on orthogonal distance expectile regression (ODER) to estimate the parameters. Extensive simulation studies and real data applications evaluate the effectiveness of our method in reducing measurement error bias, and demonstrate its capability in reducing simulation error compared to linear and quantile regression schemes.
Article
Chemistry, Physical
M. Damej, R. Hsissou, Avni Berisha, K. Azgaou, M. Sadiku, M. Benmessaoud, N. Labjar, S. El hajjaji
Summary: In this study, a new organic compound epoxy resin (TTA) was synthesized and used as a corrosion inhibitor for carbon steel C38 in 1 M HCl acid medium. The corrosion inhibition process was investigated using experimental and theoretical calculations. The results showed that TTA acted as a mixed type inhibitor, and its inhibitory efficiency increased with concentration. Additionally, the adsorption of TTA on the carbon steel surface followed Langmuir's adsorption isotherm.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Biochemistry & Molecular Biology
William E. Peterman, Nathaniel S. Pope
Summary: The field of landscape genetics is rapidly evolving and using regression-based frameworks to infer the contributions of landscape and habitat variables to genetic differentiation. It is important to model a single conductance or resistance surface as a parameterized function of spatial covariates and estimate parameters by linking resistance distances to genetic dissimilarity. Nuisance parameters in regression models should not be confused with the mapping between spatial covariates and conductance/resistance.
Article
Environmental Sciences
Prarabdh Jain, Kedar Sahoo, Lenin Mahiya, Harsh Ojha, Harshita Trivedi, Avanish Singh, Manoj Kumar
Summary: A low cost polyvinyl alcohol-glutaraldehyde cross-linked hydrogel beads were successfully used for color removal from model industrial effluent containing Congo Red dye, achieving a high adsorption capacity and showing good reusability. Adsorption analysis revealed a multi-layer adsorption and pseudo second order kinetics, with fixed bed experiments best explained by the Thomas mathematical model. The studies demonstrated that external and internal mass diffusion were no longer rate limiting factors in the experiments.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2021)
Article
Environmental Sciences
Hongqing Zhu, Yujia Huo, Xin He, Wei Wang, Shuhao Fang, Yilong Zhang
Summary: The mechanism of gas adsorption by oxygen-containing functional groups (OCFGs) in Danhou lignite was studied through experiment and simulation, establishing a macromolecular model and determining the density of the lignite. Results showed that the adsorption of CH4 by OCFGs is affected by adsorption positions and directions, with different electrostatic forces impacting the adsorption capacities. The findings can be utilized in coal and gas outburst prevention and control.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Polymer Science
Matteo Di Virgilio, Saverio Latorrata, Cinzia Cristiani, Giovanni Dotelli
Summary: The increasing quantity and heterogeneity of waste from electrical and electronic equipment (WEEE) due to rapid technological advancement require innovative methods for recycling and recovery processes. This study focuses on understanding the adsorption and release mechanisms of activated carbon (AC) and its pentaethylenehexamine (PEHA)-modified derivative (MAC) for treating valuable rare earth elements (REEs) derived from WEEE. The experimental data and mathematical modeling suggest that these materials have potential suitability for industrial-level processes.
Article
Engineering, Chemical
Li Zhang, Jing Huang, Xuemei Liu, Simeng Luo, Lingxiao Qu
Summary: This study modified bagasse with phosphoric acid, nitric acid, and oxalic acid to obtain PMB, NMB, and OMB adsorbents for Cr(VI) adsorption in wastewater. An orthogonal test was conducted to investigate the effects of immersion ratio, immersion temperature, immersion time, and acid concentration on the adsorption performance. The results showed that the adsorbent had the highest adsorption efficiency under specific conditions. Characterization analysis revealed that the surface properties of PMB, NMB, and OMB differed from those of bagasse, and they exhibited better adsorption performance than the original bagasse. Langmuir adsorption isotherm and quasi-secondary kinetic equation confirmed the adsorption of Cr(VI) by PMB, NMB, and OMB. Overall, PMB, NMB, and OMB can effectively purify Cr(VI) wastewater.
DESALINATION AND WATER TREATMENT
(2022)
Article
Environmental Sciences
Qunpo Jia, Bowen Li, Bo Li, Yanpeng Cai, Xiao Yuan
Summary: This study investigated the adsorption properties of four selected neonicotinoids (NEOs) on urban tidal stream sediments. Results showed that the adsorption of NEOs onto sediments followed a linear isotherm model, and the adsorption amounts varied for different NEOs. The adsorption processes were exothermic reactions, and their rates were influenced by pH, flow rates, and organic matter content.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Physical
Giani de Vargas Briao, Meuris Gurgel Carlos da Silva, Melissa Gurgel Adeodato Vieira, Khim Hoong Chu
Summary: This paper evaluates three modified BET equations against the original BET equation in correlating adsorption isotherms of water contaminants, showing that the modified equations outperform the original one; the Aranovich-Donohue equation stands out as a promising model for accurately tracing the atypical curve shapes of reactive blue 5G and naphthenic acid isotherms.
COLLOID AND INTERFACE SCIENCE COMMUNICATIONS
(2022)
Article
Engineering, Chemical
Khim Hoong Chu, Jean Debord, Michel Harel, Jean-Claude Bollinger
Summary: This article discusses the correlation of experimental equilibrium data for the adsorption of water contaminants on solid surfaces using various isotherm expressions, and argues that four commonly used isotherms provide the same results when fitted to the data.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Review
Chemistry, Applied
Khim Hoong Chu
Summary: This article provides a specific review of modeling approaches for describing breakthrough curves of water contaminants and serves as a cautionary guide to common and persistent modeling misconceptions. It focuses on early career researchers in the field of adsorptive water remediation. The article discusses typical data- and mechanism-driven models, along with numerical fixed bed models and their various curve broadening mechanisms. It also highlights the use of analytical fixed bed models for linear and nonlinear trace systems. The article concludes with a summary of misconceptions associated with the use of phenomenological and empirical models to fit breakthrough curves.
SEPARATION AND PURIFICATION REVIEWS
(2023)
Article
Biotechnology & Applied Microbiology
Giani de Vargas Briao, Khim Hoong Chu
Summary: This paper explores the use of the Lambert W function to invert the loading-implicit isotherms of Elovich, Volmer, and Jossens to solve for adsorbed phase concentration as a function of liquid phase concentration. The practical implementation of the Lambert W function in Excel provides a novel method to fit loading-implicit isotherms to experimental data of water contaminants.
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Murat Yilmaz, Mohd Ali Hashim, Khim Hoong Chu
Summary: This article examines the limitations of the widely used Brunauer-Emmett-Teller (BET) equation in fitting nonstandard type II isotherm data in adsorptive water remediation. It introduces the Aranovich-Donohue equation as a modified version of the BET equation and demonstrates its superior performance in accurately correlating anomalous isotherm data. The Aranovich-Donohue-Sips equation is also shown to effectively fit nonstandard type II isotherm data, highlighting its versatility in practical applications.
SEPARATION SCIENCE AND TECHNOLOGY
(2022)
Article
Engineering, Chemical
Khim Hoong Chu, Mohd Ali Hashim
Summary: This study explores the feasibility of using normal and log-normal probability distributions to track asymmetric breakthrough curves in fixed bed columns. It finds that different probability distributions have different fitting effects for different adsorbates, and the log-normal distribution can describe asymmetric breakthrough curves more accurately.
CHEMICAL ENGINEERING COMMUNICATIONS
(2023)
Article
Engineering, Chemical
Jean Debord, Michel Harel, Jean-Claude Bollinger, Khim Hoong Chu
Summary: This work aims to refute the claim that the Elovich isotherm is significantly inferior to the Langmuir or Freundlich isotherm in correlating adsorption equilibrium data. The mistaken finding is a result of comparing linearized versions of the three isotherms based on different sets of transformed data. By discriminating isotherms based on untransformed data, the Elovich isotherm is shown to be highly competitive against the Langmuir or Freundlich isotherm. Furthermore, this work demonstrates how a modified form of the Elovich isotherm can be used to evaluate the energy distribution of heterogeneous surfaces.
CHEMICAL ENGINEERING SCIENCE
(2022)
Review
Engineering, Chemical
Ackmez Mudhoo, Khim Hoong Chu, Prasenjit Mondal
Summary: Attrition resistance is an important measure of mechanical strength in adsorbents used for aqueous adsorption. This review discusses the quantification of attrition resistance, variability in attrition loss among different adsorbents, and the implications of attrition on adsorption systems. Opportunities for further research are presented to enhance understanding of attrition in real-scale water purification.
Article
Engineering, Chemical
Khim Hoong Chu, Mohd Ali Hashim, Hadis Bashiri, Jean Debord, Michel Harel, Jean-Claude Bollinger
Summary: The FH isotherm, which was first introduced in the mid-2000s in the field of water contaminant adsorption, has gained significant attention in recent years, largely due to its coverage in review articles. This article highlights the incompatibility of the linear form of the FH isotherm with its original nonlinear version. The study shows that the linearized FH isotherm suffers from serious defects, including incorrect parameter estimates and the inability to plot standard isotherm curves. It is recommended to use the original form of the FH isotherm in data fitting to avoid publishing meaningless research. Additionally, the article presents a novel application of the FH isotherm to evaluate the energy distribution of heterogeneous adsorbents.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Chemistry, Physical
Khim Hoong Chu, Mohd Ali Hashim
Summary: The Harkins-Jura isotherm equation was initially developed for sigmoid or type II isotherms in gas-solid adsorption systems. However, it has been exclusively used for hyperbolic or type I isotherms in water contaminant adsorption since the mid-2000s. Compared to the well-established Langmuir and Freundlich equations, the Harkins-Jura isotherm is inferior in modeling type I adsorption data and performs poorly in modeling type II data. Its limited modeling power suggests that it is time to bid farewell to the mediocre Harkins-Jura isotherm.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Multidisciplinary
Giani de Vargas Briao, Mohd Ali Hashim, Khim Hoong Chu
Summary: The Sips isotherm equation, widely used for studying water contaminant adsorption, has some problematic application issues. Firstly, the linear version of the Sips equation promoted in several reviews is incorrect. Secondly, comparing the Sips and Langmuir-Freundlich equations is inappropriate as they are mathematically equivalent. Lastly, applying the Sips equation to type I isotherms, which are hyperbolic curves, is less valuable than using simpler models like the Langmuir and Freundlich equations. The Sips equation is more effectively applied to type V isotherms, which are sigmoid curves.
SEPARATION SCIENCE AND TECHNOLOGY
(2023)
Review
Engineering, Environmental
Hai Nguyen Tran, Jean-Claude Bollinger, Stefano Salvestrini, Khim Hoong Chu, Ruey-Shin Juang
Summary: The Radke-Prausnitz model, a three-parameter model belonging to the Langmuir-Freundlich-type equation, is analyzed in this study to promote its proper application in adsorption research. The correct expression, citation, and units of its parameters are provided. The model has important implications for understanding adsorption processes.
JOURNAL OF ENVIRONMENTAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Jean Debord, Khim Hoong Chu, Michel Harel, Stefano Salvestrini, Jean-Claude Bollinger
Summary: The name of Herbert Freundlich is associated with the relationship between adsorbed amount and concentration in solution. The Freundlich isotherm is considered as the model of choice for correlating experimental adsorption data. However, his 1907 paper was not widely cited until the early 2000s, and those citations were often incorrect. This paper identifies the historical developments of the Freundlich isotherm and discusses its theoretical points, along with suggesting future ideas for exploration.
Letter
Engineering, Environmental
Khim Hoong Chu, Mohd Ali Hashim
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Dujduan Sompornpailin, Phattarapan Mongconpattarasuk, Chalita Ratanatawanate, Ronbanchob Apiratikul, Khim Hoong Chu, Patiparn Punyapalakul
Summary: The adsorption mechanisms of three nonsteroidal anti-inflammatory drugs (NSAIDs) on different materials were compared. Pristine MIL-53(Al) showed the highest adsorption capacity, while MIL-53(Al)/alginate exhibited high selectivity in wastewater treatment.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)