期刊
INORGANIC CHEMISTRY
卷 55, 期 23, 页码 12435-12440出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b02385
关键词
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资金
- Center for Sustainable Use of Renewable Feedstocks (CenSURF), a National Science Foundation (NSF) Center for Chemical Innovation (CCI)
- NIH Shared Instrument Grant [1S10OD012077-01A1]
- MRSEC Program of the NSF [DMR 1121053]
- NSF
The group 11 hydride clusters [Ag6H4(dppm)(4)(OAc)(2)] (1) and [Cu3H(dppm)(3)(OAc)(2)] (2) (dppm = 1,1-bis(diphenylphosphino)methane) were synthesized in moderate yields from the reaction of M(OAc) (M = Ag, Cu) with Ph2SiH2, in the presence of dppm. Complex 1 is the first structurally characterized homometallic polyhydrido silver cluster to be isolated. Both 1 and 2 catalyze the hydrosilylation of (alpha/beta-unsaturated) ketones. Notably, this represents the first example of hydrosilylation with an authentic silver hydride complex.
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