期刊
ADVANCED ENERGY MATERIALS
卷 11, 期 47, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202102648
关键词
blend morphology; bulk heterojunction blend; fluorination effects; organic solar cells; thieno[3; 4-c]pyrrole-4; 6-dione
类别
资金
- Center for Light Energy Activated Redox Processes (LEAP)
- Energy Frontier Research Center - US Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences [DE-SC0001059]
- Office of Naval Research [N00014-20-1-2116]
- AFOSR [FA9550-18-1-0320]
- Flexterra Corporation
- Institute for Sustainability and Energy at Northwestern (ISEN)
- US DOE [DE-AC02-06CH11357]
- National Natural Science Foundation of China [21875148]
- Institute for Sustainability and Energy at Northwestern
- Office of the Vice President for Research at Northwestern
- China Scholarship Council [201906240142]
Fluorination of donor and/or acceptor blocks in OSCs can negatively affect device performance, as seen in the lower efficiency of fluorinated compared to non-fluorinated systems. TEM analysis reveals larger phase domain sizes and decreased exciton dissociation efficiency in fluorinated blends, while GIWAXS shows less textured structures and SLC testing indicates lower and unbalanced hole/electron mobility in fluorinated blends.
Fluorination of the donor and/or acceptor blocks of photoactive semiconducting polymers is a leading strategy to enhance organic solar cell (OSC) performance. Here, the effects are investigated in OSCs using fluorine-free (TPD-3) and fluorinated (TPD-3F) donor polymers, paired with the nonfullerene acceptor Y6. Interestingly and unexpectedly, fluorination negatively affects performance, and fluorine-free TPD-3:Y6 OSCs exhibit a far higher power conversion efficiency (PCE = 14.5%) than in the fluorine-containing TPD-3F:Y6 blends (PCE = 11.5%). Transmission electron microscopy (TEM) analysis indicates that the TPD-3F:Y6 blends have larger phase domain sizes than TPD-3:Y6, which reduces exciton dissociation efficiency to 81% for TPD-3F:Y6 versus 93% for TPD-3:Y6. Additionally, grazing incidence wide-angle X-ray scattering (GIWAXS) reveals that the TPD-3F:Y6 blends are less textured than those of TPD-3:Y6, while space-charge limited currents reveal lower and unbalanced hole/electron mobility in TPD-3F:Y6 versus TPD-3:Y6 blends. Charge recombination dynamic, transient absorption, and donor-acceptor miscibility assays additionally support this picture. Furthermore, conventional architecture TPD-3:Y6 OSCs deliver a PCE of 15.2%, among the highest to date for halogen-free polymer donor OSCs. Finally, a large-area (20.4 cm(2)) TPD-3:Y6 blend module exhibits an outstanding PCE of 9.31%, one of the highest to date for modules of area >20 cm(2).
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