4.7 Article

Cellulose Nanofiber-Based Aerogels from Wheat Straw: Influence of Surface Load and Lignin Content on Their Properties and Dye Removal Capacity

期刊

BIOMOLECULES
卷 12, 期 2, 页码 -

出版社

MDPI
DOI: 10.3390/biom12020232

关键词

aerogels; dye removal; lignocellulosic biomass; circular economy; biorefinery

资金

  1. Department of Economic Transformation, Industry, Knowledge and Universities (Regional Government of Andalusia) [P18-RT-4064]

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Water pollution is a serious global issue. Nanocellulose-based aerogels have excellent adsorption capacities, making them ideal for water purification. In this study, (ligno)cellulose nanofibers were obtained from wheat straw residues using different pre-treatments to produce bioaerogels with varying consistencies. The materials were characterized and tested for dye removal capacity. The results showed that the adsorption capacity was better for TEMPO-oxidized aerogels, while the residual lignin content in one type of aerogel showed improvement in removal capacity.
Water pollution is one of the most serious problems worldwide. Nanocellulose-based aerogels usually show excellent adsorption capacities due to their high aspect ratio, specific surface area and surface charge, making them ideal for water purification. In this work, (ligno)cellulose nanofibers (LCNFs/CNFs) from wheat straw residues were obtained using two types of pre-treatments: mechanical (Mec) and TEMPO-mediated oxidization (TO), to obtain different consistency (0.2, 0.4, 0.6 and 0.8) bioaerogels, and their adsorption capacities as dye removers were further studied. The materials were characterized in terms of density, porosity and mechanical properties. An inversely proportional relationship was observed between the consistencies of the aerogels and their achieved densities. Despite the increase in density, all samples showed porosities above 99%. In terms of mechanical properties, the best results were obtained for the 0.8% consistency LCNF and CNF-Mec aerogels, reaching 67.87 kPa and 64.6 kPa for tensile strength and Young's modulus, respectively. In contrast, the adsorption capacity of the aerogels was better for TEMPO-oxidized aerogels, reaching removal rates of almost 100% for the CNF-TO5 samples. Furthermore, the residual lignin content in LCNF-Mec aerogels showed a great improvement in the removal capacity, reaching rates higher than 80%, further improving the cost efficiency of the samples due to the reduction in chemical treatments.

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